Laser-Engraveable Flexographic Precursor Composition
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Solution Overview
Problem
Flexographic printing precursors face challenges in achieving high imaging speed and quality while maintaining cost-effectiveness, with existing solutions often compromising on one aspect to improve another, and there is a need for improved sensitivity and manufacturability using near-IR laser-engraving without the drawbacks of carbon dioxide lasers.
Innovation Solution
A laser-engraveable composition comprising one or more elastomeric rubbers, specifically CLCB EPDM elastomeric rubbers, combined with near-infrared radiation absorbers and a vulcanizing composition, which includes a mixture of peroxides, to enhance imaging sensitivity and manufacturability, allowing for rapid compression recovery and improved physical properties.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Productivity
If direct laser engraving is used to achieve high imaging speed, then productivity is improved, but manufacturing precision deteriorates due to difficulty in achieving sufficient relief image depth
Solution Approach 1:
The patent changes the physical and chemical parameters of the laser-engraveable layer composition by incorporating specific elastomeric rubbers (EPDM, NBR, SBR) with controlled molecular weights and compositions, along with tailored fillers and curing agents. This enables the material to respond optimally to laser energy, achieving both high imaging speed and sufficient relief depth (50-500 μm) through enhanced laser sensitivity and ablation efficiency.
Solution Approach 2:
The patent creates a composite laser-engraveable layer composition combining multiple elastomeric rubber types (EPDM, NBR, SBR) with specific fillers (carbon black, metal oxides) and curing agents. This composite structure provides synergistic effects where the elastomeric matrix offers flexibility and laser responsiveness, while fillers enhance absorption and structural integrity, enabling simultaneous achievement of high imaging speed and manufacturing precision.
2Manufacturing precision
If high energy laser fluence is used to achieve sufficient relief depth, then manufacturing precision is improved, but use of energy increases
Solution Approach 1:
The patent modifies the material parameters of the laser-engraveable layer by incorporating elastomeric rubbers with specific molecular weights and compositions, along with tailored filler content and types. These parameter changes enhance the material's laser absorption coefficient and ablation efficiency, allowing sufficient relief depth (50-500 μm) to be achieved at lower laser fluence levels, thereby reducing energy consumption while maintaining manufacturing precision.
Solution Approach 2:
The patent replaces the need for high mechanical energy input (high laser fluence) with optimized material composition that inherently responds more efficiently to laser energy. The tailored elastomeric rubber-filler-curing agent system converts laser energy more effectively into material removal, substituting the need for brute-force high energy input with smart material design, thus reducing overall energy consumption while achieving required relief depths.
3Ease of manufacture
If conventional elastomeric systems are used for laser engraving, then ease of manufacture is maintained, but manufacturing precision deteriorates due to tar-like agglomerates and surface defects
Solution Approach 1:
The patent optimizes the compositional parameters of the elastomeric system by selecting specific rubber types (EPDM, NBR, SBR) with controlled molecular weights, adjusting filler content and distribution, and incorporating appropriate curing agents. These parameter changes prevent tar-like agglomerate formation during laser engraving by ensuring uniform material response and complete ablation, thereby achieving clean surfaces with excellent printability while maintaining ease of manufacture through conventional processing methods.
Solution Approach 2:
The patent develops a composite formulation combining multiple elastomeric rubber types with specifically selected fillers and curing agents. This composite structure prevents the formation of tar-like agglomerates by ensuring homogeneous material composition and consistent laser response throughout the layer. The synergistic interaction between components enables complete, clean ablation without surface defects, improving manufacturing precision while maintaining ease of manufacture through standard compounding and processing techniques.
4Manufacturing precision
If photosensitive layers with UV curing are used, then manufacturing precision is improved, but device complexity increases due to additional processing steps
Solution Approach 1:
The patent extracts and removes the photosensitive layer and UV curing step from the traditional flexographic printing precursor structure. By using a laser-engraveable layer composed of elastomeric rubbers with tailored fillers that directly respond to laser energy for relief image formation, the invention eliminates the need for separate photomask alignment, UV curing equipment, and liquid processing steps, thereby reducing device complexity while maintaining manufacturing precision through direct laser engraving.
Solution Approach 2:
The patent replaces the UV photopolymerization system (requiring photomasks, UV lamps, and liquid developers) with a direct laser engraving system using elastomeric rubber-based compositions. The laser-engraveable layer responds directly to laser energy through thermal and mechanical mechanisms, substituting the complex photochemical processing chain with a simpler, more direct energy-to-material transformation process, thus reducing device complexity while preserving image resolution.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The solution enables faster and more consistent laser engraving with improved resolution and durability, reducing equipment costs and maintaining high-quality printability, while minimizing tar-like agglomerates and surface defects.
Implementation Method 1
at least 2 phr and up to and including 30 phr of a near-infrared radiation absorber
Implementation Method 2
direct laser engraving (DLE) of a laser-engraveable composition (layer)
Implementation Method 3
a vulcanizing composition chosen from the group consisting of: (1) a sulfur composition, (2) a peroxide composition, or (3) a composition comprising a mixture of a sulfur composition and a peroxide composition
Data Source
AI summary
A laser-engraveable composition comprises one or more elastomeric rubbers including at least 10 parts of one or more CLCB EPDM elastomeric rubbers, based on parts per hundred of the total weight of elastomeric rubbers (phr). The laser-engraveable composition further comprises 2-30 phr of a near-infrared radiation absorber and either 1-80 phr of an inorganic, non-infrared radiation absorber filler, or a vulcanizing composition that comprises a mixture of at least two peroxides. One first peroxide has a t90 value of 1-6 minutes as measured at 160° C., and a second peroxide has a t90 value of 8-20 minutes as measured at 160° C. This laser-engraveable composition can be used to form various flexographic printing precursors that can be laser-engraved to provide relief images in flexographic printing plates, printing cylinders, or printing sleeves.