Laser Spectrometer for On-Site Drilling Mud Isotope Analysis

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Solution Overview

Problem

Existing devices for analyzing the gaseous content of drilling muds, particularly for measuring carbon isotopes, are unsuitable for on-site use due to the need for constant pressure and temperature conditions, making off-line laboratory analysis necessary.

Innovation Solution

A device comprising a gas-phase chromatograph, combustion oven, and an optical measurement unit with a laser and sensor for on-line analysis, allowing precise quantification of gaseous constituents in drilling muds near an oil well, using a polymer transport line and a vacuum pump for gas extraction and analysis.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If an IRMS is used for precise isotope analysis, then measurement precision is improved, but device complexity and climate control requirements increase, making on-site operation difficult

Engineering Contradiction:
Improveisotope analysis precisionVSAvoidclimate control assembly complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent extracts the measurement function from the complex climate-controlled IRMS environment by using a laser spectrometer that can operate directly in the drilling environment without requiring constant temperature and pressure control. The laser spectrometer measures isotopic ratios of carbon compounds directly in the drilling mud gas phase, eliminating the need for complex climate control assemblies while maintaining measurement precision.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent replaces the mechanical climate control system with an optical measurement system. Instead of using a complex IRMS that requires temperature and pressure stabilization, the invention uses a laser spectrometer with optical cavities that can measure isotopic compositions directly in the uncontrolled drilling environment, substituting mechanical environmental control with optical measurement resilience.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Measurement precision

If a climate-controlled laboratory is used for analysis, then measurement precision is maintained, but loss of time and productivity increase due to off-line analysis

Engineering Contradiction:
Improveanalysis precisionVSAvoidanalysis time delay
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent implements preliminary action by deploying the laser spectrometer directly at the drilling site, allowing real-time measurement of isotopic ratios as drilling proceeds. This eliminates the need to collect samples and transport them to a laboratory for later analysis, enabling continuous monitoring and immediate geological interpretation without time loss.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The system performs self-service analysis by measuring isotopic compositions directly in the drilling environment without requiring external laboratory facilities. The laser spectrometer processes the gas phase samples from drilling mud on-site, making the system autonomous and eliminating dependence on off-line laboratory analysis infrastructure.

Inventive Principle:
Principle #25Self-service

3Device complexity

If a simple optical measurement system is used, then device complexity is reduced for on-site operation, but measurement precision may deteriorate

Engineering Contradiction:
Improveinstrumentation simplicityVSAvoidquantification precision
Core Design Contradiction:
Device complexityVSMeasurement precision

Solution Approach 1:

The patent enhances the simple optical measurement system by introducing an optical cavity dimension that increases the effective path length of laser light through the sample. The optical cavity allows multiple passes of the laser beam through the gas phase sample, increasing absorption signal strength and enabling precise isotopic ratio measurements with a relatively simple laser spectrometer configuration.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

The system uses periodic modulation of the laser frequency to scan through specific absorption lines of carbon isotopes. This periodic frequency modulation allows the simple optical system to distinguish between different isotopic species by detecting their characteristic absorption frequencies, maintaining measurement precision through frequency-domain analysis rather than requiring complex physical separation systems.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables precise, on-line analysis of gaseous constituents, including isotopic ratios, in a hostile environment without the need for a climate-controlled assembly, simplifying the instrumentation and allowing for on-site operation.

Implementation Method 1

a laser for emitting a beam, a sensor for detecting the transmitted beam

Methodology Applied
Scientific EffectAbsorption spectroscopy: Absorption Spectroscopy

Data Source

PatentEP2062031B1Device for quantifying the content of at least one gaseous constituent contained in a gaseous sample from a fluid, related assembly and process
Publication Date: 2018.10.10 GEOSERVICES EQUIP SAS
  • EP2062031B1 patent drawingFigure 1
  • EP2062031B1 patent drawingFigure 2
  • EP2062031B1 patent drawingFigure 3

AI summary

This device comprises a means (111) for forming a gaseous flow from the sample, and a means (121) for separation by means of selective retention each gaseous constituent. It comprises a means (113) for combustion of the gaseous flow in order to form a gaseous residue from each constituent, and a means (115) for quantifying the content of each constituent to be analysed in the gaseous flow. The quantification means (115) comprise an optical measurement cell (127) which is connected to the combustion means (113), and a means (161) for introducing a laser incident optical signal into the cell (127). The quantification means (115) also comprise means (133) for measuring a transmitted optical signal resulting from an interaction between the optical signal and each gaseous residue in the cell (127), and means (125) for calculating said content on the basis of the transmitted optical signal.