pH-Stable Laccase for Melanoidin Degradation

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Solution Overview

Problem

Current household detergents face challenges in effectively removing stubborn stains caused by melanoidins and phenolic organic compounds from dense surfaces, such as fabrics and tooth enamel, due to pH sensitivity and incompatibility with proteases, leading to incomplete stain removal and color damage.

Innovation Solution

A biotechnology based on laccase from Aspergillus spp., which is stable across a pH range of 3.0-8.0 and compatible with proteases, is used to degrade melanoidins and phenolic organic compounds, ensuring effective stain removal without damaging the surface color.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If laccase is used to remove melanoidin stains, then stain removal efficiency is improved, but laccase activity is reduced due to pH sensitivity

Engineering Contradiction:
Improvestain removal efficiencyVSAvoidlaccase activity stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent modifies the operating pH parameter from conventional acidic conditions (pH 3-5) to neutral or slightly alkaline conditions (pH 7-9), enabling laccase to maintain high activity for melanoidin degradation while ensuring compatibility with proteases and effectiveness in typical household detergent environments

Inventive Principle:
Principle #35Parameter changes

2Productivity

If laccase is used for stain removal, then cleaning efficiency is improved, but compatibility with proteases is reduced

Engineering Contradiction:
Improvecleaning efficiencyVSAvoidenzyme compatibility
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

By shifting the pH regime to neutral or slightly alkaline conditions, the patent resolves the incompatibility between laccase and proteases that occurs at acidic pH, allowing both enzymes to coexist and function synergistically in the same detergent formulation

Inventive Principle:
Principle #35Parameter changes

3Productivity

If strong oxidants are used to remove stains, then stain removal capability is improved, but color damage to surfaces occurs

Engineering Contradiction:
Improvestain removal capabilityVSAvoidcolor damage
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent employs laccase, a copper-containing oxidase enzyme, which catalyzes the oxidation of melanoidins through controlled electron transfer. This enzymatic oxidation achieves effective stain removal while being inherently milder than chemical oxidants like hydrogen peroxide or sodium hypochlorite, thus preserving the color and integrity of treated surfaces

Inventive Principle:
Principle #38Strong oxidants (Accelerated oxidation)

Solution Approach 2:

The patent replaces aggressive chemical oxidation mechanisms with enzymatic catalysis, substituting harsh chemical oxidants with a biologically derived enzyme that achieves similar or superior stain removal through selective biochemical pathways, thereby reducing harmful effects on surface materials

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The laccase-based biotechnology achieves targeted degradation of complex biological contaminants, maintaining the color and appearance of dense surfaces, even in cold water conditions, and is compatible with various household detergent components, enhancing cleaning efficiency and dermatological safety.

Implementation Method 1

laccase from Aspergillus spp., which is stable across a pH range of 3.0-8.0 and compatible with proteases, is used to degrade melanoidins and phenolic organic compounds

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentEP4385491A1Ph-stable biotechnology composition based on laccase for targeted degradation of coloured melanoidines and/or phenolic organic compounds on dense surfaces
Publication Date: 2024.06.19 SKYLAB AG
  • EP4385491A1 patent drawingFigure 1
  • EP4385491A1 patent drawingFigure 2
  • EP4385491A1 patent drawingFigure 3

AI summary

The invention relates to a composition comprising laccase and optionally a serine protease and the use of said composition in the treatment of melanoidins and/or phenolic organic compounds, e.g. as a laundry washing composition, cleaning composition, whitening cosmetic composition.