Laminated Volatilization Suppressing Coating for Metal Substrates

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Solution Overview

Problem

Existing methods for preventing volatilization in high-temperature metal components, such as those used in glass and semiconductor manufacturing, face issues with coating layer detachment and cracking, leading to insufficient oxygen barrier performance and reduced product lifespan.

Innovation Solution

A laminated film structure comprising a dense adhesive layer and a porous protective layer, where the adhesive layer has a porosity of less than 10% and the protective layer has a porosity of 10-50%, with specific particle size and thickness ranges, is applied to the metallic base material to prevent oxygen invasion and crack propagation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a single-layer coating is applied to prevent volatilization, then the manufacturing process is simple, but the coating layer detaches and cracks under thermal cycling

Engineering Contradiction:
Improvecoating process simplicityVSAvoidcoating layer integrity
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The coating is divided into multiple layers: a bottom coating layer applied first, followed by a top coating layer. This segmentation allows each layer to perform specific functions - the bottom layer adheres to the metal substrate while the top layer provides oxidation resistance, resolving the contradiction between manufacturing simplicity and coating integrity under thermal cycling.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent uses composite coating structures combining different materials with complementary properties. The bottom layer uses materials optimized for adhesion to the metal substrate, while the top layer uses materials with superior oxidation resistance. This composite approach maintains manufacturing feasibility while significantly improving coating reliability during thermal cycling.

Inventive Principle:
Principle #40Composite materials

2Strength

If surface treatment is applied to improve fixing strength, then detachment is reduced, but cracking still occurs and oxygen barrier performance is insufficient

Engineering Contradiction:
Improvefixing strength between coating and substrateVSAvoidoxygen barrier performance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The coating system is segmented into functional layers where the bottom layer addresses adhesion requirements through surface treatment and material selection, while the top layer independently provides oxygen barrier functionality. This segmentation allows optimization of each layer for its specific function without compromising the other.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The bottom coating layer acts as an intermediary between the metal substrate and the top coating layer. It provides the necessary mechanical anchoring through surface treatment while also serving as a diffusion barrier, preventing oxygen from reaching the substrate even when the top layer develops minor defects.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If a porous oxygen barrier film is applied, then manufacturing is easy, but oxygen penetrates easily and the film peels off

Engineering Contradiction:
Improvefilm application simplicityVSAvoidoxygen barrier effectiveness
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The coating system segments the barrier function across two layers. The bottom layer provides a dense, low-porosity foundation that serves as the primary oxygen barrier, while the top layer can be more porous yet still effective. This segmentation maintains manufacturing simplicity while dramatically improving oxygen barrier effectiveness compared to a single porous layer.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs composite coating materials where the bottom layer uses materials with low porosity and high density for optimal oxygen barrier performance, while the top layer may use materials that are easier to apply but still provide protection. This composite material approach resolves the contradiction between ease of manufacture and oxygen barrier effectiveness.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The laminated film structure effectively prevents detachment and crack propagation, enhancing the oxygen barrier performance and extending the product lifespan by maintaining the integrity of the metallic base material.

Implementation Method 1

the adhesive layer has a porosity of less than 10%

Methodology Applied
Scientific EffectPorosity: Porosity

Implementation Method 2

a first layer which is an adhesive layer between the metallic base material and the second layer

Methodology Applied
Scientific EffectThermal spray: Plasma Spray

Data Source

PatentUS11993534B2Volatilization suppressing component, and method for manufacturing same
Publication Date: 2024.05.28 FURUYA KINZOKU KK
  • US11993534B2 patent drawing
  • US11993534B2 patent drawing
  • US11993534B2 patent drawing

AI summary

The volatilization suppressing component according to the present disclosure has a metallic base material; and a laminated film having at least a first layer formed on a portion or the entirety of a surface of the metallic base material, and a second layer formed on the first layer, wherein the first layer is an adhesive layer between the metallic base material and the second layer, and the second layer is a protective layer for the first layer.