Isosorbide Ether Derivatives for Stable Preservative Systems

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Solution Overview

Problem

Existing preservatives, especially those with ester functions, have limited storage stability and low antimicrobial activity, requiring high concentrations that can cause undesired side effects in compositions like detergents and cosmetics.

Innovation Solution

The use of specific isosorbide ether derivatives with defined structures enhances antimicrobial activity and storage stability, either as standalone preservatives or boosters for existing preservatives, effectively inhibiting a wide range of microorganisms at lower concentrations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If known ester function containing preservatives are used, then antimicrobial activity is achieved, but storage stability deteriorates and side effects increase due to required high concentrations

Engineering Contradiction:
Improveantimicrobial activityVSAvoidstorage stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent changes the chemical structure parameters of preservatives by using isosorbide derivatives with specific alkyl chains (C8-C12) instead of traditional ester-based preservatives. This structural parameter change enables both high antimicrobial activity and excellent storage stability, resolving the contradiction between effectiveness and stability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite preservative systems combining isosorbide derivatives with other compatible substances to achieve synergistic effects. This composite approach enhances antimicrobial activity while maintaining storage stability, allowing lower concentrations to be used and reducing side effects.

Inventive Principle:
Principle #40Composite materials

2Reliability

If high concentrations of antimicrobial preservatives are used to achieve sufficient antimicrobial activity, then microbial inhibition is improved, but undesired side effects increase

Engineering Contradiction:
Improveantimicrobial activityVSAvoidside effects
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

By changing the chemical parameters to isosorbide derivatives with specific molecular structures, the patent achieves high antimicrobial activity at lower concentrations (MIC values indicating potent activity), thereby reducing the harmful side effects associated with high concentrations of traditional preservatives.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If ester function containing preservatives are used, then some preservative activity is achieved, but storage stability deteriorates due to instability of ester functions

Engineering Contradiction:
Improvepreservative activityVSAvoidstorage stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent fundamentally changes the chemical functional groups from unstable ester functions to stable ether and hydroxyl groups in isosorbide derivatives. This parameter change eliminates the storage stability issues associated with ester hydrolysis while maintaining effective preservative activity through the unique molecular structure of isosorbide derivatives.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS9993000B2Isosorbide ether derivatives with preservation activity
Publication Date: 2018.06.12 BASF SE

AI summary

Isosorbide mono ether derivatives with preservation activity.