Jet Mixing for Cyclopentadiene Dimerization

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Solution Overview

Problem

Conventional cyclopentadiene dimerization processes are energy-intensive and inefficient, with high energy consumption due to long residence times and inadequate mixing, leading to limited conversion rates and unwanted side reactions.

Innovation Solution

A method using a jet mixer to inject a C5 hydrocarbon mixture comprising cyclopentadiene into a C5 hydrocarbon liquid in a reactor tank, allowing for efficient mixing and heat dissipation without extra cooling structures, reducing energy consumption and capital expenditure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a tubular reactor is used to provide long residence time for high conversion rate, then the conversion rate of cyclopentadiene is improved, but the reactor length and energy consumption increase significantly

Engineering Contradiction:
Improveconversion rateVSAvoidreactor length
Core Design Contradiction:
ProductivityVSLength of moving object

Solution Approach 1:

The patent replaces the conventional tubular reactor configuration with a jet mixing system where high-velocity jet streams create intense turbulence and mixing. This substitution of mechanical mixing architecture enables rapid molecular contact and reaction without requiring long residence times or extended reactor lengths, achieving high conversion rates in a compact vessel.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The jet mixing system employs periodic pulsing of jet streams to create recurring turbulence cycles. This periodic action continuously regenerates mixing intensity throughout the reactor volume, maintaining high reaction rates without requiring prolonged residence times, thereby achieving high conversion in a compact reactor configuration.

Inventive Principle:
Principle #19Periodic action

2Productivity

If a tubular reactor with long residence time is used, then the conversion rate is improved, but the energy consumption increases due to extended heating requirements

Engineering Contradiction:
Improveconversion rateVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent replaces the conventional tubular reactor configuration with a jet mixing system where high-velocity jet streams create intense turbulence and mixing. This substitution of mechanical mixing architecture enables rapid molecular contact and reaction without requiring long residence times or extended reactor lengths, achieving high conversion rates in a compact vessel.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The jet mixing system employs periodic pulsing of jet streams to create recurring turbulence cycles. This periodic action continuously regenerates mixing intensity throughout the reactor volume, maintaining high reaction rates without requiring prolonged residence times, thereby achieving high conversion in a compact reactor configuration.

Inventive Principle:
Principle #19Periodic action

3Stability of the object's composition

If impellers are used to mix the liquid in the reactor, then mixing is provided, but the energy consumption increases and hot spots are formed

Engineering Contradiction:
Improvemixing efficiencyVSAvoidenergy consumption
Core Design Contradiction:
Stability of the object's compositionVSUse of energy by moving object

Solution Approach 1:

The patent replaces conventional impeller-based mechanical mixing with a jet mixing system. High-velocity jet streams injected into the reactor create intense turbulence and chaotic flow patterns that achieve superior mixing efficiency. This substitution eliminates the need for energy-intensive impellers while preventing hot spot formation through more uniform heat distribution via turbulent mixing.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Stability of the object's composition

If impellers are used to mix the liquid, then mixing action is provided, but the mixing is insufficient and hot spots are formed

Engineering Contradiction:
Improvemixing efficiencyVSAvoidtemperature uniformity
Core Design Contradiction:
Stability of the object's compositionVSTemperature

Solution Approach 1:

The patent replaces conventional impeller-based mechanical mixing with a jet mixing system. High-velocity jet streams injected into the reactor create intense turbulence and chaotic flow patterns that achieve superior mixing efficiency. This substitution eliminates the need for energy-intensive impellers while preventing hot spot formation through more uniform heat distribution via turbulent mixing.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly reduces energy consumption, improves mixing efficiency, and minimizes side reactions by maintaining uniform temperature distribution, achieving higher conversion rates of cyclopentadiene to dicyclopentadiene while reducing operating costs.

Implementation Method 1

injecting the C5 hydrocarbon mixture stream as a jet stream into C5 hydrocarbon liquid in the tank at a velocity in a range of 1 m/s to 10 m/s... The injecting causes mixing of the C5 hydrocarbon mixture stream and the C5 hydrocarbon liquid

Methodology Applied
Scientific EffectTurbulent mixing: Turbulence

Implementation Method 2

the exothermic heat generated by the dimerization reaction can be quickly dissipated with low energy consumption

Methodology Applied
Scientific EffectHeat dissipation: Convection

Implementation Method 3

the C5 hydrocarbon liquid in the tank can be used as the heat sink medium without need of extra cooling structures

Methodology Applied
Scientific EffectHeat sink: Heat Sink

Implementation Method 4

dimerization of cyclopentadiene to form dicyclopentadiene... under reaction conditions sufficient to dimerize the cyclopentadiene to form dicyclopentadiene. The reaction conditions include a reaction temperature of between 40 °C to 130 °C

Methodology Applied
Scientific EffectDimerization reaction: Chemical Bonding

Implementation Method 5

the exothermic heat generated by the dimerization reaction

Methodology Applied
Scientific EffectExothermic reaction: Exothermic Reaction

Data Source

PatentEP3802468B1Dimerization of cyclopentadiene using reactive jet mixing
Publication Date: 2024.12.18 SABIC GLOBAL TECHNOLOGIES BV
  • EP3802468B1 patent drawingFigure 1
  • EP3802468B1 patent drawingFigure 2A~2B
  • EP3802468B1 patent drawingFigure 3~4

AI summary

Systems and methods for producing dicyclopentadiene from cyclopentadiene using reactive jet mixing are disclosed. A C5 hydrocarbon mixture that comprises cyclopentadiene (C5H6) is injected as a jet stream into C5 hydrocarbon liquid in a reactor tank. Under appropriate reaction conditions, cyclopentadiene is dimerized to form dicyclopentadiene.