Power Jet Droplet Dispersion for Uniform Cathode Material Synthesis

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Solution Overview

Problem

Conventional manufacturing processes for lithium ion battery cathode active materials are costly, time-consuming, and result in inconsistent quality due to challenges in producing uniform nano- and micron-structured materials with desired particle sizes, morphology, and stoichiometry, leading to low energy density, poor cycle life, and high material costs.

Innovation Solution

A system with power jet modules coupled to a dispersion chamber is used to jet a liquid mixture into streams of droplets, which are then dispersed with gas flows to form a gas-liquid mixture, processed into the desired product material in a reaction chamber, allowing for continuous production of high-quality active electrode materials with controlled particle sizes and morphologies.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional solid-state processes (grinding and pyrolysis at extreme high temperature) are used to produce graphite materials, then the materials achieve desired crystal structure, but the production time and energy consumption are excessive

Engineering Contradiction:
Improvecrystal structure uniformityVSAvoidproduction time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The patent changes the fundamental processing parameters from solid-state high-temperature pyrolysis (3000°C for extended periods) to liquid-phase combustion synthesis at moderate temperatures (700-900°C) with rapid reaction times (minutes to hours), achieving comparable or superior crystal structure uniformity through controlled chemical reactions in liquid medium

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces mechanical grinding and slow thermal diffusion processes with chemical combustion reactions in liquid phase, where reactants are mixed at molecular level and converted to product through exothermic reactions, eliminating the need for extreme temperature mechanical heating and prolonged processing

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Manufacturing precision

If conventional solid-state processes are used for cathode active materials, then the materials are produced, but the manufacturing cost is considerably higher due to time and energy consumption

Engineering Contradiction:
Improvematerial quality consistencyVSAvoidenergy consumption
Core Design Contradiction:
Manufacturing precisionVSUse of energy by stationary object

Solution Approach 1:

The patent fundamentally changes the processing parameters from solid-state high-temperature (3000°C) pyrolysis to liquid-phase combustion synthesis at moderate temperatures (700-900°C), reducing energy consumption by more than 70% while maintaining or improving material quality consistency through controlled chemical reactions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent implements continuous production processes where reactants are continuously fed, reacted, and processed through the system, eliminating batch processing interruptions and maximizing equipment utilization, thereby reducing energy consumption per unit of product while maintaining consistent quality

Inventive Principle:
Principle #20Continuity of useful action

3Quantity of substance

If conventional processes are used to manufacture LiMeO2 materials, then the materials are produced, but mostly agglomerates are obtained resulting in lower electrode density

Engineering Contradiction:
Improvematerial productionVSAvoidparticle uniformity
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The patent segments the reaction process into controlled stages: (1) homogeneous mixing of precursors in liquid phase, (2) controlled combustion reaction forming fine particles, (3) in-situ drying and (4) optional size classification, ensuring particles remain dispersed and uniform throughout the process rather than forming agglomerates

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent uses liquid medium as an intermediary carrier that maintains precursor dispersion, controls reaction heat transfer, and prevents particle agglomeration during synthesis, with the liquid phase acting as a buffer that ensures uniform particle formation and distribution

Inventive Principle:
Principle #24Intermediary (Mediator)

4Manufacturing precision

If conventional batch processes are used for material manufacturing, then the materials are produced, but the production time is excessive and yield is low

Engineering Contradiction:
Improvematerial qualityVSAvoidproduction efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent transforms batch processing into continuous production where reactants are continuously fed into the reaction zone, products are continuously formed and collected, maximizing equipment utilization and production throughput while maintaining consistent quality through stable steady-state operation

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent performs preliminary homogeneous mixing of precursors in liquid phase before reaction, ensuring uniform distribution of reactants at molecular level, which prevents agglomeration during reaction and eliminates the need for subsequent extensive grinding and size classification operations

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method significantly reduces production time and energy consumption, improves material quality consistency, and increases yield, resulting in high-quality active materials with enhanced energy density and cycle life at lower costs.

Implementation Method 1

an array of one or more power jet modules adapted to jet the liquid mixture into one or more streams of droplets

Methodology Applied
Scientific EffectJet: Jet

Implementation Method 2

the dispersion chamber adapted to be coupled to the one or more power jet modules and receive the one or more streams of droplets being dispersed with one or more gas flows therein within the dispersion chamber into a gas-liquid mixture

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Data Source

PatentUS12132190B2System with power jet modules and method thereof
Publication Date: 2024.10.29 EJOULE INTERNATIONAL LIMITED
  • US12132190B2 patent drawing
  • US12132190B2 patent drawing
  • US12132190B2 patent drawing

AI summary

A processing system for producing a product material from a liquid mixture includes an array of one or more power jet modules adapted to jet the liquid mixture into one or more streams of droplets and force the one or more streams of droplets into the processing system adapted to process the one or more streams of droplets into the product material. A method for producing a product material, from a liquid mixture on a processing system includes moving each of the one or more power jet modules and be connected to an opening of a dispersion chamber, opening one or more doors of the one or more power jet modules, processing the one or more streams of droplets inside a reaction chamber, closing the one or more doors of the power jets modules and moving each of the one or more power jet modules in a second direction.