Irradiated Polymer Cement Paste Strength

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Solution Overview

Problem

The use of plastic as an aggregate in partial replacement of cement in cement paste can adversely impact compressive strength, making it unsuitable for various applications, and existing recycling methods, such as mechanical recycling, may degrade plastic quality and increase pollution.

Innovation Solution

Incorporating irradiated polymer particles with increased crystallinity and crosslinking, along with silicon dioxide and calcium oxide, into the cement paste to enhance its compressive strength and reduce porosity, allowing for partial replacement of cement while maintaining or improving mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If plastic is used as an aggregate in partial replacement of cement in cement paste, then greenhouse gas emissions are reduced, but compressive strength deteriorates

Engineering Contradiction:
Improvegreenhouse gas emissionsVSAvoidcompressive strength
Core Design Contradiction:
Object-generated harmful factorsVSStrength

Solution Approach 1:

The patent applies gamma irradiation to change the physical and chemical parameters of plastic particles, increasing their crystallinity and creating crosslinked structures. This transforms the plastic from a material that weakens cement paste into one that can maintain or improve compressive strength while still enabling cement substitution and reducing greenhouse gas emissions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite system by combining irradiated plastic particles with cement and specific additives (silicon dioxide, alumina). This composite approach allows the plastic-cement mixture to achieve compressive strength comparable to pure cement paste, resolving the contradiction between using plastic for environmental benefits and maintaining structural strength

Inventive Principle:
Principle #40Composite materials

2Ease of repair

If standard mechanical recycling is used for plastic waste, then plastic can be recovered and reused, but plastic quality degrades and additional pollution is generated

Engineering Contradiction:
Improveplastic recyclabilityVSAvoidpollution and quality degradation
Core Design Contradiction:
Ease of repairVSObject-generated harmful factors

Solution Approach 1:

The patent converts the typically harmful effect of plastic waste into a beneficial building material. By using gamma irradiation to treat waste plastic particles and incorporate them into cement paste, the invention transforms plastic waste from an environmental pollutant into a functional construction material that reduces greenhouse gas emissions while managing plastic waste effectively

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting cement paste exhibits comparable compressive strength to traditional cement paste, reducing greenhouse gas emissions and offering an environmentally friendly alternative for construction applications.

Implementation Method 1

irradiating the particles of the polymer with a dose of gamma radiation increasing crystallinity and crosslinking of the polymer

Methodology Applied
Scientific EffectGamma radiation: Radiation

Implementation Method 2

irradiating the particles of the polymer with a dose of gamma radiation increasing crystallinity and crosslinking of the polymer

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Implementation Method 3

a combination of the silicon dioxide and the calcium oxide may form high-density phases in the cement paste

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 4

irradiating the particles of the polymer with a dose of gamma radiation increasing crystallinity and crosslinking of the polymer

Methodology Applied
Scientific EffectCrosslinking:

Data Source

PatentUS10947158B2Polymer irradiation in cement paste formation
Publication Date: 2021.03.16 MASSACHUSETTS INST OF TECH
  • US10947158B2 patent drawing
  • US10947158B2 patent drawing
  • US10947158B2 patent drawing

AI summary

Devices, systems, and methods of the present disclosure are generally directed to building material including particles of a polymer in an irradiated form, a cement including calcium oxide, and at least one additive including silicon dioxide. In cement paste formed from a mixture of these components, the polymer in the irradiated form may decrease porosity as compared to porosity of cement paste formed without the polymer, and a combination of the silicon dioxide and the calcium oxide may form high-density phases in the cement paste. With these characteristics, such cement paste may exhibit at least the same compressive strength as cement paste formed from the cement by itself. Thus, in certain instances, the particles of the polymer may displace a portion of the cement in a manner that maintains compressive strength while facilitating reduction of greenhouse gas emissions associated with cement paste formation.