Laminate Surfactant Copolymer Suppresses Liquid Crystal Alignment Defects

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Solution Overview

Problem

Liquid crystal layers on optical alignment layers often exhibit alignment defects due to insufficient aligning regulation power, particularly with optical alignment treatments, which affect the performance of image display devices.

Innovation Solution

A laminate comprising an optical alignment layer with a liquid crystal layer formed from a composition containing a liquid crystal compound and a surfactant, where the surfactant is a copolymer with a fluorinated alkyl group and a mesogenic group, and the liquid crystal compound is immobilized in a horizontal alignment state, enhancing alignment stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If an optical alignment layer is used instead of a stretched birefringence film, then the alignment process is simplified and manufacturing efficiency is improved, but alignment defects occur in the liquid crystal layer

Engineering Contradiction:
Improvemanufacturing efficiencyVSAvoidalignment quality
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

A surfactant copolymer is introduced as an intermediary substance between the optical alignment layer and the liquid crystal layer. This copolymer contains both a mesogenic group (which interacts with liquid crystal molecules) and a fluorinated alkyl group (which provides surfactant properties). The surfactant acts as a mediator that enhances the aligning regulation power of the optical alignment layer, enabling effective alignment transfer while preventing alignment defects in the liquid crystal layer.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the chemical composition parameters of the liquid crystal composition by incorporating a surfactant copolymer with specific molecular structure (containing mesogenic groups and fluorinated alkyl groups). This parameter change in composition enables the liquid crystal layer to achieve proper alignment on the optical alignment layer by modifying the interfacial interaction properties and enhancing alignment stability.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If optical alignment treatment is used, then the alignment process is simplified compared to rubbing treatment, but the aligning regulation power is insufficient

Engineering Contradiction:
Improvealignment process simplicityVSAvoidaligning regulation power
Core Design Contradiction:
Ease of manufactureVSForce

Solution Approach 1:

The surfactant copolymer serves as an intermediary that amplifies the aligning regulation power of the optical alignment layer. By incorporating mesogenic groups that interact strongly with liquid crystal molecules and fluorinated alkyl groups that provide surfactant functionality, the copolymer enhances the optical alignment effect without requiring mechanical rubbing treatment.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention uses a composite material approach by creating a surfactant copolymer that combines two functional components: mesogenic groups (for liquid crystal alignment) and fluorinated alkyl groups (for surfactant properties). This composite molecular structure provides both the simplicity of optical alignment and the sufficient aligning regulation power that would otherwise require mechanical rubbing.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution effectively suppresses alignment defects in liquid crystal layers, improving the performance and reliability of image display devices by ensuring better alignment and stability of the liquid crystal layer.

Implementation Method 1

the surfactant is a copolymer having a repeating unit containing a fluorinated alkyl group, and a repeating unit containing a mesogenic group

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

a liquid crystal layer provided on the optical alignment layer may have alignment defects depending on the kind of liquid crystal compound

Methodology Applied
Scientific EffectLiquid Crystals: Liquid Crystals

Implementation Method 3

the optical alignment layer contains a compound having a photo-alignable group, and the photo-alignable group is a group having a cinnamoyl structure

Methodology Applied
Scientific EffectPhoto-alignable group: Photochromism

Data Source

PatentUS11487152B2Laminate and image display device
Publication Date: 2022.11.01 FUJIFILM CORP
  • US11487152B2 patent drawing
  • US11487152B2 patent drawing
  • US11487152B2 patent drawing

AI summary

The present invention provides a laminate and an image display device, in which alignment defects of a liquid crystal layer provided on an optical alignment layer are suppressed. The laminate includes an optical alignment layer and a liquid crystal layer provided on the optical alignment layer. In the laminate, the liquid crystal layer is formed from a liquid crystal composition containing a liquid crystal compound and a surfactant, and the liquid crystal compound is immobilized in a horizontal alignment state, and the surfactant is a copolymer having a repeating unit containing a fluorinated alkyl group and having a repeating unit containing a mesogenic group.