Electrically Isolating Polymer Coatings for Electrowetting Devices

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Solution Overview

Problem

Existing electrowetting devices face challenges in fabricating robust devices that can withstand electrical breakdown while in direct contact with liquid, as current multilayer barriers are insufficient for providing both high voltage resistance and effective water penetration protection.

Innovation Solution

A composition comprising crosslinkable monomers, hydrophobic monomers, and dielectric constant enhancing agents such as ferroelectric particulates or electro-active polymers is used to create an electrically isolating coating that provides a physical barrier, enhancing both hydrophobicity and dielectric properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If multilayer barriers are used to provide high voltage resistance, then voltage breakdown resistance is improved, but device complexity increases and fabrication robustness deteriorates

Engineering Contradiction:
Improvevoltage breakdown resistanceVSAvoidmultilayer barrier complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines multiple functions (hydrophobicity, dielectric properties, and barrier protection) into a single polymer composition rather than using separate multilayer barriers. The composition includes crosslinkable monomers for structural integrity, hydrophobic monomers for water resistance, and dielectric constant enhancing agents for voltage breakdown resistance, all integrated in one coating layer.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention uses a composite polymer composition incorporating multiple types of monomers and dielectric enhancing agents (such as ferroelectric particulates or electro-active polymers) to achieve superior electrical isolation and hydrophobicity properties in a single material system, eliminating the need for complex multilayer structures.

Inventive Principle:
Principle #40Composite materials

2Reliability

If existing multilayer barriers are used for water penetration protection, then water resistance is improved, but fabrication robustness and durability worsen

Engineering Contradiction:
Improvewater penetration resistanceVSAvoidfabrication robustness
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent integrates water penetration protection and hydrophobicity into the polymer composition itself through the inclusion of hydrophobic monomers, eliminating the need for separate hydrophobic barrier layers in multilayer structures.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention modifies the chemical composition parameters by incorporating specific ratios of crosslinkable monomers (5-50 wt%), hydrophobic monomers (30-60 wt%), and dielectric constant enhancing agents (5-20 wt%), creating a composition that achieves both water resistance and fabrication robustness through optimized material properties rather than complex layering.

Inventive Principle:
Principle #35Parameter changes

3Duration of action of stationary object

If robust devices are fabricated to withstand electrical breakdown, then device durability is improved, but device complexity increases

Engineering Contradiction:
Improvedevice durabilityVSAvoidfabrication complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent employs a composite polymer composition with crosslinkable monomers forming a robust network structure, hydrophobic monomers providing chemical stability, and dielectric constant enhancing agents delivering superior electrical breakdown resistance, achieving long device lifetime through material composition rather than fabrication complexity.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting coatings offer improved resistance to water penetration, high voltage breakdown, and high dielectric constants, enabling the development of more robust electrowetting devices with enhanced performance and durability.

Implementation Method 1

at least one dielectric constant enhancing agent selected from the group consisting of: dielectric enhancing monomers, ferroelectric particulates, and electro-active polymers

Methodology Applied
Scientific EffectDielectric constant enhancement: Dielectric Permittivity

Implementation Method 2

at least one crosslinkable monomer; at least one hydrophobic monomer

Methodology Applied
Scientific EffectCrosslinking polymerization: Photopolymerisation

Implementation Method 3

at least one hydrophobic monomer

Methodology Applied
Scientific EffectHydrophobicity: Hydrophobe

Data Source

PatentUS8920620B2Electrically isolating polymer composition
Publication Date: 2014.12.30 CORNING INC
  • US8920620B2 patent drawing
  • US8920620B2 patent drawing
  • US8920620B2 patent drawing

AI summary

A composition that includes at least one crosslinkable monomer; at least one hydrophobic monomer; and at least one dielectric constant enhancing agent selected from dielectric enhancing monomers, ferroelectric particulates, and electroactive polymers. Coatings including the polymer of compositions, and articles including electrically isolating layers are also disclosed.