Intermediate Transfer Member with Self-Release Additives

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Solution Overview

Problem

Existing intermediate transfer members in xerographic systems face issues such as brittleness, incomplete toner transfer, charge exchange leading to image deterioration, and the need for separate release layers, which increase costs and complexity, while also requiring external release assistance.

Innovation Solution

An intermediate transfer member comprising a thermosetting polyimide, a conductive component, and a carboxylic acid functionalized fluoro component that chemically reacts to form a polymeric network, enabling self-release from metal substrates without external assistance, thus eliminating the need for separate release layers and enhancing mechanical and electrical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If a separate release layer is deposited on a metal substrate, then the intermediate transfer member components can be separated by peeling or mechanical devices, but the cost and time of preparation increase and the release layer modifies the intermediate transfer member characteristics

Engineering Contradiction:
Improveseparation of intermediate transfer member componentsVSAvoidnumber of layers in intermediate transfer member
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent combines the release functionality directly into the intermediate transfer member coating by incorporating release additives (such as fluorinated compounds or siloxanes) into the polyimide coating composition. This eliminates the need for a separate release layer, reducing the number of layers from two (release layer + intermediate transfer member) to one integrated structure, thereby reducing complexity while maintaining ease of separation.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent uses chemical intermediaries (release additives) incorporated into the coating that facilitate separation between the intermediate transfer member and the metal substrate. These additives act as mediators that enable controlled release without requiring external peeling mechanisms or separate release layers, thus simplifying the overall structure while maintaining operational ease.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of operation

If liquid fluoro agent is used in intermediate transfer member, then release properties are improved, but the polyimide phase separates making release control difficult

Engineering Contradiction:
Improverelease properties of intermediate transfer memberVSAvoidhomogeneity of polyimide coating
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The patent creates a composite coating material by chemically incorporating release additives (such as perfluorocarboxylic acids or siloxane compounds) into the polyimide matrix during the coating formation process. This results in a homogeneous composite material where the release properties are uniformly distributed throughout the coating, preventing phase separation while maintaining controlled release capability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical parameters of the polyimide coating by incorporating release additives with specific chemical structures (such as fluorinated groups or siloxane groups) that change the surface energy and release characteristics of the coating. This allows control of release properties through chemical composition adjustments rather than using separate liquid fluoro agents that cause phase separation.

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If intermediate transfer member is used in color systems with synchronous development, then multiple toner transfers are achieved, but charge exchange between toner particles and transfer member causes incomplete transfer and image deterioration

Engineering Contradiction:
Improvecapability to handle color toner transfersVSAvoidcompleteness of toner transfer
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent adjusts the electrical parameters of the intermediate transfer member by incorporating conductive additives (such as carbon black or metal particles) into the polyimide coating. This modifies the surface resistivity and charge distribution characteristics, reducing charge exchange between toner particles and the transfer member during synchronous color development, thereby improving toner transfer completeness and image quality.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite coating structure combining polyimide with conductive and release additives. This multi-functional composite material simultaneously provides mechanical strength, controlled release properties, and optimized electrical characteristics for reliable toner transfer in color systems, eliminating the need for separate functional layers.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves high efficiency in toner transfer with minimal image resolution issues, improved stability, and reduced production costs by allowing self-release from metal substrates, resulting in high-quality images with excellent mechanical and electrical properties.

Implementation Method 1

the carboxylic acid functionalized fluoro component chemically reacts with the polyimide to form a polymeric network of the polyimide, and the carboxylic acid functionalized fluoro component

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS8784696B2Intermediate transfer members containing internal release additives
Publication Date: 2014.07.22 XEROX CORP
  • US8784696B2 patent drawing
  • US8784696B2 patent drawing
  • US8784696B2 patent drawing

AI summary

An intermediate transfer member that includes a polyimide, a conductive component, and a carboxylic acid functionalized fluoro component.