Indium Tungsten Zinc Oxide Semiconductor Film for TFT Threshold Voltage Control

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Solution Overview

Problem

Amorphous oxide semiconductor films used in TFTs have limited field-effect mobility and higher threshold voltage compared to traditional amorphous silicon, making it difficult to maintain optimal device operation within the same voltage range.

Innovation Solution

An oxide semiconductor film composed of nanocrystalline or amorphous oxide with indium, tungsten, and zinc, where the tungsten content is between 0.5 and 5 atomic % and the electric resistivity is greater than 10^-1 Ωcm, is used as a channel layer, achieving a threshold voltage of 0 to 4 V and high field-effect mobility.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If amorphous oxide semiconductor film is used in TFT channel layer, then higher carrier mobility can be expected compared with a-Si, but the field-effect mobility is limited to at most approximately 10 cm2/Vs

Engineering Contradiction:
Improvecarrier mobilityVSAvoidfield-effect mobility
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent changes the compositional parameters of the oxide semiconductor film by introducing tungsten as a dopant element and controlling the In/(In+Zn) atomic ratio within 0.1 to 0.5. This parameter optimization resolves the contradiction by achieving field-effect mobility exceeding 10 cm2/Vs while maintaining the amorphous oxide semiconductor structure.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite oxide semiconductor material containing indium, zinc, and tungsten in specific ratios. The addition of tungsten (0.01 to 5 atomic %) to the In-Zn-O system forms a composite material that simultaneously improves carrier mobility and field-effect mobility, resolving the technical contradiction.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If oxide sintered body mainly made of indium including tungsten is used to fabricate oxide semiconductor film, then the material can be suitably used for sputtering method, but the threshold voltage Vth becomes higher than 4 V

Engineering Contradiction:
Improvesuitability for sputtering methodVSAvoidthreshold voltage
Core Design Contradiction:
Ease of manufactureVSEase of operation

Solution Approach 1:

The patent optimizes the compositional parameters by controlling the In/(In+Zn) atomic ratio to 0.1-0.5 and adding tungsten at 0.01-5 atomic %. This parameter control achieves threshold voltage within 0 to 4 V range while maintaining ease of manufacture through sputtering method.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces tungsten locally as a dopant element at controlled concentrations (0.01 to 5 atomic %) within the oxide semiconductor film. This local addition of tungsten improves electrical properties and reduces threshold voltage to within the desired 0 to 4 V range while preserving the overall material structure suitable for sputtering fabrication.

Inventive Principle:
Principle #3Local quality

3Ease of operation

If conventional a-Si is used as semiconductor material for TFT, then threshold voltage Vth is generally 2 to 4 V, but when switching to oxide semiconductor material, maintaining the same Vth range becomes difficult

Engineering Contradiction:
Improvethreshold voltage rangeVSAvoidmaterial compatibility
Core Design Contradiction:
Ease of operationVSAdaptability or versatility

Solution Approach 1:

The patent changes the compositional parameters of the oxide semiconductor film by controlling the In/(In+Zn) atomic ratio within 0.1 to 0.5 and adding tungsten at 0.01 to 5 atomic %. These parameter adjustments enable the oxide semiconductor to achieve threshold voltage within the conventional 0 to 4 V range, ensuring compatibility with existing device designs.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a homogeneous oxide semiconductor film with uniform distribution of indium, zinc, and tungsten elements. The controlled composition (In/(In+Zn) ratio of 0.1-0.5 and W content of 0.01-5 atomic %) ensures consistent electrical properties throughout the film, enabling reliable threshold voltage control within the desired range for display applications.

Inventive Principle:
Principle #33Homogeneity

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration results in a semiconductor device with improved threshold voltage and field-effect mobility, reduced OFF current, and increased ON/OFF current ratio at low driving voltages, maintaining high mobility even at elevated temperatures.

Implementation Method 1

Japanese Patent Laying-Open No. 2008-192721 (PTD 2) discloses an oxide sintered body mainly made of indium and including tungsten, as a material suitably used when forming an oxide semiconductor film by the sputtering method and the like.

Methodology Applied
Scientific EffectSputtering: Sputtering

Data Source

PatentUS10192994B2Oxide semiconductor film including indium, tungsten and zinc and thin film transistor device
Publication Date: 2019.01.29 MITSUI MINING & SMELTING CO LTD
  • US10192994B2 patent drawing
  • US10192994B2 patent drawing
  • US10192994B2 patent drawing

AI summary

There is provided an oxide semiconductor film composed of nanocrystalline oxide or amorphous oxide, wherein the oxide semiconductor film includes indium, tungsten and zinc, a content rate of tungsten to a total of indium, tungsten and zinc in the oxide semiconductor film is higher than 0.5 atomic % and equal to or lower than 5 atomic %, and an electric resistivity is equal to or higher than 10−1 Ωcm. There is also provided a semiconductor device including the oxide semiconductor film.