Iron Wire Spray Material for Engine Tribology

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Solution Overview

Problem

Existing wire-form spray materials for arc wire spraying in internal combustion engines lack optimal tribological properties and machinability, leading to inefficiencies in friction reduction and wear resistance, particularly in critical system states like top and bottom dead centers in cylinder contact surface/piston ring systems.

Innovation Solution

A wire-form spray material comprising iron with microalloys that form pearlite, bainite, and wear-resistant martensite phases upon solidification, optimized with specific carbon, silicon, manganese, chromium, copper, and nitrogen content to enhance tribological performance and machinability, with controlled cooling and alloy composition to achieve a dense, uniform coating.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If wire-form spray material with conventional alloy composition is used, then the coating can be deposited, but the tribological properties (wear resistance and friction reduction) are insufficient

Engineering Contradiction:
Improvewear resistanceVSAvoidcoating deposition quality
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies parameter changes by precisely controlling the alloy composition within specific ranges (carbon: 0.20-0.60 wt%, silicon: 0.10-0.50 wt%, manganese: 0.50-1.50 wt%, chromium: 0.05-0.40 wt%, copper: 0.05-0.30 wt%, nitrogen: 0.005-0.050 wt%) to transform the microstructure into pearlite and bainite phases, thereby improving wear resistance and friction reduction properties while maintaining coating deposition quality

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite microstructure consisting of multiple phases (pearlite, bainite, and martensite) through controlled alloying and thermal spraying, where each phase contributes different properties: pearlite provides wear resistance, bainite provides toughness, and martensite provides hardness, achieving superior tribological performance

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If wire-form spray material is used for arc wire spraying, then coating can be applied, but the machinability of the spray coating is poor

Engineering Contradiction:
ImprovemachinabilityVSAvoidcoating density
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent improves machinability by controlling the alloy composition to form a microstructure with specific hardness and ductility characteristics, particularly through the pearlite and bainite phases that provide a balance between strength and machinability, while maintaining coating density through optimized spraying parameters

Inventive Principle:
Principle #35Parameter changes

3Reliability

If microalloy elements are added to form wear-resistant phases, then tribological properties improve, but the complexity of alloy composition increases

Engineering Contradiction:
Improvetribological propertiesVSAvoidalloy composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent manages alloy composition complexity by establishing specific concentration ranges for each microalloy element (carbon: 0.20-0.60 wt%, silicon: 0.10-0.50 wt%, manganese: 0.50-1.50 wt%, chromium: 0.05-0.40 wt%, copper: 0.05-0.30 wt%, nitrogen: 0.005-0.050 wt%) that work synergistically to form the desired microstructure without requiring excessive elements, thus improving tribological properties while controlling compositional complexity

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting spray coating exhibits improved wear resistance, reduced friction, and enhanced machinability, with low porosity and roughness, and improved corrosion resistance, effectively addressing the tribological challenges in engine components.

Implementation Method 1

an electric arc is generated between two wire-form spray materials by applying a voltage. The wire tips thus melt off

Methodology Applied
Scientific EffectElectric arc: Electric Arc

Implementation Method 2

upon solidification of the spray material at least pearlite and bainite are produced

Methodology Applied
Scientific EffectSolidification: Phase Change

Data Source

PatentUS9546414B2Wire-type spray material for a thermally sprayed layer having a pearlite, bainite, martensite structure
Publication Date: 2017.01.17 MERCEDES BENZ GROUP AG
  • US9546414B2 patent drawing
  • US9546414B2 patent drawing

AI summary

A wire-form spray material, in particular for arc wire spraying, essentially comprising iron. The spray material is formed at least with carbon as a microalloy such that upon solidification of the spray material a fine pearlitic, bainitic, martensitic structure arises in which finely dispersed nitrides are present.