Lactide Production via Volatile Solvent Evaporation

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Solution Overview

Problem

Current methods for manufacturing lactide are inefficient and costly, with conventional processes requiring multiple steps such as polymerization, depolymerization, and purification, which can lead to the formation of undesired side products and lower reaction rates.

Innovation Solution

A method involving the use of a solution of lactic acid in a volatile organic solvent, such as C2-C10 ketones or C2-C10 ethers, where the solvent is evaporated to form lactic acid oligomers, followed by the addition of a catalyst to convert them into lactide, bypassing traditional back-extraction and distillation steps.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional polymerization and depolymerization steps are used to manufacture lactide, then lactide can be produced, but the process is inefficient and costly with lower reaction rates

Engineering Contradiction:
Improvereaction rateVSAvoidprocess complexity
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The invention extracts and eliminates the unnecessary back-extraction and distillation steps from the conventional lactide manufacturing process. By using a volatile organic solvent that can be directly evaporated, the process removes the complex purification steps while maintaining product quality, thereby improving reaction efficiency and reducing manufacturing complexity

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the physical state and composition parameters by using a volatile organic solvent system instead of conventional aqueous systems. This parameter change enables direct evaporation of the solvent to form lactic acid oligomers, which then undergo cyclization more efficiently, significantly improving the reaction rate and simplifying the overall process

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If conventional processes with multiple steps are used, then lactide can be manufactured, but extensive equipment and processing costs are incurred

Engineering Contradiction:
Improvecost effectivenessVSAvoidequipment requirements
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The invention extracts and eliminates the unnecessary back-extraction and distillation steps from the conventional lactide manufacturing process. By using a volatile organic solvent that can be directly evaporated, the process removes the complex purification steps while maintaining product quality, thereby improving reaction efficiency and reducing manufacturing complexity

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention merges the solvent removal and oligomer formation steps into a single evaporation process. The volatile organic solvent serves multiple functions: it dissolves lactic acid, facilitates oligomerization upon evaporation, and can be easily removed without requiring separate purification equipment, thereby reducing device complexity and processing costs

Inventive Principle:
Principle #5Merging (Combining)

3Manufacturing precision

If conventional methods are used, then lactide is produced, but undesired side products are formed and optical purity is reduced

Engineering Contradiction:
Improveoptical purityVSAvoidside products
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The invention changes the physical state and composition parameters by using a volatile organic solvent system instead of conventional aqueous systems. This parameter change enables direct evaporation of the solvent to form lactic acid oligomers, which then undergo cyclization more efficiently, significantly improving the reaction rate and simplifying the overall process

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention converts the potential harm of solvent residue into a benefit by selecting a volatile organic solvent that evaporates completely during the heating process. The volatility that could have been a disadvantage becomes an advantage, ensuring complete solvent removal and preventing side reactions, thereby maintaining high optical purity and minimizing side product formation

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process results in a higher reaction rate, reduced formation of side products, and cost savings by eliminating the need for extensive equipment and processing costs, while maintaining high optical purity of the lactide produced.

Implementation Method 1

subjecting the solution to an evaporation step to remove volatile organic solvent and water, resulting in the formation of a composition comprising lactic acid oligomer

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

adding catalyst to the composition comprising lactic acid oligomer, and bringing the mixture to reaction conditions, to form lactide

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentEP3256460B1Method for manufacturing lactide
Publication Date: 2022.08.03 PURAC BIOCHEM BV
  • EP3256460B1 patent drawingFigure 1~2
  • EP3256460B1 patent drawing

AI summary

The invention pertains to a method for producing lactide comprising the steps of - providing a solution of lactic acid in a volatile organic solvent, - subjecting the solution to an evaporation step to remove volatile organic solvent and water, resulting in the formation of a composition comprising lactic acid oligomer, - adding catalyst to the composition comprising lactic acid oligomer, and bringing the mixture to reaction conditions, to form lactide. It has been found that the process according to the invention results in the efficient production of lactide with a high production rate and a good product quality.