Jettable Solder Resist Composition for High-Temperature PCB Printing

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Solution Overview

Problem

Existing inkjet printing technologies for solder masks on printed circuit boards face limitations due to ink viscosity restrictions, which affect the choice of components and film thickness, and UV-curable inks struggle with compatibility with high-temperature soldering processes while maintaining physical properties.

Innovation Solution

A jettable composition comprising reactive monomers or prepolymers with epoxy or oxetane functional groups, free radical polymerizable compounds, thermal cross-linking agents like blocked isocyanates, and radical initiators, which are photocurable and thermosetting, allowing for higher viscosity inks suitable for inkjet printing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the viscosity of inkjet solder mask composition is increased to improve film thickness and mechanical properties, then the ink can no longer be deposited using conventional inkjet printheads which require low viscosity (5-15 mPa·s)

Engineering Contradiction:
Improvemechanical propertiesVSAvoidinkjet depositability
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent changes the chemical composition parameters of the ink by incorporating epoxy or oxetane functional groups with specific molecular structures that provide both adequate viscosity for jetting and the required mechanical properties after curing. The composition includes reactive diluents that adjust viscosity while maintaining curability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite ink composition combining multiple components: epoxy/oxetane functional groups, free radical polymerizable compounds, thermal cross-linking agents, and radical initiators. This composite approach allows the ink to exhibit both jettable flow characteristics and cured mechanical strength.

Inventive Principle:
Principle #40Composite materials

2Reliability

If UV curable inks are used to achieve rapid cure and high crosslinking density, then chemical resistance and mechanical properties improve, but compatibility with high temperature soldering processes becomes difficult to maintain

Engineering Contradiction:
Improvechemical resistanceVSAvoidsoldering process compatibility
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent merges UV curability with thermal cross-linking capability in a single composition. The ink contains both photopolymerizable groups for rapid UV curing and epoxy/oxetane groups with thermal cross-linking agents for high-temperature stability during soldering. This combination allows the coating to withstand soldering temperatures while maintaining chemical resistance.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent applies a preliminary UV cure to form a protective layer before the soldering process, then uses the thermal cross-linking components to further strengthen the coating during the high-temperature soldering step. This sequential curing approach ensures both chemical resistance and temperature compatibility.

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If conventional photolithographic developing processes are used to ensure precise patterning, then manufacturing precision is maintained, but the number of process steps and materials required increases

Engineering Contradiction:
Improvepatterning precisionVSAvoidnumber of process steps
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent extracts the patterning function from the complex photolithographic process by using inkjet printing to directly deposit the solder mask composition in the desired pattern. This eliminates the need for separate photoresist application, photolithographic exposure, and developing steps, reducing overall process complexity while maintaining precision through digital control.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition enables efficient deposition of solder resist with improved film thickness and mechanical properties, ensuring compatibility with high-temperature soldering processes and maintaining chemical resistance.

Implementation Method 1

a free radical polymerizable compound; and a radical initiator

Methodology Applied
Scientific EffectFree radical polymerization: Photopolymerisation

Implementation Method 2

UV curable inks are preferred for the design of solder mask inks as they allow rapid cure and a high degree of crosslinking

Methodology Applied
Scientific EffectPhotocuring: Photopolymerisation

Implementation Method 3

a thermal cross-linking agent comprising an isocyanate compound

Methodology Applied
Scientific EffectThermal cross-linking: Chemical Bonding

Data Source

PatentEP3887454B1Jettable composition
Publication Date: 2026.01.28 ELECTRA POLYMER LTD
  • EP3887454B1 patent drawing

AI summary

A jettable composition is described, comprising a reactive monomer, oligomer or prepolymer containing at least one epoxy or oxetane functional group; a free radical polymerizable compound; a thermal cross-linking agent; and a radical initiator, along with an electronic device having the composition jetted thereon and a method of manufacturing an electronic device.