Selective Laser Etching for Dual-Finish Metal Coatings

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Solution Overview

Problem

Conventional chrome plating methods struggle to achieve a combination of matte and shiny finishes on the same part without compromising border definition and outdoor durability, particularly in automotive applications, due to the complexity of pretreatment processes and the use of organic layers.

Innovation Solution

A process involving selective etching of a metal layer using a Yag laser to create distinct textures and shines, followed by application of non-corrodible metals via PVD or electrolysis, allowing for homogeneous and resistant surfaces with varying finishes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If organic layers are applied partially on the chrome-plated shiny surface to create matte areas, then different finishes can be achieved, but border definition and outdoor durability (adherence, scratch resistance) are compromised

Engineering Contradiction:
Improvedifferent finishesVSAvoidadherence and scratch resistance
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent applies preliminary action by etching the nickel layer before applying the final chromium coating. The laser selectively removes nickel in desired matte areas, creating a textured substrate that is then covered with chromium. This ensures the chromium layer provides both the visual contrast and the required durability, eliminating the need for separate organic matte layers that compromised adherence and scratch resistance.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces the chemical/organic approach (applying organic matte layers) with a physical approach (laser etching). The laser ablates the nickel layer to create a textured surface, and the subsequent chromium deposition provides both the matte appearance and the required mechanical properties. This substitution eliminates the inherent weaknesses of organic layers while maintaining design flexibility.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Adaptability or versatility

If detachable elements are inserted to create matte and shiny areas, then different finishes can be achieved, but the part complexity and manufacturing process are increased

Engineering Contradiction:
Improvedifferent finishesVSAvoidprocess complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent applies segmentation by dividing the surface treatment into distinct zones (shiny and matte areas) through selective laser etching. The laser selectively removes nickel in specific patterns to create the desired matte regions, while leaving other areas intact for a shiny finish. This allows complex multi-finish designs to be achieved on a single integrated part without requiring separate detachable elements or multiple assembly steps.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent achieves universality by using a single chromium coating process that serves multiple functions: it provides corrosion protection, creates the final visual appearance, and maintains mechanical durability across both shiny and matte areas. The selective etching of nickel before chromium deposition allows one coating process to produce multiple surface finishes, eliminating the need for separate treatments or detachable elements for different regions.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Reliability

If conventional electrolytic baths are used for chrome plating, then corrosion protection is achieved, but plastics require complex pretreatment processes

Engineering Contradiction:
Improvecorrosion protectionVSAvoidpretreatment process
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by depositing a nickel layer and selectively etching it before the final chromium coating. This pre-treatment of the nickel layer creates a textured substrate that improves chromium adhesion and eliminates the need for complex plastic pretreatment processes. The nickel etching step prepares the surface in advance, ensuring reliable corrosion protection without requiring extensive plastic surface modification.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent introduces nickel as an intermediary layer between the plastic substrate and the final chromium coating. The nickel layer serves as a mediator that simplifies the pretreatment process - it can be selectively etched to create the desired surface texture and provide a reliable bonding interface for the chromium, avoiding the need for complex direct plastic pretreatment while ensuring corrosion protection.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables a part to have areas with different finishes without detachable elements or organic layers, ensuring outdoor and indoor durability with a seamless transition between mirror shine, matte, and intermediate tones, while maintaining resistance to external aggressions.

Implementation Method 1

The selective etching is performed by means of a laser which goes over the surface matting the desired area or areas

Methodology Applied
Scientific EffectLaser ablation: Laser Ablation

Implementation Method 2

These metals can be applied to the part by PVD or any other suitable technique

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentEP2470376B1Treatment of parts with metallized finish areas with a differentiated appearance
Publication Date: 2015.08.26 ZANINI AUTO GRUP

AI summary

The invention relates to a process for the treatment of parts for creating a surface with areas with shiny and matte appearances, in which on the surface previously coated with a first layer of copper and a second layer of metal a selective etching of the second layer is performed, wherein the selective etching of the second layer is performed according to the area or areas to be glazed with respect to the rest of the part. The process allows a finish with areas of a different shine (from mirror shine to matte), the differences in thickness of which cannot be observed by the human eye without optical aids.