ITO Radio Wave Absorber Composition for Humidity-Stable Performance

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Solution Overview

Problem

Existing radio wave absorbers with indium tin oxide resistive layers containing less than 20 weight % tin oxide fail to maintain desired radio wave absorption performance after long-term exposure to high-temperature and high-humidity environments.

Innovation Solution

A radio wave absorber with a resistive layer containing indium tin oxide, an electrical conductor, and a dielectric layer, where the tin oxide content is between 0 and 20 weight % and the hydrogen atom concentration is 5% or more of the total indium, tin, and oxygen atoms, ensuring stable amorphous structure and performance under high-temperature and high-humidity conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the content of tin oxide in indium tin oxide is reduced to less than 20 weight % to achieve lower sheet resistance and improved radio wave absorption, then the radio wave absorption performance deteriorates after long-term exposure to high-temperature and high-humidity environments

Engineering Contradiction:
Improveradio wave absorption performance stabilityVSAvoidenvironmental degradation
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The invention changes the compositional parameters of the resistive layer by controlling the tin oxide content to less than 20 weight % while simultaneously controlling the hydrogen atom concentration to 5% or more of total atoms. This parameter optimization allows achieving lower sheet resistance while maintaining stability under environmental conditions.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite structure consisting of a resistive layer (indium tin oxide with controlled composition), a dielectric layer (polymer), and an electrical conductor. This multi-layer composite design enables the system to achieve both low sheet resistance and environmental stability through the synergistic effect of different materials.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If the content of tin oxide in indium tin oxide is reduced to less than 20 weight % to achieve lower sheet resistance, then the structural stability and amorphous state maintenance deteriorate under high-temperature and high-humidity conditions

Engineering Contradiction:
Improveamorphous structure stabilityVSAvoidperformance after environmental exposure
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The invention optimizes the compositional parameters by controlling hydrogen atom concentration to 5% or more of total atoms in the resistive layer. This compositional control maintains the amorphous structure stability while enabling lower tin oxide content for reduced sheet resistance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The dielectric layer composed of polymer acts as an intermediary between the resistive layer and the external environment. This intermediate layer protects the resistive layer from environmental degradation while maintaining the electrical performance, allowing the system to use lower tin oxide content without compromising structural stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The absorber maintains desired radio wave absorption performance for an extended period, even after exposure to 85° C and 85% relative humidity for 500 hours, with a return loss of 10 dB or more, and retains amorphous state stability.

Implementation Method 1

an electrical conductor that reflects a radio wave

Methodology Applied
Scientific EffectElectromagnetic reflection: Reflection

Implementation Method 2

a resistive layer including indium tin oxide as a main component

Methodology Applied
Scientific EffectElectromagnetic absorption: Absorption (EM radiation)

Data Source

PatentUS11844201B2Radio wave absorber and laminate for radio wave absorbers
Publication Date: 2023.12.12 NITTO DENKO CORP
  • US11844201B2 patent drawing
  • US11844201B2 patent drawing

AI summary

A radio wave absorber (1a) includes a resistive layer (20), an electrical conductor (30), and a dielectric layer (10). The resistive layer (20) includes indium tin oxide as a main component. The electrical conductor (30) reflects a radio wave. The dielectric layer (10) is disposed between the resistive layer (20) and the electrical conductor (30) in the thickness direction of the resistive layer (20). The dielectric layer (10) is formed of a polymer. The content of tin oxide in the indium tin oxide included in the resistive layer (20) is more than 0 weight % and less than 20 weight %. The number of hydrogen atoms included in the resistive layer (20) is 5% or more of the total number of indium atoms, tin atoms, oxygen atoms, and hydrogen atoms included in the resistive layer (20).