Laser Melting Tablet Production for Matrix Effect Reduction

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Solution Overview

Problem

Existing methods for producing tablets from sample materials face challenges in achieving precise control over the melting and solidification processes, which can result in cracking, crystallization, or loss of strength, especially in the case of orodispersible tablets that require controlled cooling.

Innovation Solution

The method involves using laser radiation, plasma radiation, or electron beams to melt a mixture of sample material and flux, with real-time monitoring and power control to achieve precise energy input, allowing for rapid and controlled melting and solidification, and optionally grinding the sample material to a fine particle size before mixing with the flux to enhance homogenization.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the melt is cooled quickly to prevent crystallization, then the tablet maintains strength, but the tablet may crack

Engineering Contradiction:
Improvetablet strengthVSAvoidcracking
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent applies dynamic control of the cooling process by adjusting cooling rate based on real-time monitoring of melt temperature and viscosity. The system transitions from rapid cooling to controlled cooling at different stages, allowing the tablet to maintain strength while preventing cracking through adaptive process control.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent implements feedback control by monitoring melt temperature and cooling rate in real-time, and adjusting the cooling process accordingly. Sensors detect the state of the melt and provide feedback to the control system, which modifies cooling parameters to prevent both crystallization and cracking, resolving the contradiction between maintaining strength and avoiding defects.

Inventive Principle:
Principle #23Feedback

2Stability of the object's composition

If the melt is cooled slowly to allow controlled solidification, then crystallization is avoided, but the tablet loses strength

Engineering Contradiction:
Improvecompositional uniformityVSAvoidtablet strength
Core Design Contradiction:
Stability of the object's compositionVSStrength

Solution Approach 1:

The patent uses dynamic cooling rate adjustment to optimize both compositional uniformity and tablet strength. By varying the cooling rate during different stages of solidification and applying real-time monitoring, the system achieves controlled solidification that maintains strength while ensuring compositional homogeneity.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent changes physical parameters during the cooling process, including temperature, cooling rate, and atmospheric conditions. These parameter changes are optimized to achieve the desired balance between avoiding crystallization and maintaining tablet strength, resolving the contradiction between compositional stability and mechanical strength.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional heating methods are used to melt the sample material, then the process is simple, but the melting process cannot be precisely controlled

Engineering Contradiction:
Improveprocess simplicityVSAvoidmelting control precision
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent replaces conventional mechanical or thermal heating systems with laser radiation for melting the sample material. This substitution enables precise control of the melting process through laser power modulation, focusing, and scanning control, while maintaining ease of manufacture through automated laser systems with user-friendly interfaces.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent utilizes laser parameters such as power, pulse duration, scanning speed, and focal position to precisely control the melting process. By adjusting these parameters, the system achieves accurate control over melting while keeping the process relatively simple through automated parameter control and real-time monitoring.

Inventive Principle:
Principle #35Parameter changes

4Productivity

If the tablet production process is accelerated to improve productivity, then output increases, but control over melting and solidification deteriorates

Engineering Contradiction:
Improvetablet production rateVSAvoidmelting and solidification control
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent implements continuous laser melting and continuous monitoring during the tablet production process. This continuous action allows for accelerated production while maintaining precise control through real-time feedback, as the laser can continuously melt material and the system can continuously adjust parameters without interruption or batch processing delays.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent employs real-time feedback control during accelerated tablet production, where sensors continuously monitor the melting and solidification processes even at high speeds. The control system rapidly adjusts laser parameters and cooling conditions based on this feedback, enabling both high productivity and precise control to be achieved simultaneously.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of tablets with a homogeneous, chemically uniform melt that minimizes the effects of grain size distribution and mineralogical properties, improving analysis by reducing the matrix effect and maintaining sample homogeneity, while also allowing for rapid production and precise control over the melting process.

Implementation Method 1

the sample material-melting agent mixture is melted by means of laser radiation

Methodology Applied
Scientific EffectLaser radiation: Laser

Implementation Method 2

a very precisely definable, locally delimitable and locally very high energy input into the mixture of sample material and flux to be melted

Methodology Applied
Scientific EffectThermal energy transfer: Heating

Implementation Method 3

the sample material-melting agent mixture is melted by means of laser radiation, plasma radiation and/or electron beams

Methodology Applied
Scientific EffectPlasma radiation: Plasma

Implementation Method 4

the sample material-melting agent mixture is melted by means of laser radiation, plasma radiation and/or electron beams

Methodology Applied
Scientific EffectElectron beam heating: Electron Beam

Implementation Method 5

the mixture of sample material and flux is melted and the melt is solidified, the solidified melt being in the form of a tablet

Methodology Applied
Scientific EffectSolidification: Freezing

Data Source

PatentEP3265776B1Method for producing a tablet which comprises a sample material
Publication Date: 2019.05.08 THYSSENKRUPP IND SOLUTIONS AG
  • EP3265776B1 patent drawingFigure 1~2
  • EP3265776B1 patent drawingFigure 3
  • EP3265776B1 patent drawingFigure 4

AI summary

The invention relates to a method for producing a tablet which comprises a sample material, the sample material being mixed at least to some extent with a melting agent, the mixture of sample material and melting agent at least partially being molten and the melt being caused to solidify, the solidified melt having tablet form or being converted to tablet form. Said method is characterized by melting the mixture of sample material and melting agent by means of laser radiation, plasma radiation and/or electron radiation.