Laser Sealing of Ceramic Base and Glass Substrate

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Solution Overview

Problem

Laser sealing methods face challenges in increasing bonding strength between the element base and the sealing material layer in hermetic packages, particularly when the element base is made of ceramic, leading to thermal degradation and reduced long-term reliability.

Innovation Solution

A method involving the formation of a sealing material layer on a ceramic base through firing, followed by laser sealing with a glass substrate to enhance bonding strength, using a bismuth-based glass with refractory fillers to ensure a sufficient reaction layer and improved thermal stability, while maintaining the hermetic integrity of the package.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If laser sealing is used to seal the element base and glass substrate, then thermal degradation of the element is prevented, but bonding strength between the element base and sealing material layer is insufficient

Engineering Contradiction:
Improveprevention of thermal degradationVSAvoidbonding strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The sealing material layer is formed on the element base before the laser sealing process. This preliminary formation allows the sealing material to be in close contact with the element base surface, ensuring strong bonding while maintaining the advantages of laser sealing. The sealing material layer is applied, dried, and fired before the actual sealing operation, creating a prepared interface for strong bonding.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent controls the thickness of the sealing material layer within a specific range (1-10 μm) to optimize both bonding strength and laser sealing effectiveness. By adjusting this parameter, the patent achieves sufficient bonding strength while maintaining the rapid heating characteristics of laser sealing that prevent thermal degradation of the element.

Inventive Principle:
Principle #35Parameter changes

2Strength

If traditional firing sealing is used to increase bonding strength, then bonding strength between element base and sealing material layer is improved, but thermal degradation of the element occurs

Engineering Contradiction:
Improvebonding strengthVSAvoidprevention of thermal degradation
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent replaces traditional thermal firing sealing with laser sealing. Instead of using conventional heating methods that cause thermal degradation, the patent employs laser energy to rapidly heat and melt the sealing material layer, achieving strong bonding without subjecting the temperature-sensitive element to prolonged high-temperature exposure.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent utilizes the phase transition of the sealing material from solid to liquid state through rapid laser heating. The sealing material is heated above its melting point, flows to fill gaps and create strong bonds, then rapidly cools and solidifies, forming a strong bond between the element base and glass substrate without prolonged thermal exposure to the element.

Inventive Principle:
Principle #36Phase transitions

3Productivity

If the sealing material layer is formed thinly for laser sealing, then the sealing process is rapid, but the reaction layer is insufficient and bonding strength decreases

Engineering Contradiction:
Improvesealing speedVSAvoidbonding strength
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The patent optimizes the thickness of the sealing material layer to a specific range (1-10 μm) that balances sealing speed and bonding strength. This parameter control ensures the layer is thin enough for rapid laser heating and sealing while being sufficiently thick to generate an adequate reaction layer and achieve strong bonding.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a sealing material comprising glass powder and refractory filler in specific proportions. This composite composition enables the material to form a strong reaction layer rapidly under laser heating, achieving both high bonding strength and fast sealing speed by combining the reactivity of glass with the thermal stability of refractory materials.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly increases the bonding strength between the ceramic base and the sealing material layer, preventing thermal degradation and enhancing the long-term reliability of the hermetic package by ensuring a strong and stable seal.

Implementation Method 1

irradiating the sealing material layer with laser light from a glass substrate side to seal the ceramic base and the glass substrate with each other through intermediation of the sealing material layer

Methodology Applied
Scientific EffectLaser heating: Laser

Implementation Method 2

the laser sealing is a method involving locally heating the sealing material layer to cause the sealing material layer to soften and flow

Methodology Applied
Scientific EffectLight absorption and thermal conversion: Absorption (EM radiation)

Implementation Method 3

locally heating the sealing material layer to cause the sealing material layer to soften and flow

Methodology Applied
Scientific EffectSoftening and flowing: Melting

Implementation Method 4

reaction time between the element base and the sealing material layer is also shortened. As a result, a reaction layer is not sufficiently generated at an interface between the element base and the sealing material layer

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS10600954B2Method for producing hermetic package
Publication Date: 2020.03.24 NIPPON ELECTRIC GLASS CO LTD
  • US10600954B2 patent drawing
  • US10600954B2 patent drawing

AI summary

A technical object of the present invention is to devise a method by which bonding strength between an element base and a sealing material layer can be increased without thermal degradation of a member to be housed inside, to thereby improve long-term reliability of a hermetic package. A method of producing a hermetic package of the present invention includes the steps of: preparing a ceramic base and forming a sealing material layer on the ceramic base; preparing a glass substrate and arranging the ceramic base and the glass substrate so that the glass substrate is brought into contact with the sealing material layer on the ceramic base; and irradiating the sealing material layer with laser light from a glass substrate side to seal the ceramic base and the glass substrate with each other through intermediation of the sealing material layer, to thereby provide a hermetic packages.