Laser Ablation Feedstock Powder with Thermal Gradient Control

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Solution Overview

Problem

Existing methods for producing feedstock powders for laser-based additive manufacturing face challenges in achieving uniform composition, spherical shape, and homogeneously mixed phases, while also requiring expensive source materials and suffering from low throughput and phase instabilities.

Innovation Solution

The use of controlled-cooling laser ablation techniques to vaporize source materials in a temperature-controlled vaporization chamber, creating a vertical thermal gradient that controls nucleation, coagulation, and agglomeration, resulting in uniform, spherical, and homogeneously mixed microparticles suitable for additive manufacturing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If mechanical attrition is used to produce feedstock powder, then throughput is high and source materials are inexpensive, but the powder is non-uniform in composition and shape

Engineering Contradiction:
ImprovethroughputVSAvoidpowder uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent replaces mechanical attrition with laser ablation, substituting a mechanical system with an optical/thermal system. The laser beam vaporizes source material to form particles, eliminating the mechanical contact that causes non-uniformity while maintaining high throughput capability.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the physical parameters of the source material by controlling laser power, pulse duration, and ambient conditions during ablation. By adjusting these parameters, the process produces uniform spherical particles with consistent composition, resolving the uniformity issue while preserving high productivity.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If conventional atomization is used to produce feedstock powder, then uniform and spherical powders are created, but expensive source materials and low throughput are required

Engineering Contradiction:
Improvepowder uniformityVSAvoidthroughput
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent replaces conventional atomization with laser ablation, substituting a mechanical/electrical system with an optical system. This allows the use of inexpensive solid source materials instead of expensive liquid precursors or melts, while maintaining the ability to produce uniform spherical particles and significantly improving throughput.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Manufacturing precision

If conventional atomization is used to produce feedstock powder, then uniform and spherical powders are created, but phase instabilities occur

Engineering Contradiction:
Improvepowder uniformityVSAvoidphase stability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent controls the thermal parameters during particle formation by adjusting laser power, pulse duration, and cooling rates. This precise control over temperature and cooling conditions ensures that the desired phase structure is achieved and maintained, eliminating phase instabilities while preserving particle uniformity.

Inventive Principle:
Principle #35Parameter changes

4Productivity

If mechanical attrition is used to produce feedstock powder, then high throughput is achieved, but defective powders with non-spherical shapes are produced

Engineering Contradiction:
ImprovethroughputVSAvoidparticle sphericity
Core Design Contradiction:
ProductivityVSShape

Solution Approach 1:

The patent replaces mechanical attrition with laser ablation, substituting a mechanical system with an optical/thermal system. The laser vaporizes material that then condenses into spherical particles, eliminating the mechanical deformation that causes non-spherical shapes while maintaining high throughput.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent inherently produces spherical particles through the vaporization and condensation mechanism of laser ablation. The spherical shape emerges naturally from the isotropic nature of the phase transition process, ensuring uniform morphology without mechanical deformation.

Inventive Principle:
Principle #14Spheroidality (Curvature)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the production of high-quality feedstock powders that are uniform in composition, shape, and phase, suitable for laser-based additive manufacturing, while using relatively inexpensive source materials and achieving improved throughput compared to conventional methods.

Implementation Method 1

directing a focused energy source toward a source material to vaporize compounds of the source material

Methodology Applied
Scientific EffectLaser ablation: Laser Ablation

Implementation Method 2

vaporize compounds of the source material

Methodology Applied
Scientific EffectVaporization: Evaporation

Implementation Method 3

passing the compounds through a temperature-controlled vaporization chamber to cool the compounds and form solid microparticles

Methodology Applied
Scientific EffectCooling: Cooling

Implementation Method 4

cool the compounds and form solid microparticles

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 5

creating a vertical thermal gradient that controls nucleation, coagulation, and agglomeration

Methodology Applied
Scientific EffectNucleation: Nucleation

Implementation Method 6

creating a vertical thermal gradient that controls nucleation, coagulation, and agglomeration

Methodology Applied
Scientific EffectCoagulation: Coagulation

Implementation Method 7

creating a vertical thermal gradient that controls nucleation, coagulation, and agglomeration

Methodology Applied
Scientific EffectAgglomeration:

Data Source

PatentUS12202046B2Laser ablation methods for producing feedstock powder suitable for laser-based additive manufacturing
Publication Date: 2025.01.21 BATTELLE ENERGY ALLIANCE LLC
  • US12202046B2 patent drawing
  • US12202046B2 patent drawing

AI summary

Methods and systems for producing feedstock powders, suitable for use in laser-based additive manufacturing, use laser ablation to vaporize a source material, which may be in bulk solid or solid coarse grain form. The source material is vaporized by a laser (or other focused energy source) in a vaporization chamber that is temperature controlled to provide a vertical thermal gradient. The vertical thermal gradient may be controlled to, in turn, control the nucleation, coagulation, and agglomeration of the vaporized molecules, enabling formation of microparticles that may then be used as feedstock powders in laser-based additive manufacturing. The produced feedstock powder particles may be of uniform composition, of uniform shape (e.g., substantially spherical), and of uniform phase or homogeneously mixed phases.