L-ascorbic Acid Stability via Vitis Vinifera Extract Mediators

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Solution Overview

Problem

L-ascorbic acid solutions are unstable in aqueous solutions due to oxidation, limited solubility, and rapid decomposition, which hinders its effective use in medical and cosmetic applications.

Innovation Solution

Compositions comprising L-ascorbic acid combined with Vitis Vinifera extract, resveratrol, melatonin, and polyphenols, along with polymeric ethers and thiosulfates, enhance stability and bioavailability, allowing for higher concentrations and improved intracellular penetration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If L-ascorbic acid is dissolved in aqueous solution, then it becomes soluble and bioavailable, but it quickly oxidizes and decomposes

Engineering Contradiction:
Improvesolubility of L-ascorbic acidVSAvoidstability of L-ascorbic acid
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent introduces oxygen-scavenging compounds (such as vitamin E, ferulic acid, or other antioxidants) as intermediary substances that protect L-ascorbic acid from oxidation by reacting with oxygen or free radicals first. This mediator approach allows L-ascorbic acid to remain stable in aqueous solution without immediate decomposition

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite formulation combining L-ascorbic acid with stabilizing agents, penetration enhancers, and other functional components. This composite approach allows the system to simultaneously achieve solubility, stability, and bioavailability that individual components cannot provide alone

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If L-ascorbic acid concentration is increased for better efficacy, then therapeutic effect improves, but oxidation and decomposition accelerate

Engineering Contradiction:
Improveconcentration of L-ascorbic acidVSAvoidstability of high concentration solution
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

Oxygen-scavenging compounds are incorporated at specific concentrations to protect high levels of L-ascorbic acid from oxidation. These intermediaries create a protective environment that enables higher stable concentrations of vitamin C in the formulation

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies solution parameters such as pH level, ionic strength, and presence of chelating agents to create conditions where high concentrations of L-ascorbic acid remain stable. By controlling these parameters, the formulation maintains both high concentration and reliability

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If L-ascorbic acid is stabilized in non-aqueous solvents, then stability improves, but intracellular penetration decreases

Engineering Contradiction:
Improvestability of L-ascorbic acidVSAvoidintracellular penetration
Core Design Contradiction:
Stability of the object's compositionVSEase of operation

Solution Approach 1:

The patent adjusts the pH of the aqueous solution to match or be slightly lower than the pH of skin and biological tissues. This pH optimization enhances both stability and penetration, as the protonated form of L-ascorbic acid at lower pH has better membrane permeability while remaining stable in the formulation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

Penetration enhancers such as fatty acids, surfactants, or other membrane-active compounds are introduced as intermediaries that facilitate the transport of L-ascorbic acid across cell membranes. These mediators temporarily interact with the membrane structure to allow vitamin C entry without compromising the stability of the aqueous formulation

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The combination stabilizes L-ascorbic acid, increasing its efficiency and bioavailability, providing antioxidant, anti-inflammatory, and anti-aging benefits, while promoting collagen synthesis and wound healing.

Implementation Method 1

L-ascorbic acid is readily soluble in water, but it quickly oxidises in aqueous solutions

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentEP2362778B1Compositions comprising vitamin c
Publication Date: 2018.02.07 TUTINO MARCO
  • EP2362778B1 patent drawingFigure 1
  • EP2362778B1 patent drawingFigure 2~3
  • EP2362778B1 patent drawingFigure 4~5

AI summary

Compositions according to the invention comprise one or more vitamins and/or hormones and/or alpha arbutine and/or their derivatives in association with an Vitis Vinifera extract, preferably an aqueous extract, and/or one or more of its components, such as resveratrol, polyphenols and anthocyanidine, and/orionene polimers, along with one or more adjuvants and/or excipients pharmaceutically or cosmetically acceptable.