Laser Crystal Analysis via Fluorescent Defect Conversion

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Solution Overview

Problem

Current methods for analyzing crystal defects and impurities, such as X-ray topographic and spectroscopic techniques, are insufficiently sensitive to low concentrations and cannot distinguish between natural and synthetic crystals, and are costly or modify the crystal structure.

Innovation Solution

A laser method that creates, modifies, or diffuses defects within crystals using focused laser beams, allowing for precise control over defect formation and detection via fluorescence, enabling detailed analysis of crystal characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional analysis techniques (X-ray, spectroscopic methods) are used to analyze crystal defects and impurities, then information about defect type, concentration, and distribution can be obtained, but the methods are insufficiently sensitive to low concentrations and cannot distinguish between natural and synthetic crystals

Engineering Contradiction:
Improvedetection sensitivityVSAvoidability to distinguish natural vs synthetic
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent changes the physical parameter of defect interaction by using laser-induced defects that interact differently with the crystal lattice based on its origin. The laser writing process creates defects whose properties (fluorescence characteristics, formation dynamics) serve as fingerprints for distinguishing natural from synthetic crystals, overcoming the limitations of conventional techniques.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces conventional mechanical/X-ray analysis methods with a laser-based optical system. Instead of using X-ray diffraction or absorption spectroscopy, the invention uses laser writing to create defects and detect their optical properties (fluorescence, absorption), providing a non-contact, non-destructive method with higher sensitivity and discriminatory power.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Measurement precision

If X-ray techniques are used to identify dislocation patterns, then distinctive patterns of synthetic vs natural crystals can be identified, but the techniques are expensive to implement and use

Engineering Contradiction:
Improvedislocation pattern identificationVSAvoidimplementation cost
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent replaces expensive, complex X-ray equipment with a relatively simple, inexpensive laser system. The laser writing apparatus uses standard laser components and common optical detectors, eliminating the need for costly X-ray generators, detectors, and associated safety infrastructure while achieving comparable or superior analytical capability.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent substitutes the complex mechanical and radiological X-ray system with a simpler optical laser system. The laser-based method uses light-matter interaction to probe crystal defects, replacing the need for X-ray diffraction apparatus with compact laser sources and optical detectors, significantly reducing implementation costs.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Reliability

If synthesis processes are altered or post synthesis processes applied to produce crystals with point defects matching natural crystals, then synthetic crystals can be made to resemble natural ones, but this requires modification of the crystal growth process

Engineering Contradiction:
Improvematching of defect characteristicsVSAvoidcrystal growth process complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies preliminary action by using laser writing to intentionally create specific defects in synthetic crystals before they are finalized. This post-growth defect engineering allows precise control over defect type, position, and concentration, enabling synthetic crystals to be tailored to match or exceed natural crystal characteristics without complicating the growth process itself.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the approach from modifying growth parameters to changing defect parameters after growth. Instead of altering temperature, pressure, or composition during crystal growth, the invention uses laser parameters (wavelength, pulse duration, intensity) to create and control defects, decoupling defect engineering from the growth process and simplifying manufacturing.

Inventive Principle:
Principle #35Parameter changes

4Manufacturing precision

If laser is used to create, modify, or diffuse defects within crystals, then high positional accuracy and minimal crystal damage are achieved, but the method requires conversion of non-fluorescent defects into fluorescent ones for detection

Engineering Contradiction:
Improvepositional accuracy of defectsVSAvoiddetection requirement
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent changes the optical parameter of the defects by converting non-fluorescent defects into fluorescent ones through laser treatment. The laser writing process modifies the electronic structure of defects, inducing fluorescence that enables detection. This parameter change transforms invisible defects into detectable signals without compromising the high positional accuracy achieved during defect creation.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Provides high positional accuracy and minimal crystal damage while converting non-fluorescent defects into fluorescent ones, offering additional information about crystal type, origin, and quality through spectroscopic analysis.

Implementation Method 1

focusing a laser into a crystal to induce the creation, modification, dissociation, or diffusion of defects within a focal region of the laser

Methodology Applied
Scientific EffectLaser heating: Laser

Implementation Method 2

detecting, via fluorescence, when a colour centre is formed within the focal region

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Data Source

PatentEP3833965B1Laser method and apparatus for analysing crystals
Publication Date: 2026.01.28 OXFORD UNIVERSITY INNOVATION LTD
  • EP3833965B1 patent drawingFigure 1A~1B
  • EP3833965B1 patent drawingFigure 2
  • EP3833965B1 patent drawingFigure 3~4

AI summary

A method of analysing crystals is described. The method comprises focusing a laser into a crystal to induce the creation, modification, dissociation, or diffusion of one or more defects within a focal region of the laser. A signal dependent on the creation, modification, dissociation or diffusion of the one or more defects within the focal region of the laser is measured during or after the aforementioned process and used to determine one or more characteristics of the crystal being analysed. In one configuration, one or more fluorescent defects are created, modified, or dissociated and the fluorescent signal is analysed to determine the type of crystal being analysed.