Laser-Carbonized Gas Sensor for Hazardous Material Detection

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Solution Overview

Problem

Conventional gas sensors for detecting hazardous materials in industrial environments require high power, are complex to manufacture, and lack repeatability and reproducibility due to their sophisticated architecture and reliance on ion beam irradiation and plasma treatment, making them unsuitable for immediate and reliable gas detection in industrial settings.

Innovation Solution

A gas sensor with a carbon structure formed by carbonizing a carbide material layer using a CO2 laser, which includes a photoresist and ethanol solution, allowing for the formation of a carbon structure with high adsorption performance and electrical property changes upon exposure to gas particles, enabling efficient detection of hazardous materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional graphene-based gas sensors are manufactured using ion beam irradiation and plasma treatment, then gas adsorption capability is improved, but manufacturing complexity and equipment requirements increase significantly

Engineering Contradiction:
Improvegas adsorption capabilityVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent replaces complex mechanical and chemical treatment systems (ion beam irradiation equipment and plasma treatment equipment) with a simple laser irradiation system. The laser directly carbonizes the photoresist layer to form graphene structures, eliminating the need for sophisticated vacuum chambers, ion sources, and plasma generation equipment, thus dramatically simplifying the manufacturing process while maintaining effective gas adsorption capability

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the manufacturing approach from multi-step physical/chemical treatments to a single-step thermal carbonization process controlled by laser parameters (power, scanning speed, wavelength). By adjusting these parameters, the photoresist is directly converted into functional graphene structures with appropriate porosity and surface area for gas sensing, achieving reliable performance through parameter optimization rather than complex process sequences

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If pump systems are used to introduce gases into sensors, then gas detection capability is improved, but power consumption increases

Engineering Contradiction:
Improvegas detection capabilityVSAvoidpower consumption
Core Design Contradiction:
Measurement precisionVSUse of energy by moving object

Solution Approach 1:

The patent enables the sensor to function passively by placing the carbonized graphene sensor directly in the hazardous gas environment. The graphene material's inherent high surface area and porosity allow spontaneous adsorption of gas molecules without requiring active gas introduction systems. This self-service approach eliminates pump power consumption while maintaining effective gas detection capability through the material's intrinsic properties

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent extracts and removes the pump system from the sensor architecture entirely. By relying on the graphene material's natural adsorption properties and direct environmental exposure, the design eliminates the energy-consuming gas introduction subsystem, achieving power-efficient operation suitable for portable and distributed sensing applications

Inventive Principle:
Principle #2Taking out (Extraction)

3Adaptability or versatility

If conventional sensor systems include multiple additional components, then sensing functionality is improved, but device size and architectural complexity increase

Engineering Contradiction:
Improvesensing functionalityVSAvoiddevice size
Core Design Contradiction:
Adaptability or versatilityVSVolume of moving object

Solution Approach 1:

The patent creates a universal sensing platform where the carbonized graphene structure serves multiple functions simultaneously: it acts as the gas adsorption medium, the electrical conduction path, and the sensing element itself. This multi-functionality eliminates the need for separate components for gas introduction, separation, and detection, achieving compact integration while maintaining versatile sensing capabilities for various hazardous gases

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent merges the photoresist layer, carbonization process, and sensing element formation into a single integrated structure. The photoresist pattern directly becomes the graphene sensor structure after laser carbonization, combining what were previously separate components (substrate, sensing material, electrode patterns) into one unified fabrication process and final structure, dramatically reducing device size and component count

Inventive Principle:
Principle #5Merging (Combining)

4Reliability

If ion beam irradiation and plasma treatment are used for graphene-based sensors, then gas adsorption is improved, but repeatability and reproducibility deteriorate

Engineering Contradiction:
Improvegas adsorptionVSAvoidrepeatability and reproducibility
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent replaces ion beam irradiation and plasma treatment with laser irradiation, which provides more consistent and controllable processing. Laser parameters (power, speed, wavelength) can be precisely controlled and replicated across production batches, eliminating the variability inherent in plasma conditions and ion beam parameters. This substitution improves manufacturing precision and ensures repeatable graphene structure formation with consistent gas adsorption performance

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent transitions from difficult-to-control process parameters (plasma power, gas flow rates, ion beam energy) to easily controlled and replicated laser parameters. The carbonization process is governed by well-defined thermal parameters that can be precisely set and maintained, ensuring that every sensor produced under the same conditions exhibits identical performance characteristics, thereby improving repeatability and reproducibility

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The gas sensor achieves high adsorption performance for gases with varying vapor pressures, allowing for rapid and repeatable detection of hazardous materials through resistance changes, and can be manufactured more simply than conventional sensors, facilitating industrial applications.

Implementation Method 1

carbonizing, based on an irradiation of a laser on the carbide material layer, the carbide material layer to form a carbon structure capable of adsorbing gas particles

Methodology Applied
Scientific EffectLaser carbonization: Pyrolysis

Implementation Method 2

a carbon structure with high adsorption performance and electrical property changes upon exposure to gas particles

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS20240255456A1Gas sensor comprising carbon structure having high adsorption performance for gas and method for manufacturing the same
Publication Date: 2024.08.01 HONGIK UNIV IND ACAD COOP FOUND
  • US20240255456A1 patent drawing
  • US20240255456A1 patent drawing
  • US20240255456A1 patent drawing

AI summary

A method for manufacturing a gas sensor includes forming an electrode pattern; forming a carbide material layer on the electrode pattern; carbonizing, based on an irradiation of a laser on the carbide material layer, the carbide material layer to form a carbon structure capable of adsorbing gas particles; and electrically connecting a measurement device to the electrode pattern. The measurement device is configured to measure electrical properties of the electrode pattern. The gas sensor is capable of detecting hazardous materials such as nitrogen oxide.