Stable Ketoprofen Amitriptyline Oxymetazoline Injection Formulations

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Solution Overview

Problem

Conventional pharmaceutical irrigation fluids lack analgesic and anti-inflammatory effects, and stable liquid formulations of ketoprofen, amitriptyline, and oxymetazoline are challenging due to solubility and stability issues, particularly in aqueous solutions where these drugs are prone to chemical degradation.

Innovation Solution

The development of stable liquid pharmaceutical formulations of ketoprofen, amitriptyline, and oxymetazoline that include 1-99% polyol, 10-500 mM sodium citrate, and a pH of 4.5-7.0, with polyethylene glycol (PEG) as a preferred polyol, and the addition of sodium ethylenediamine tetraacetic acid (EDTA) to enhance stability, allowing for prolonged storage without significant degradation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional physiologic irrigation fluids are used, then the surgical site can be irrigated, but the fluids do not provide analgesic or anti-inflammatory effects

Engineering Contradiction:
Improvetherapeutic efficacyVSAvoidfunctional capability
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent combines multiple therapeutic agents (ketoprofen, amitriptyline, and oxymetazoline) with physiologic irrigation fluid to create a multi-functional solution that provides both irrigation and therapeutic effects (analgesic and anti-inflammatory) simultaneously, eliminating the need for separate medication administration

Inventive Principle:
Principle #5Merging (Combining)

2Reliability

If lyophilized drug combination is reconstituted and used in dilute irrigation solution, then therapeutic benefits are achieved, but the formulation is complex and requires multiple steps

Engineering Contradiction:
Improvetherapeutic benefitVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent pre-formulates the therapeutic agents in a stable concentrated liquid solution with appropriate solvents and stabilizers, allowing the solution to be stored ready-to-use and simply diluted with irrigation fluid during surgery, eliminating the need for lyophilization and reconstitution steps

Inventive Principle:
Principle #10Preliminary action

3Stability of the object's composition

If stable liquid formulations of ketoprofen, amitriptyline, and oxymetazoline are developed, then solubility and shelf life are improved, but formulation stability is challenging due to chemical degradation

Engineering Contradiction:
Improveshelf lifeVSAvoidchemical stability
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent uses stabilizers and appropriate pH buffers as intermediary substances that protect the therapeutic agents from chemical degradation, oxidation, and hydrolysis, maintaining formulation stability and preventing drug decomposition during storage

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent optimizes formulation parameters including pH level, solvent composition, and stabilizer concentration to create a chemical environment that minimizes drug degradation and maintains long-term stability of the liquid formulation

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The formulations maintain stability for at least six months to several years at temperatures ranging from 2°C to 30°C, significantly improving the solubility and shelf life of the drugs compared to lyophilized forms, ensuring effective anti-inflammatory and analgesic action during surgical and therapeutic procedures.

Implementation Method 1

The formulations include 1-99% polyol, and 10-500 mM sodium citrate at a pH of 4.5-7.0

Methodology Applied
Scientific EffectSolvation: Solvation

Implementation Method 2

10-500 mM sodium citrate at a pH of 4.5-7.0

Methodology Applied
Scientific EffectpH buffering:

Implementation Method 3

the addition of sodium ethylenediamine tetraacetic acid (EDTA) to enhance stability

Methodology Applied
Scientific EffectChelation:

Data Source

PatentEP2739266B1Stable Anti-inflammatory solutions for injection
Publication Date: 2016.07.27 OMEROS CORP
  • EP2739266B1 patent drawingFigure 1A
  • EP2739266B1 patent drawingFigure 1B
  • EP2739266B1 patent drawingFigure 2A

AI summary

The present invention relates to stable liquid formulations of ketoprofen, amitriptyline, and oxymetazoline.