Iron Oxyhydroxide Nanodispersion Stability Without Auxiliary Components

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Solution Overview

Problem

Existing methods for forming stable nanodispersion liquids with iron oxyhydroxide require auxiliary components and often leave residual components from these materials, making it difficult to achieve a dispersion with minimal impurities.

Innovation Solution

A nanodispersion liquid is produced using β-iron oxyhydroxide with an average particle diameter of 0.2 μm or less, where the iron oxyhydroxide is the primary component, and the liquid contains no additional components other than those derived from an iron compound and a base or pH adjusting agent, with specific properties such as granular crystal shape and high chlorine content, allowing for stability without auxiliary components.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional production methods using auxiliary components are used, then stable nanodispersion liquid can be formed, but the dispersion liquid contains residual components from auxiliary materials

Engineering Contradiction:
Improvestability of nanodispersion liquidVSAvoidresidual components from auxiliary materials
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention extracts and eliminates the need for auxiliary components (buffer compounds, hydroxycarboxylic acids, metal hydroxides) from the production process. By using only iron compound and base as raw materials, all auxiliary components and their residual products are completely removed, solving the contradiction between stability and purity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The iron oxyhydroxide particles themselves provide the necessary surface charge and stability through their natural properties, without requiring external auxiliary components. The system becomes self-sufficient, using only the essential iron compound and base to achieve both stability and purity.

Inventive Principle:
Principle #25Self-service

2Reliability

If auxiliary components are used in production, then nanodispersion liquid can be stabilized, but production process becomes complicated

Engineering Contradiction:
Improvestability of nanodispersion liquidVSAvoidproduction process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention removes all auxiliary components (buffer compounds, hydroxycarboxylic acids, metal hydroxides, and their corresponding production steps) from the process. Only iron compound and base remain as raw materials, dramatically simplifying the production process while maintaining stability.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the production parameters to use only two raw materials (iron compound and base) with controlled pH, eliminating the need for multiple auxiliary components and complex production steps while achieving stable nanodispersion liquid.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional sols are used, then production is possible, but stability is only maintained when nearly neutral pH

Engineering Contradiction:
Improveproduction feasibilityVSAvoidpH range stability
Core Design Contradiction:
Ease of manufactureVSAdaptability or versatility

Solution Approach 1:

The invention changes the pH parameter range from narrow (nearly neutral) to wide (pH 2-6), achieving stability across acidic conditions. This is accomplished through the simplified production method using only iron compound and base, which creates particles with surface properties stable across this broader pH range.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The nanodispersion liquid produced by this invention has universal stability across multiple pH conditions (acidic to nearly neutral), unlike conventional sols that are only stable at nearly neutral pH. This multi-pH stability expands the applicability and versatility of the product.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Data Source

PatentUS10781109B2Iron oxyhydroxide nanodispersion liquid
Publication Date: 2020.09.22 NIPPON SODA CO LTD
  • US10781109B2 patent drawing
  • US10781109B2 patent drawing
  • US10781109B2 patent drawing

AI summary

It is an object of the present invention to provide a nanodispersion liquid of iron oxyhydroxide that is stable and does not contain components derived from auxiliary components. The nanodispersion liquid of iron oxyhydroxide according to the present invention is a nanodispersion liquid in which particles comprising iron oxyhydroxide as a main component and having an average particle diameter d50 of 0.2 μm or less and a d90 of 1 μm or less are dispersed in a solvent. The iron oxyhydroxide is preferably β-iron oxyhydroxide. The nanodispersion liquid of iron oxyhydroxide according to the present invention preferably contains no other components than a substance derived from at least either of an iron compound and a base, a pH adjusting agent, and a solvent.