Jasmonic Acid Derivative Emulsion Stability via Siloxane Elastomer

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Solution Overview

Problem

Jasmonic acid derivatives, such as sodium tetrahydrojasmonate, are challenging to formulate into stable emulsions due to their high electrolyte content and amphiphilic characteristics, leading to texture and stability issues in anti-aging compositions.

Innovation Solution

A stable anti-aging composition is developed with an aqueous phase containing at least one jasmonic acid derivative and an oil phase including dimethicone and an emulsifying crosslinked siloxane elastomer, which converts into droplets upon application of force, allowing effective penetration into keratinous substrates like skin, hair, or nails.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If high concentrations of jasmonic acid derivatives are incorporated into an emulsion, then anti-aging efficacy is improved, but phase separation occurs due to high electrolyte content and amphiphilic characteristics

Engineering Contradiction:
Improveconcentration of jasmonic acid derivativeVSAvoidemulsion stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent introduces an intermediary oil phase containing dimethicone and emulsifying crosslinked siloxane elastomer that mediates between the aqueous phase (containing jasmonic acid derivative) and the external environment. This intermediary phase prevents direct interaction between the electrolyte-containing aqueous phase and other components, thereby preventing phase separation while allowing high concentrations of jasmonic acid derivative to be carried in the aqueous phase.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the physical-chemical parameters of the emulsion system by adjusting the phase ratio (aqueous phase to oil phase from about 3 to about 12), the concentration of dimethicone (1% to 25%), and the concentration of emulsifying crosslinked siloxane elastomer (0.1% to 20%). These parameter changes optimize the balance between carrying high concentrations of jasmonic acid derivative and maintaining emulsion stability.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If the emulsion is designed to be stable and non-separating, then carry capacity for jasmonic acid derivative is improved, but tactile pleasure and water-releasing effect are reduced

Engineering Contradiction:
Improvecarry capacity for jasmonic acid derivativeVSAvoidtactile pleasure and water-releasing effect
Core Design Contradiction:
Quantity of substanceVSEase of operation

Solution Approach 1:

The patent applies dynamics by designing the emulsion to transition from a stable, non-separating state during storage and application to a water-releasing state upon mechanical stimulation. The emulsifying crosslinked siloxane elastomer enables the emulsion to maintain stability under normal conditions but release water and form droplets when subjected to shear force from rubbing or mechanical cleansing devices, thus providing both stability and tactile pleasure.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent utilizes phase transitions by designing the emulsion to remain in a stable emulsion phase during storage and initial application, then transition to a water-releasing phase containing droplets upon mechanical stimulation. This phase transition allows the emulsion to first provide stable carrier capacity and then release water and active ingredients upon user interaction, enhancing both carry capacity and tactile pleasure.

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition maintains high concentrations of jasmonic acid derivatives without phase separation, providing a tactilely pleasing texture and a transformative water-releasing effect that enhances the penetration of the active ingredients into the substrate.

Implementation Method 1

an anti-aging composition in the form of a stable emulsion... capable of carrying high amounts of jasmonic acid derivatives... without experiencing separation of the emulsion

Methodology Applied
Scientific EffectEmulsion: Emulsion

Implementation Method 2

The anti-aging composition converts from an emulsion to a plurality of droplets upon application of shear such as, for example, rubbing

Methodology Applied
Scientific EffectPhase change under shear stress:

Data Source

PatentUS9034833B1Anti-aging composition containing high levels of a jasmonic acid derivative
Publication Date: 2015.05.19 LOREAL SA
  • US9034833B1 patent drawing
  • US9034833B1 patent drawing

AI summary

A water-releasing anti-aging composition in the form of an emulsion and process for preparing the anti-aging composition are provided. The anti-aging composition includes an aqueous phase and an oil phase. The aqueous phase includes at least one electrolytic jasmonic acid derivative at a concentration by weight of about 2% to about 20%, based upon weight of the composition. The oil phase includes dimethicone at a concentration by weight of about 1% to about 25%, and an emulsifying crosslinked siloxane elastomer at a concentration by weight of about 0.1% to about 20%, both based upon weight of the composition. The anti-aging composition has a phase ratio of the aqueous phase to the oil phase of about 3.0 to about 12.0. The anti-aging composition converts from an emulsion to a plurality of droplets upon application of shear.