Laminate Forming with Separate Isocyanate-Reactive Adhesive Components

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Solution Overview

Problem

Existing laminate production processes using solvent-based adhesives require a drying step, which increases equipment and processing costs, and pre-mixed solvent-less adhesives with sufficient adhesion exhibit a short pot life and slow curing properties.

Innovation Solution

A process involving the uniform application of an isocyanate component and an isocyanate-reactive component to separate substrates, followed by mixing and curing to form a solvent-less adhesive layer, with a stoichiometric ratio of 1.0 to 5.0, to create a laminate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If solvent-based adhesives are used to form laminates, then adhesion between substrates is achieved, but an additional drying step is required which increases equipment and processing costs

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoidequipment requirements
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The invention extracts and eliminates the solvent component from the adhesive system, transitioning from solvent-based to solvent-less adhesives. This removal of the solvent eliminates the need for drying equipment and processing steps, directly resolving the contradiction between adhesion effectiveness and equipment complexity

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the chemical composition parameters of the adhesive by using solvent-less formulations with specific isocyanate-to-reactive component ratios (1:4 to 4:1). This parameter change enables the adhesive to cure without solvent evaporation, eliminating the drying step and associated equipment while maintaining bonding performance

Inventive Principle:
Principle #35Parameter changes

2Device complexity

If pre-mixed solvent-less adhesives are used to eliminate drying steps, then equipment costs are reduced, but the adhesive exhibits short pot life and slow curing properties

Engineering Contradiction:
Improveequipment requirementsVSAvoidbonding speed and pot life
Core Design Contradiction:
Device complexityVSProductivity

Solution Approach 1:

The invention segments the adhesive into two separate components: an isocyanate component and a reactive component. These components are applied separately to substrates and only mix upon contact between substrates, preventing premature reaction and extending pot life while enabling fast curing once mixed, thus resolving the contradiction between equipment simplicity and bonding productivity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention performs preliminary action by pre-applying each adhesive component to substrates before they are laminated together. This allows the components to be ready for immediate reaction upon substrate contact, enabling fast bonding without requiring pre-mixing that would limit pot life, thereby resolving the contradiction between equipment simplicity and bonding speed

Inventive Principle:
Principle #10Preliminary action

3Strength

If pre-mixed solvent-less adhesives are used to provide sufficient adhesion, then bonding strength is achieved, but pot life is short and curing is slow

Engineering Contradiction:
Improveadhesion between substratesVSAvoidpot life
Core Design Contradiction:
StrengthVSDuration of action of moving object

Solution Approach 1:

The invention divides the adhesive system into two stable, non-reactive components that can be stored and handled separately with extended pot life. When applied to substrates and brought into contact, these segments rapidly react to form strong bonds, thus resolving the contradiction between adhesion strength and pot life duration

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention creates a dynamic system where the adhesive components remain stable and non-reactive during storage and application (long pot life), but rapidly react when substrates are laminated together (fast curing). This dynamic behavior resolves the contradiction between maintaining adhesion capability and extending usable time

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method allows for faster bonding and curing of laminates without the need for additional drying steps, reducing equipment costs and improving pot life.

Implementation Method 1

bringing the first substrate and the second substrate together, thereby mixing and reacting the isocyanate component and the isocyanate-reactive component to form an adhesive composition between the first substrate and the second substrate

Methodology Applied
Scientific EffectChemical reaction (isocyanate-amine reaction): Chemical Bonding

Implementation Method 2

curing the adhesive composition to bond the first substrate and the second substrate

Methodology Applied
Scientific EffectCuring reaction: Chemical Bonding

Data Source

PatentUS20250296310A1Process for Forming a Laminate
Publication Date: 2025.09.25 ARKEMA FRANCE SA
  • US20250296310A1 patent drawing
  • US20250296310A1 patent drawing
  • US20250296310A1 patent drawing

AI summary

The present disclosure provides a process for forming a laminate. The process includes (A) uniformly applying an isocyanate component to a first substrate, the isocyanate component containing an isocyanate compound; (B) uniformly applying an isocyanate-reactive component to a second substrate, the isocyanate-reactive component containing an amine-terminated compound; (C) bringing the first substrate and the second substrate together, thereby mixing and reacting the isocyanate component and the isocyanate-reactive component to form an adhesive composition between the first substrate and the second substrate; (D) curing the adhesive composition to bond the first substrate and the second substrate; and (E) forming the laminate.