Laser Structuring Metal-Polymer Adhesion

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Solution Overview

Problem

Existing methods for joining metal and polymer materials face challenges such as poor adhesion, uneven anti-corrosion coating thickness, high energy and time consumption, and material inefficiency, particularly when dealing with corrosion-resistant steel.

Innovation Solution

A process involving pulsed laser surface structuring of metal workpieces to create microgrooves with specific dimensions and nanostructures, enhancing adhesion and allowing uniform anti-corrosion coating, while being time and energy efficient for various metal materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If ultrashort pulsed laser illumination is used to create deep recesses with depth/diameter ratio ≥5, then form-locked joint is improved, but air entrapment increases reducing contact area and adhesion

Engineering Contradiction:
Improveform-locked joint strengthVSAvoidadhesion quality
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent changes the depth/diameter ratio parameter from ≥5 (prior art) to <5 (specifically 0.5-4.0), which fundamentally alters the recess geometry to prevent air entrapment while maintaining form-locked joint strength. This parameter modification resolves the contradiction by eliminating the root cause of air pocket formation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs periodic laser pulsing with specific duty cycles and repetition rates to create the optimized microstructure. The periodic action allows controlled material removal that forms open recesses rather than closed deep cavities, preventing air entrapment while maintaining mechanical interlocking.

Inventive Principle:
Principle #19Periodic action

2Reliability

If conventional laser surface structuring is used, then adhesion is improved, but processing time and energy consumption increase

Engineering Contradiction:
Improveadhesion qualityVSAvoidprocessing speed
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The use of ultrashort pulsed laser with high repetition rates enables rapid material processing through accumulated ablation. The periodic pulsing delivers high peak power for efficient material removal while the short duty cycle prevents heat accumulation, achieving fast processing speeds with superior adhesion quality.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The ultrashort laser pulses induce direct phase transitions from solid to vapor through ablation, bypassing the melting stage. This phase transition mechanism enables extremely rapid material removal with minimal heat affected zone, significantly reducing processing time while creating optimal surface microstructure for adhesion.

Inventive Principle:
Principle #36Phase transitions

3Object-affected harmful factors

If electroplating is applied to laser-structured surfaces with deep recesses, then corrosion protection is improved, but coating uniformity deteriorates due to current concentration and capillary effects

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidcoating thickness uniformity
Core Design Contradiction:
Object-affected harmful factorsVSManufacturing precision

Solution Approach 1:

By changing the recess depth parameter to maintain depth/diameter ratio <5, the patent eliminates the geometric conditions that cause current concentration and capillary effects during electroplating. The modified geometry allows uniform current distribution and coating deposition, achieving both corrosion protection and coating uniformity.

Inventive Principle:
Principle #35Parameter changes

4Loss of substance

If adhesive bonding is used for joining metal and polymer, then material consumption is reduced, but joint strength becomes highly sensitive to temperature and humidity fluctuations

Engineering Contradiction:
Improvematerial consumptionVSAvoidjoint strength stability
Core Design Contradiction:
Loss of substanceVSReliability

Solution Approach 1:

The patent creates a composite surface structure combining macroscopic form-locked recesses with microscopic roughness features. This composite structure enables both mechanical interlocking and increased surface area for chemical bonding, achieving joint strength that is insensitive to environmental conditions while using minimal material.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process ensures strong adhesion between metal and polymer, uniform anti-corrosion coating, and reduces material and energy consumption, making it suitable for mass production and various metal materials, including corrosion-resistant steel.

Implementation Method 1

providing a laser device comprising a pulsed laser source... The metal workpiece material illuminated by the laser beam is instantaneously vaporized due to the high energy concentration, which, in combination with the moving laser beam, leads to the formation of narrow grooves

Methodology Applied
Scientific EffectLaser ablation: Laser Ablation

Implementation Method 2

a portion of the metal workpiece material illuminated by the laser beam is merely melted and the overpressure due to the aforementioned metal vapours pushes the melt along the walls of the groove to the outside

Methodology Applied
Scientific EffectLaser heating: Heating

Implementation Method 3

the overpressure due to the aforementioned metal vapours pushes the melt along the walls of the groove

Methodology Applied
Scientific EffectVapor pressure: Vapour Pressure

Implementation Method 4

Part of the metal vapours condenses on the needle surface, forming additional nanostructures after solidification

Methodology Applied
Scientific EffectCondensation: Condensation

Data Source

PatentEP4344814A1Process for surface structuring of a metal workpiece and process for producing a hybrid product from a metal workpiece and a polymer material
Publication Date: 2024.04.03 ISKRA ISD D O O
  • EP4344814A1 patent drawingFigure 1~2
  • EP4344814A1 patent drawing
  • EP4344814A1 patent drawing

AI summary

The invention relates to a process for surface structuring of a metal workpiece and process for producing a hybrid product from a metal workpiece and a polymer material. The technical problem is how to provide a time and energy efficient process that will ensure good adhesion between the metal and the polymer. The technical problem is solved by a process comprising providing a metal workpiece, providing a laser device comprising a pulsed laser source and a controller adapted to control the laser, providing scanning-focusing optics for guiding and focusing the laser beam, the scanning-focusing optics being adapted to guide the laser beam over the surface of the metal workpiece.