Nanoparticle Synthesis via Laser Vaporization and Electric Field

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Solution Overview

Problem

Current laser-based nanoparticle production methods face limitations such as low production rates, the need for costly vacuum equipment, and the simultaneous generation of unwanted fragments, particularly in laser ablation and pulsed laser deposition techniques.

Innovation Solution

A new technique involving the vaporization of precursor materials using a laser beam and a high-intensity electric field, which allows for the generation and collection of nanoparticles without the need for vacuum equipment, enabling higher production rates and controlled deposition of nanoparticles on substrates, with the ability to adjust nanoparticle size distribution through varying process parameters.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If laser ablation or pulsed laser deposition is used for nanoparticle production, then nanoparticles can be generated quickly without chemical methods, but the production rate remains low and unwanted fragments are simultaneously generated

Engineering Contradiction:
Improvenanoparticle production rateVSAvoidnanoparticle size uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The invention separates the nanoparticle generation process into distinct stages: vaporization of precursor material followed by controlled condensation in a supersaturated atmosphere. This segmentation allows nanoparticles to form independently without fragment generation, improving both production rate and size uniformity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the physical parameters of the process by creating a supersaturated vapor atmosphere through controlled cooling rates and vapor pressure conditions. This parameter change enables direct condensation into uniform nanoparticles without the ablation process that generates fragments

Inventive Principle:
Principle #35Parameter changes

2Reliability

If vacuum equipment is used for laser-based nanoparticle production, then the process can be controlled, but costly vacuum systems are required

Engineering Contradiction:
Improveprocess controlVSAvoidvacuum system requirement
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention replaces expensive vacuum systems with a simpler atmospheric pressure system that uses controlled vapor generation and cooling. The process operates in ambient atmosphere with controlled vapor pressure, eliminating the need for costly vacuum equipment while maintaining reliable process control

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The invention substitutes the mechanical vacuum system with a thermal and mass transfer-based system. Instead of removing air to create vacuum, the process uses controlled vaporization, supersaturation, and condensation in ambient atmosphere, replacing complex mechanical vacuum equipment with simpler thermal control mechanisms

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Productivity

If conventional chemical methods are used for nanoparticle synthesis, then large amounts of nanoparticles can be produced, but toxic chemicals are used

Engineering Contradiction:
Improvenanoparticle production scaleVSAvoidtoxic chemical usage
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The invention replaces chemical synthesis methods with a physical vaporization and condensation process. Precursor materials are vaporized by laser heating and then condensed in a supersaturated atmosphere to form nanoparticles, eliminating the need for toxic chemical reagents and reactions while maintaining scalable production

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Object-generated harmful factors

If biological methods are used for nanoparticle synthesis, then toxic chemicals are avoided, but polydispersity of formed nanoparticles is high

Engineering Contradiction:
Improvechemical toxicityVSAvoidnanoparticle size distribution
Core Design Contradiction:
Object-generated harmful factorsVSManufacturing precision

Solution Approach 1:

The invention achieves narrow size distribution by precisely controlling the physical parameters of vaporization and condensation. By controlling cooling rates, vapor pressure, and supersaturation levels, the process produces monodisperse nanoparticles without the polydispersity characteristic of biological methods, while still avoiding toxic chemicals

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method achieves higher nanoparticle generation rates, eliminates the need for costly vacuum systems, and allows for precise control over nanoparticle size and deposition, while avoiding the formation of unwanted fragments, thus improving the efficiency and scalability of nanoparticle production.

Implementation Method 1

irradiating with a laser beam a solid or liquid precursor material with a view to vaporizing same

Methodology Applied
Scientific EffectLaser heating: Laser

Implementation Method 2

vaporizing same by means of the action of the laser beam

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 3

the strong electric field existing at the tip of the electrode will cause the resulting vapors and the process atmosphere to be electrically charged

Methodology Applied
Scientific EffectIonization: Ionisation

Implementation Method 4

they will be entrained along the lines of the electric field to the counter electrode

Methodology Applied
Scientific EffectElectric wind: Ion Wind

Implementation Method 5

During movement, said supersaturated vapors will cool down more or less quickly depending on the speed of the existing gaseous stream, where vapors condensing and finally giving rise to nanoparticles by means of nucleation and growth processes

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 6

irradiating with a laser beam a solid or liquid precursor material

Methodology Applied
Scientific EffectLaser radiation: Laser

Data Source

PatentUS11148945B2Method assisted by a laser and high-intensity electric fields for the synthesis and collection of nanoparticles and the generation of coatings
Publication Date: 2021.10.19 UNIVE DE VIGO
  • US11148945B2 patent drawing
  • US11148945B2 patent drawing

AI summary

The present invention relates to a method for synthesizing and collecting, in a single step, nanoparticles of different materials, and for producing coatings thereof on materials with simple or complex geometries, both in a controlled atmosphere and in ambient conditions, by means of the combined application of a laser beam and high-intensity electric fields.