Ketone-Based Cleaning Composition for Semiconductor Adhesive Residue Removal

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Solution Overview

Problem

The increasing density of electrode terminals in semiconductor devices requires effective methods to maintain electrical characteristics during substrate processing, particularly in removing adhesive residues without damaging solder balls or pads.

Innovation Solution

A cleaning composition comprising a solvent with a ketone compound content of 40 wt % to 90 wt %, quaternary ammonium salt, and primary amine is applied to semiconductor substrates to efficiently remove adhesive layer residues, preventing damage to solder balls and pads.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional cleaning methods are used to remove adhesive residues, then the adhesive layer can be removed, but solder balls and pads may be damaged

Engineering Contradiction:
Improveadhesive residue removal qualityVSAvoiddamage to solder balls and pads
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the cleaning composition by specifying precise proportions of ketone compounds (40-90 wt%), quaternary ammonium salts (5-60 wt%), and primary amines (5-60 wt%). This optimized composition achieves effective adhesive removal while preventing damage to sensitive components like solder balls and pads, resolving the contradiction between cleaning effectiveness and component safety

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The cleaning composition uses a composite chemical formulation combining ketone compounds, quaternary ammonium salts, and primary amines in specific ratios. This composite approach leverages the synergistic effects of different chemical components to achieve both thorough adhesive residue removal and protection of solder balls and pads, eliminating the need for harsh conventional cleaners

Inventive Principle:
Principle #40Composite materials

2Productivity

If the number of electrode terminals is increased and pitch is reduced, then device integration is improved, but maintaining electrical characteristics during processing becomes more difficult

Engineering Contradiction:
Improvedevice integration densityVSAvoidelectrical characteristics maintenance
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent controls the chemical parameters of the cleaning composition (ketone 40-90 wt%, quaternary ammonium salt 5-60 wt%, primary amine 5-60 wt%) to achieve optimal cleaning effectiveness. This precise parameter control allows for complete adhesive removal without damaging the densely packed electrode terminals and pads, thereby maintaining electrical characteristics while supporting high integration density

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The cleaning composition creates a controlled chemical environment that mimics ideal cleaning conditions - effective enough to remove all adhesive residues but gentle enough to preserve the integrity of densely packed electrical components. This balanced approach enables processing of high-density interconnect structures without compromising electrical performance

Inventive Principle:
Principle #26Copying

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The cleaning composition effectively removes adhesive residues, improving the yield of semiconductor devices by maintaining electrical characteristics and preventing damage to sensitive components.

Implementation Method 1

a solvent including a ketone compound and having a content that is equal to or greater than 40 wt % and less than 90 wt %

Methodology Applied
Scientific EffectDissolution: Solvation

Implementation Method 2

quaternary ammonium salt, and primary amine

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS11380537B2Method of manufacturing a semiconductor device and a cleaning composition for an adhesive layer
Publication Date: 2022.07.05 SAMSUNG ELECTRONICS CO LTD
  • US11380537B2 patent drawing
  • US11380537B2 patent drawing
  • US11380537B2 patent drawing

AI summary

Embodiments of the inventive concepts provide a method of manufacturing a semiconductor device and a cleaning composition for an adhesive layer. The method includes preparing a semiconductor substrate to which an adhesive layer adheres, removing the adhesive layer from the semiconductor substrate, and applying a cleaning composition to the semiconductor substrate to remove a residue of the adhesive layer. The cleaning composition includes a solvent including a ketone compound and having a content that is equal to or greater than 40 wt % and less thaadminn 90 wt %, quaternary ammonium salt, and primary amine.