Laser Ablation Surface Modification for Cigarette Filters

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Solution Overview

Problem

Current methods for producing cigarette filters require large quantities of additives for efficient filtration, leading to increased costs and complexity due to non-uniform mixing and potential contamination of mainstream smoke, while existing surface modification processes do not facilitate a single-step filter formation.

Innovation Solution

A continuous process using high energy ablation to anchor selective materials onto filter supports in a single step, eliminating the need for bulk additive blending and solvent-based applications, allowing for improved filtration efficiency and reduced mass transfer into smoke, with the option to use multiple chambers for targeted compound filtration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If large quantities of additives are physically blended with fibers for efficient selective filtration, then filtration efficiency is improved, but filter design complexity and cost increase

Engineering Contradiction:
Improvefiltration efficiencyVSAvoidfilter design complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention extracts the filtration function from bulk additive blending and relocates it to the fiber surface through grafting.Selective filtration materials are grafted directly onto the outer surface of filter fibers, concentrating the filtration function at the interface where smoke contact occurs, thereby achieving efficient filtration without requiring large quantities of additives throughout the bulk filter structure

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention applies local quality by concentrating filtration materials specifically at the outer surface of filter fibers where smoke interaction occurs. The grafting process creates a localized functional layer with high filtration activity at the critical interface, while the bulk fiber structure maintains its mechanical properties, optimizing both filtration efficiency and structural integrity

Inventive Principle:
Principle #3Local quality

2Reliability

If large quantities of additives are physically blended with fibers, then filtration efficiency is improved, but the process requires additional process controls and negative impact on throughput

Engineering Contradiction:
Improvefiltration efficiencyVSAvoidthroughput
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The invention implements continuous useful action through a continuous grafting process where filter materials pass through the modification zone without interruption. The in-line surface modification allows continuous production of grafted fibers, maintaining high throughput while consistently applying filtration materials, eliminating the batch processing and rework associated with traditional blending methods

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The invention merges the fiber formation process with surface modification by integrating the grafting step into the continuous filter manufacturing line. The surface modification is performed in-line during fiber production, combining two previously separate operations into one continuous process, thereby eliminating additional process controls and maintaining high production throughput

Inventive Principle:
Principle #5Merging (Combining)

3Reliability

If physical blending of additives is used for selective filtration, then filtration function is achieved, but uniform mixing and uniform modification of filter surface are problematic

Engineering Contradiction:
Improvefiltration functionVSAvoiduniformity of additive distribution
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The invention replaces mechanical blending with a chemical grafting mechanism. Instead of relying on physical mixing of additives with fibers (which creates non-uniform distribution), the filtration materials are chemically bonded to fiber surfaces through controlled grafting reactions, ensuring uniform and predictable distribution of functional materials at the molecular level

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention changes the fundamental parameter of material attachment from physical mixing to chemical bonding. The grafting process transforms the interaction mechanism between additives and fibers, creating strong covalent bonds that ensure uniform distribution and prevent the aggregation and non-uniformity inherent in physical blending methods

Inventive Principle:
Principle #35Parameter changes

4Reliability

If additives are physically blended with filter fibers, then filtration capability is achieved, but there is possibility of extra movement into cigarette mainstream smoke

Engineering Contradiction:
Improvefiltration capabilityVSAvoidcontamination of mainstream smoke
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention extracts the filtration materials from the bulk filter structure and relocates them to the outer surface of fibers through grafting. This positioning ensures that filtration materials remain stationary at the fiber surface where they can effectively intercept smoke components, preventing the material movement and potential contamination that occurs with bulk blending approaches

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process enhances filtration selectivity, reduces material costs, and simplifies filter design by achieving uniform surface modification in a single step, improving compatibility and wettability, and allowing for the use of organic or inorganic precursors to form functional groups or nanoscale materials with enhanced selectivity.

Implementation Method 1

A high energy source such as a laser is used to vaporize or ablate target precursors. The laser causes the target material to ablate, evaporate or fragment resulting in the formation of atomic or molecular species.

Methodology Applied
Scientific EffectLaser ablation: Laser Ablation

Implementation Method 2

These species recombine in a region close to the target to form corresponding modification additive materials. The modification additives may then be carried by a convective or forced flow to the vicinity of a cold plate where they condense onto the surface of a filter material

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 3

The modification additives may then be carried by a convective or forced flow to the vicinity of a cold plate

Methodology Applied
Scientific EffectConvection: Convection

Data Source

PatentUS7478637B2Continuous process for surface modification of cigarette filter materials
Publication Date: 2009.01.20 PHILIP MORRIS USA INC
  • US7478637B2 patent drawing
  • US7478637B2 patent drawing
  • US7478637B2 patent drawing

AI summary

Process and apparatus are provided for depositing target materials onto the surface of a moving substrate which may be used in the preparation of composites, cigarette filters, cigarette wrapper, bandages, biomedical applications, cosmetic and cleaning materials, and the like. A moving substrate comprising a fibrous mat or paper passes through one or more reaction chambers each having hot and cold regions. At least one target material is positioned in the hot region, and a laser beam ablates the material thereby producing modified additive material. As the substrate moves through the cold region of the reaction chamber, the modified additive material adheres to the exposed surface of the substrate.