Corrosion Test Method Using Kaolinite Electrolyte

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Solution Overview

Problem

Current corrosion resistance test methods for coated metal materials are time-consuming and lack reliability in evaluating the performance of coating films on steel sheets under different baking conditions, making it difficult to rapidly optimize coating conditions and assess rust prevention for vehicles.

Innovation Solution

A corrosion resistance test method involving a water-containing material with a mixture of water, an electrolyte, and kaolinite, where electrodes are connected to a coated metal material to supply current, accelerating the corrosion process by controlling temperature and measuring the expansion of the surface treatment film to assess corrosion reliability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional accelerated corrosion test methods (combined cycle test, salt spray test) are used, then corrosion resistance can be evaluated, but the evaluation process takes several months which is too time-consuming for rapid optimization of coating conditions

Engineering Contradiction:
Improvecorrosion resistance evaluation reliabilityVSAvoidevaluation time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The invention changes the chemical composition parameters of the electrolyte material by incorporating specific concentrations of hydrogen peroxide (5-20 mass%) and nitric acid (0.1-5 mass%), along with controlling pH (1-3) and temperature (20-80°C). These parameter modifications accelerate the corrosion reaction rate while maintaining evaluation reliability, reducing test time from several months to a practical duration.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite electrolyte material combining multiple chemical components (hydrogen peroxide, nitric acid, water, and optional additives) to create a synergistic corrosion environment. This composite electrolyte solution provides both strong oxidizing power for accelerated corrosion and controlled chemistry for reliable evaluation, achieving fast yet accurate corrosion resistance assessment.

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional corrosion test methods are used, then corrosion evaluation can be performed, but the results lack sufficient reliability for assessing coating films under different baking conditions

Engineering Contradiction:
Improvecoating condition optimization speedVSAvoidevaluation result reliability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The invention optimizes multiple parameters simultaneously: electrolyte composition (hydrogen peroxide 5-20 mass%, nitric acid 0.1-5 mass%), pH control (1-3), and temperature range (20-80°C). These parameter adjustments create a standardized accelerated corrosion environment that produces reliable, reproducible results for comparing coating films under different baking conditions, enabling rapid and trustworthy coating condition optimization.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If standard electrolyte materials are used in corrosion testing, then the test can be performed, but the corrosion process progresses too slowly to achieve rapid evaluation

Engineering Contradiction:
Improvecorrosion evaluation reliabilityVSAvoidcorrosion process acceleration
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The invention dramatically changes the electrolyte's chemical aggressiveness by introducing hydrogen peroxide (5-20 mass%) as a strong oxidant and nitric acid (0.1-5 mass%) for pH control and additional oxidation. This transforms a slow conventional corrosion process into a rapidly progressing reaction while maintaining controlled conditions for reliable evaluation through standardized composition and temperature control.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention employs hydrogen peroxide and nitric acid as strong oxidizing agents to accelerate the corrosion process. These oxidants enhance the electrochemical corrosion reactions at the coating-metal interface, significantly increasing the corrosion rate and enabling rapid evaluation while maintaining reproducible results through controlled concentrations and pH levels.

Inventive Principle:
Principle #38Strong oxidants (Accelerated oxidation)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables a faster and more reliable evaluation of corrosion resistance by accelerating the corrosion process, allowing for quicker optimization of coating conditions and improved quality control in coating factories and vehicle rust prevention.

Implementation Method 1

the water-containing material penetrates into the surface treatment film

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

electrodes to be in contact with the water-containing material contained in the one water-containing material holder or in each of the water-containing material holders, and electrically connecting, with an external circuit, between the one electrode and the metal base, or between the electrodes; and supplying a current between the one electrode and the metal base, or between at least one of the electrodes and at least one of the other electrodes, as an anode and a cathode, respectively to bring corrosion of the coated metal material to progress

Methodology Applied
Scientific EffectElectrochemical corrosion: Electrolysis

Data Source

PatentUS11860081B2Corrosion resistance test method for coated metal material and water-containing material for use therein
Publication Date: 2024.01.02 MAZDA MOTOR CORP
  • US11860081B2 patent drawing
  • US11860081B2 patent drawing
  • US11860081B2 patent drawing

AI summary

A corrosion resistance test method for a coated metal material that includes a metal base and a surface treatment film, includes the steps of: disposing one or more water-containing material holders each holding a water-containing material to be in contact with the surface treatment film and one or more electrodes to be in contact with the water-containing material, and electrically connecting, with an external circuit, between the one electrode and the metal base, or between the electrodes; and supplying a current between the one electrode and the metal base, or between at least one of the electrodes and at least one of the other electrodes, as an anode and a cathode, to bring corrosion of the coated metal material to progress. The water-containing material comprises water, an electrolyte material, and kaolinite, and comprises the kaolinite at 36.0 mass % or more to 45.0 mass % or less.