Lanthanide Implant Work Function Adjustment

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Solution Overview

Problem

Conventional CMOS transistor fabrication faces challenges in achieving predictable and stable threshold voltages due to limitations in gate dielectric thickness and dopant diffusion, particularly in scaling down semiconductor devices while maintaining performance.

Innovation Solution

Incorporating a lanthanide series material into the gate dielectric and silicon-based gate electrode, with subsequent annealing to drive the lanthanide series material into the gate dielectric, effectively reducing the work function of NMOS transistors and tuning the threshold voltage without affecting PMOS transistors.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If gate dielectric thickness is reduced to enable device scaling, then device density and integration are improved, but threshold voltage control and electrical performance deteriorate

Engineering Contradiction:
Improvedevice densityVSAvoidthreshold voltage control
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent introduces lanthanide series materials to modify the work function of the gate electrode, thereby changing the electrical parameters of the transistor. By adjusting the work function through material composition control, the threshold voltage can be precisely tuned even with thin gate dielectrics, resolving the contradiction between device scaling and threshold voltage control.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite gate electrode structures incorporating lanthanide series materials combined with other materials (such as tungsten, molybdenum, or polysilicon). These composite materials provide both the low work function needed for NMOS devices and the mechanical stability required for thin-gate structures, enabling both high device density and reliable threshold voltage control.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If dopant implantation is used to adjust threshold voltage, then threshold voltage tuning is achieved, but dopant diffusion causes variability and manufacturing precision deteriorates

Engineering Contradiction:
Improvethreshold voltage tuningVSAvoidthreshold voltage stability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent extracts the threshold voltage control mechanism from dopant implantation and relocates it to the gate electrode work function adjustment. By using lanthanide series materials in the gate electrode, threshold voltage is controlled through material selection rather than dopant diffusion, eliminating the variability introduced by dopant spreading and improving both manufacturing precision and device reliability.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The lanthanide series material acts as an intermediary between the gate electrode structure and the channel, mediating the electrical characteristics without requiring dopant implantation into the channel. This intermediary approach allows precise threshold voltage control through material properties rather than chemical doping, reducing manufacturing variability.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If polysilicon gate is doped to adjust work function, then gate work function is tuned, but gate conductivity and process complexity increase

Engineering Contradiction:
Improvegate work function tuningVSAvoidgate structure complexity
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

Instead of changing the doping level of polysilicon to adjust work function, the patent changes the material composition by incorporating lanthanide series elements. This parameter change in material composition provides a more direct and controllable method for adjusting work function without the need for complex doping processes, thereby reducing overall device complexity while maintaining ease of manufacture.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces the work function of NMOS transistors, enhancing the stability and predictability of threshold voltages, enabling improved device performance and scalability while maintaining equivalent electrical performance.

Implementation Method 1

with subsequent annealing to drive the lanthanide series material into the gate dielectric

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 2

effectively reducing the work function of NMOS transistors and tuning the threshold voltage

Methodology Applied
Scientific EffectWork function reduction:

Data Source

PatentUS8802519B2Work function adjustment with the implant of lanthanides
Publication Date: 2014.08.12 TEXAS INSTRUMENTS INC
  • US8802519B2 patent drawing
  • US8802519B2 patent drawing
  • US8802519B2 patent drawing

AI summary

Semiconductor devices and fabrication methods are provided, in which fully silicided gates are provided. A lanthanide series metal is implanted into the gate electrode layer prior to silicidation and diffuses into the gate dielectric during an activation anneal. This process and resultant structure provides adjustment of the gate electrode work function, thereby tuning the threshold voltage of the resulting transistor.