Joule Heating Bonding for Lithium Metal Anode Adhesion

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Solution Overview

Problem

Existing methods for manufacturing battery cell electrodes, particularly for electric vehicles, face challenges in creating a strong bond between metal electrode layers and current collectors, which is crucial for lithium metal anodes to withstand vehicle use.

Innovation Solution

The method involves using rollers with different materials to apply joule heating, causing current to flow through the metal electrode and current collector layers, resulting in localized heating that softens the metal and enhances bonding quality, allowing for improved adhesion and reduced rolling force or increased speed.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional bonding methods are used to bond metal electrode layers to current collectors, then the bonding process is simple and quick, but the bond strength is insufficient for lithium metal anodes to withstand vehicle use

Engineering Contradiction:
Improvebond strengthVSAvoidbonding process complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by transitioning from conventional cold bonding to hot rolling with temperatures exceeding the recrystallization temperature of the metal electrode layer. This temperature parameter change enables metallurgical bonding and significantly enhances bond strength between the lithium metal anode and current collector, making the electrode structure capable of withstanding vehicle use conditions.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes phase transitions by heating the metal electrode layer above its recrystallization temperature during the bonding process. This phase transition enables the metal to undergo recrystallization and metallurgical bonding with the current collector, creating a strong, durable bond that conventional room-temperature methods cannot achieve.

Inventive Principle:
Principle #36Phase transitions

2Strength

If hot rolling is used to bond metal electrode layers, then bond strength is improved, but energy consumption increases due to heating requirements

Engineering Contradiction:
Improvebond strengthVSAvoidenergy consumption
Core Design Contradiction:
StrengthVSUse of energy by moving object

Solution Approach 1:

The patent replaces conventional external heating systems with inductive heating that generates heat directly within the metal electrode layer through electromagnetic induction. This substitution of heating mechanism reduces energy loss and improves heating efficiency, thereby reducing overall energy consumption while achieving the required bond strength through hot rolling.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a stronger bond between the metal electrode and current collector layers, enhancing the durability and performance of lithium metal anode electrodes in battery cells.

Implementation Method 1

supplying current through the first roller, the first metal electrode layer, the current collector layer, and the second roller to cause joule heating and bonding of the first metal electrode layer, the current collector layer, and the second metal electrode layer

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Data Source

PatentUS20240304781A1Resistance heated roll-bonding of a lithium to a current collector layer
Publication Date: 2024.09.12 GM GLOBAL TECHNOLOGY OPERATIONS LLC
  • US20240304781A1 patent drawing
  • US20240304781A1 patent drawing
  • US20240304781A1 patent drawing

AI summary

A method for bonding a metal electrode layer and a current collector includes supplying a first metal electrode layer, a current collector layer, and a second metal electrode layer for a battery cell between a first roller and a second roller; connecting a power supply to the first roller and the second roller; and supplying current through the first roller, the first metal electrode layer, the current collector layer, and the second metal electrode layer and the second roller to cause joule heating and bonding of the first metal electrode layer, the current collector layer, and the second metal electrode layer.