Tunable Laser Diode Gas Discrimination via Temperature Shift

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Solution Overview

Problem

Current gas detection methods, such as gas chromatography and cavity ring-down spectroscopy, are inefficient for discriminating between natural gas and biogas, particularly in leak surveys, due to long response times, limited sensitivity, and high costs.

Innovation Solution

A portable laser absorption spectroscopy system that rapidly shifts between detecting different gases or their isotopes by adjusting the operating temperature of the light source and photodetector, allowing for continuous measurement of gas concentrations using a Herriott cell and laser diodes or LEDs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If gas chromatography or cavity ring-down spectroscopy is used for gas discrimination, then measurement precision is improved, but response time increases and productivity decreases

Engineering Contradiction:
Improvegas discrimination accuracyVSAvoidresponse time
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent changes the operating temperature parameter of the light source to shift its emission wavelength between two preselected wavelengths. This allows the same light source and detection system to detect different gases (or isotopes) by simply adjusting the temperature, enabling rapid switching between detection targets without the long response times associated with gas chromatography or cavity ring-down spectroscopy methods

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent makes a single light source perform multiple functions by enabling it to detect different gases or isotopes at different wavelengths through temperature adjustment. This multi-functional approach eliminates the need for multiple specialized detection systems, thereby reducing overall response time while maintaining measurement precision

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Measurement precision

If gas chromatography is used for gas discrimination, then measurement precision is improved, but device complexity and cost increase

Engineering Contradiction:
Improvegas discrimination accuracyVSAvoidsystem complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent employs a single light source that can be tuned to different wavelengths by adjusting its operating temperature, allowing one device to perform the work of multiple specialized detectors. This universal approach simplifies the overall system architecture while maintaining the ability to discriminate between different gases or isotopes with high precision

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

By changing the operating temperature parameter of the light source, the system can shift between detecting different gases or isotopes without requiring physical reconfiguration or multiple specialized components. This parameter-based switching reduces device complexity compared to systems requiring multiple fixed-wavelength detectors or complex chromatography apparatus

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If a single light source is used for multiple gas detections, then device complexity is reduced, but measurement precision may worsen

Engineering Contradiction:
Improvesystem simplicityVSAvoiddetection accuracy
Core Design Contradiction:
Device complexityVSMeasurement precision

Solution Approach 1:

The patent precisely controls the operating temperature of the light source to achieve accurate wavelength selection for detecting specific gases or isotopes. By carefully managing the temperature parameter, the system maintains measurement precision comparable to specialized single-gas detectors while benefiting from the simplified architecture of a universal detection platform

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The system employs feedback control to monitor and adjust the light source temperature, ensuring that the emitted wavelength accurately matches the absorption characteristics of the target gas or isotope. This feedback mechanism maintains high measurement precision despite the use of a single multi-functional light source

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables rapid and sensitive discrimination between various gases and their isotopes, improving detection accuracy and reducing costs by using a single setup for multiple gas analyses.

Implementation Method 1

a light beam of a selected frequency that is highly absorbed by the particular gas for which the instrument is designed is passed through a sample of the gas. The rate of absorption of the light beam is used as an indicator of the level of concentration of the gas in the sample.

Methodology Applied
Scientific EffectAbsorption spectroscopy: Absorption Spectroscopy

Implementation Method 2

changes the working or operating temperature of the light beam's source between that of a first light beam of a selected frequency that is highly absorbed by the first gas and that of a second light beam of selected frequency that is highly absorbed by the second gas

Methodology Applied
Scientific EffectTemperature-dependent wavelength shift:

Implementation Method 3

To increase the light beam's length of travel through the gas, the Herriot (multi-path) cell is used.

Methodology Applied
Scientific EffectMulti-pass optical path:

Data Source

PatentUS10775297B2Laser absorption spectroscopy system and method for discrimination of a first and a second gas
Publication Date: 2020.09.15 ECOTEC SOLUTIONS
  • US10775297B2 patent drawing
  • US10775297B2 patent drawing
  • US10775297B2 patent drawing

AI summary

A system and method to discriminate between a first preselected gas and at least one other preselected gas use of an absorption spectroscopy analyzer that includes a Herriott cell and a temperature sensitive light source. The light source operates at a temperature that emits a beam at a wavelength that corresponds to high absorption by a first preselected gas. When a predetermined level of this gas is detected in a gas sample, the analyzer changes the operating temperature of the light source to emit a beam at a wavelength that corresponds to high absorption by a second preselected gas. The second preselected gas can be a different isotope of the first preselected gas.