Laser-Driven Hydrothermal Surface Removal for Controlled Decontamination

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Solution Overview

Problem

Current methods for removing the surface of materials like concrete, brick, and rock are either inefficient, lack control, or do not utilize transient dissolution as a primary mechanism, and traditional hydrothermal processing is slow and impractical for large-scale applications.

Innovation Solution

A pulsed-laser-based method that submerges materials in a fluid and directs laser pulses at the fluid-material interface to achieve gentle, energy-efficient, and controlled removal of surface material, allowing for hydrothermal processing and real-time contamination monitoring.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If traditional hydrothermal processing is used to grow purified crystals, then material purification and recrystallization are achieved, but the process duration is extremely long (15-25 days) and requires sustained high temperature and pressure containment vessels

Engineering Contradiction:
Improvematerial purificationVSAvoidprocess duration
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The patent applies periodic pulsed laser irradiation instead of continuous heating, delivering energy in short high-intensity pulses that create transient hydrothermal conditions. This periodic action achieves material purification and recrystallization in minutes rather than days, as the pulses repeatedly induce localized high-temperature high-pressure states that drive dissolution and reprecipitation cycles

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent dramatically changes the temperature and pressure parameters from sustained moderate conditions (traditional hydrothermal) to transient extreme conditions (laser-induced). The laser pulses create momentary temperatures of thousands of degrees and pressures of thousands of atmospheres that rapidly dissolve and reprecipitate materials, achieving purification in minutes instead of weeks

Inventive Principle:
Principle #35Parameter changes

2Productivity

If laser scabbling is used to remove surface material, then material removal is achieved, but the process lacks gentle control and precision, causing uncontrolled flaking and cracking

Engineering Contradiction:
Improvematerial removal rateVSAvoidcontrol precision
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent changes the laser parameter regime from high-power continuous or long-pulse operation (causing thermal damage) to low-power short-pulse operation. By using pulses with energy below the ablation threshold but sufficient to induce hydrothermal dissolution, the process achieves gentle material removal with μm-scale precision and no uncontrolled flaking or cracking

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the mechanical fracture mechanism of laser scabbling (thermal stress-induced cracking and flaking) with a chemical dissolution mechanism. The laser-induced hydrothermal process dissolves material at the molecular level through transient high-temperature water interaction, then reprecipitates purified material, eliminating uncontrolled mechanical failure modes

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Productivity

If intense laser pulses are used to generate plasma at metal-water interface, then material removal is achieved, but the process is inappropriate for energy-efficient gentle and controlled processing of dielectric materials

Engineering Contradiction:
Improvematerial removal efficiencyVSAvoidenergy efficiency
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent applies partial action by using laser pulse energies deliberately kept below the threshold required to generate plasma or cause ablation. This sub-threshold energy level is sufficient to induce hydrothermal dissolution through transient heating but avoids the excessive energy consumption and uncontrolled material removal associated with plasma generation, achieving energy-efficient gentle processing

Inventive Principle:
Principle #16Partial or excessive action

Solution Approach 2:

The patent introduces water as an intermediary medium between the laser and the dielectric material. The laser heats the water rather than directly heating the material, and the hot water acts as the primary agent for material dissolution and removal. This intermediary approach enables energy-efficient processing by using water's high specific heat capacity to distribute and control energy delivery

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables efficient, controlled removal and recrystallization of materials, effectively decontaminating surfaces while containing hazardous materials and providing precise profiling of contamination levels, with reduced energy consumption and no hazardous aerosol release.

Implementation Method 1

absorption of the laser pulse on the surface of the solid heats the surface and the adjacent fluid

Methodology Applied
Scientific EffectLaser heating: Laser

Implementation Method 2

heats the surface and collaterally generates a transient thin layer of high-pressure and high-temperature water

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 3

absorption of the laser pulse on the surface of the solid heats the surface

Methodology Applied
Scientific EffectAbsorption of electromagnetic radiation: Absorption (EM radiation)

Data Source

PatentUS11358237B2Laser-driven hydrothermal processing
Publication Date: 2022.06.14 LAWRENCE LIVERMORE NAT SECURITY LLC
  • US11358237B2 patent drawing
  • US11358237B2 patent drawing

AI summary

Systems for processing a material by submerging the material in a fluid and directing laser pulses at the fluid and the material for processing the material. An embodiment removes the surface of concrete, brick, or rock or minerals in a relatively gentle, energy-efficient, and controlled manner that also confines the material that is removed.