Lactoferrin Thermal Stabilization via Nucleic Acid Complex

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Solution Overview

Problem

Lactoferrin is unstable to heat, particularly in neutral pH conditions, leading to denaturation and loss of physiological activities, which complicates its use in food and pharmaceutical products that require heat sterilization, and existing stabilization methods either alter product pH or require large amounts of stabilizers, affecting product properties.

Innovation Solution

The addition of a nucleic acid, such as DNA or RNA derived from soft roe, and a small amount of metal like copper to lactoferrin improves its heat stability, allowing for heat sterilization without denaturation, even in neutral pH conditions, using a mass ratio of nucleic acid to lactoferrin between 0.09 and 6.3 and a molar ratio of metal to lactoferrin between 0.04 and 3.0.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If lactoferrin is subjected to heat sterilization at neutral pH, then sterilization is achieved, but lactoferrin denatures and loses physiological activities

Engineering Contradiction:
Improvesterilization effectivenessVSAvoidlactoferrin structure stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

Nucleic acid acts as an intermediary substance that mediates between heat sterilization and lactoferrin stability. The nucleic acid forms a protective complex with lactoferrin, allowing heat sterilization to proceed while the nucleic acid shield prevents denaturation of the lactoferrin structure.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention creates a composite system consisting of nucleic acid and lactoferrin in specific mass ratios (0.01-10). This composite material combines the heat resistance properties of nucleic acid with the physiological functions of lactoferrin, achieving both sterilization and protein stability simultaneously.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If pH is adjusted to acidic range (1.0-6.5) to stabilize lactoferrin, then heat stability is improved, but product pH requirements are not met and production process becomes complicated

Engineering Contradiction:
Improvelactoferrin heat stabilityVSAvoidproduction process complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

Instead of changing the pH parameter to achieve stability, the invention changes the compositional parameter by adding nucleic acid. This allows the system to maintain neutral pH while achieving heat stability through the protective effect of nucleic acid rather than through pH adjustment.

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If large amounts of stabilizers (soybean polysaccharide, xanthan gum) are added to improve heat stability, then lactoferrin stability is improved, but product viscosity and physical properties are affected

Engineering Contradiction:
Improvelactoferrin heat stabilityVSAvoidproduct physical properties
Core Design Contradiction:
Stability of the object's compositionVSShape

Solution Approach 1:

The invention uses nucleic acid as a temporary protective agent during heat sterilization. The nucleic acid provides the necessary stability during the heat treatment process and can be present in very small amounts (mass ratio 0.01-10), avoiding the viscosity problems associated with large amounts of polysaccharide stabilizers.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Productivity

If lactoferrin is heated at 62.5°C for 30 minutes or 70°C for 15 minutes at neutral pH, then heat treatment is completed, but physiological activities are almost or completely lost

Engineering Contradiction:
Improveheat treatment efficiencyVSAvoidphysiological activity retention
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The nucleic acid is added to lactoferrin before heat treatment to establish a protective complex. This preliminary action ensures that when heat sterilization is applied, the lactoferrin is already protected and can withstand the thermal stress without losing its physiological activities.

Inventive Principle:
Principle #10Preliminary action

Data Source

PatentUS8420128B2Method of imparting heat resistance to lactoferrin
Publication Date: 2013.04.16 MORINAGA MILK IND CO LTD

AI summary

An agent for thermally stabilizing lactoferrin, which comprises a nucleic acid as an active ingredient, can be added to lactoferrin to impart thermal stability to lactoferrin. Thermally stabilized lactoferrin can be heat-sterilized at a pH value around a neutral pH value while keeping its activity.