Laser Polishing Ceramic Surfaces for Semiconductor Processing

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Solution Overview

Problem

As-deposited ceramic coatings on semiconductor manufacturing equipment often have high surface roughness and porosity, leading to cracking, flaking, and particle contamination in plasma processing chambers, which can render devices inoperable and reduce yield.

Innovation Solution

Laser polishing methods using a pulsed laser beam with a frequency of 50 kHz or more and a spot size of 10 mm² or less are applied to ceramic substrates or coated substrates to reduce surface roughness and porosity, allowing for precision sub-millimeter scale polishing without substantial material removal.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If as-deposited ceramic coatings are used to protect processing components, then resistance to chemical corrosion and plasma erosion is improved, but surface roughness and porosity increase leading to cracking and flaking

Engineering Contradiction:
Improveresistance to chemical corrosion and plasma erosionVSAvoidsurface roughness
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies laser polishing with specific parameters (pulse frequency of 1-100 kHz, spot size of 0.1-10 mm, power density of 10-1000 W/mm²) to modify the surface parameters of ceramic coatings. This changes the physical state of the coating surface, reducing roughness and porosity while maintaining the protective properties of the ceramic material.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces traditional mechanical polishing methods with laser-based surface modification. The laser beam scans across the ceramic surface, melting and re-solidifying the material to create a smooth surface without mechanical contact, thereby avoiding further damage to the brittle ceramic coating.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Manufacturing precision

If traditional polishing methods are used on ceramic coatings, then surface roughness is reduced, but substantial material removal occurs compromising coating integrity

Engineering Contradiction:
Improvesurface roughnessVSAvoidceramic coating material
Core Design Contradiction:
Manufacturing precisionVSLoss of substance

Solution Approach 1:

The patent replaces mechanical polishing with laser surface melting. The laser beam delivers controlled thermal energy to the ceramic surface, melting a thin layer that then re-solidifies as a smooth surface. This non-contact method removes minimal material while achieving the desired surface finish.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent utilizes the phase transition of ceramic material from solid to liquid and back to solid through controlled laser heating. The laser beam heats the surface above the melting point, creates a molten layer, and upon cooling, this layer solidifies with reduced roughness and porosity, preserving the underlying coating structure.

Inventive Principle:
Principle #36Phase transitions

3Reliability

If high surface roughness ceramic coatings are used, then protective properties are maintained, but particle contamination occurs rendering devices inoperable

Engineering Contradiction:
Improveprotective properties of ceramic coatingVSAvoidparticle contamination
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent modifies the surface parameters of the ceramic coating through laser polishing. By controlling laser parameters (pulse frequency, spot size, power density), the surface roughness is reduced from micrometer-scale to sub-micrometer-scale, eliminating the rough features that would otherwise generate particles during plasma processing.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the inherently rough and porous nature of as-deposited ceramic coatings into a smooth, dense surface through laser-induced melting and re-solidification. The same material that initially causes particle contamination is transformed into a particle-free protective surface that maintains all the original protective properties.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The laser polishing methods effectively reduce surface roughness by over 10% and porosity by over 30%, extending the lifetime of processing components by preventing cracking and flaking, and maintaining the integrity of patterned surfaces in plasma processing chambers.

Implementation Method 1

scanning at least a portion of the workpiece surface with a pulsed laser beam

Methodology Applied
Scientific EffectLaser heating: Laser

Implementation Method 2

laser polishing methods using a pulsed laser beam with a frequency of 50 kHz or more and a spot size of 10 mm² or less are applied to ceramic substrates or coated substrates to reduce surface roughness and porosity

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentUS20190291214A1Laser polishing ceramic surfaces of processing components to be used in the manufacturing of semiconductor devices
Publication Date: 2019.09.26 APPLIED MATERIALS INC
  • US20190291214A1 patent drawing
  • US20190291214A1 patent drawing
  • US20190291214A1 patent drawing

AI summary

Embodiments of the present disclosure provide methods of laser assisted modification, i.e., laser polishing, of ceramic substrates, or ceramic coated substrates, to desirably reduce the surface roughness and porosity thereof. In one embodiment, a method of laser polishing a workpiece surface includes scanning at least a portion of the workpiece surface with a pulsed laser beam. The laser beam has a pulse frequency of about 50 kHz or more and a spot size of about 10 mm2 or less and the workpiece surface comprises a ceramic material.