Label-Free Raman Imaging Beyond Microscopic Scales

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Solution Overview

Problem

Conventional Raman scattering-based techniques are limited to microscopic scales due to high autofluorescence background and require labeling, which is not suitable for mesoscopic or macroscopic applications, especially in biological tissues.

Innovation Solution

An imaging system using illumination light with a wavelength of at least 810nm and a detector capable of detecting light in the range of 950nm to 2500nm, allowing for Raman imaging on a mesoscopic or macroscopic scale without labeling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Area of stationary object

If conventional Raman scattering-based techniques are used, then molecular identification is achieved, but the imaging is limited to microscopic scales due to high autofluorescence background

Engineering Contradiction:
Improveimaging areaVSAvoidautofluorescence background
Core Design Contradiction:
Area of stationary objectVSObject-generated harmful factors

Solution Approach 1:

The patent changes the illumination wavelength parameter from conventional visible/near-infrared ranges to specifically at least 810nm (extending to 2000nm or beyond). This parameter change exploits the fact that autofluorescence background decreases at longer wavelengths, allowing Raman scattering to become distinguishable from background at macroscopic scales without requiring labeling

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If labeling techniques are used for molecular identification, then detection sensitivity is improved, but the object may be damaged or altered

Engineering Contradiction:
Improvedetection sensitivityVSAvoidobject damage
Core Design Contradiction:
Measurement precisionVSObject-affected harmful factors

Solution Approach 1:

The patent enables the object to serve itself by detecting its own intrinsic Raman scattering signal without requiring external labels or stains. The endogenous chemical contrast from the object's own molecular bonds provides the necessary detection sensitivity, eliminating the need for labeling procedures that could damage or alter the object

Inventive Principle:
Principle #25Self-service

3Area of stationary object

If wide-field Raman imaging is attempted, then macroscopic imaging is achieved, but the Raman signal is drowned out by elevated autofluorescence background

Engineering Contradiction:
Improvefield of viewVSAvoidsignal to noise ratio
Core Design Contradiction:
Area of stationary objectVSMeasurement precision

Solution Approach 1:

The patent changes the wavelength parameter to at least 810nm (extending to 2000nm or beyond), which simultaneously achieves wide-field illumination and improves signal-to-noise ratio. At these longer wavelengths, autofluorescence background is significantly reduced while Raman scattering remains detectable, enabling macroscopic imaging with sufficient chemical contrast

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables label-free imaging of biological tissues and objects at mesoscopic or macroscopic scales with improved Raman-to-autofluorescence contrast, overcoming the limitations of conventional Raman microscopy.

Implementation Method 1

an illumination light source configured to illuminate an area of the object; wherein light emitted by the illumination light source has a wavelength of at least 810nm

Methodology Applied
Scientific EffectLight emission: Light

Implementation Method 2

a detector configured to detect an image based on Raman scattered light from the object

Methodology Applied
Scientific EffectRaman scattering: Scattering

Implementation Method 3

Raman scattering-based techniques are based entirely on the endogenous chemical contrast without the need for labelling techniques... This method is based on detecting light from Raman scattering, an inelastic scattering process in which energy is exchanged between incident photons and the scattering object

Methodology Applied
Scientific EffectRaman scattering:

Data Source

PatentEP4636391A1Imaging system and method for imaging
Publication Date: 2025.10.22 HELMHOLTZ ZENT MUENCHEN DEUT FORSCHUNGSZENTRUM FUER GESUNDHEIT & UMWELT (GMBH)
  • EP4636391A1 patent drawingFigure 1
  • EP4636391A1 patent drawingFigure 2
  • EP4636391A1 patent drawingFigure 3

AI summary

Provided is an imaging system for imaging an object, the imaging system comprising: an illumination light source configured to illuminate an area of the object; and a detector configured to detect an image based on Raman scattered light from the object, wherein light emitted by the illumination light source has a wavelength of at least 810nm. Further provided is a method for imaging an object, the method comprising the steps of illuminating an area of the object using illumination light; and detecting an image based on Raman scattered light from the object, wherein the illumination light has a wavelength of at least 810nm.