Laser-Textured Thin-Film Semiconductors for Enhanced Light Absorption

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Solution Overview

Problem

Existing photovoltaic devices face challenges in enhancing light absorption without increasing thickness, which is costly and prone to degradation, and traditional texturing methods are difficult to implement on thin-film devices.

Innovation Solution

A method involving laser-texturing of semiconductor layers by applying pulsed laser pulses to melt and ablate the surface, creating a textured surface that enhances light absorption through refractive effects without significant material removal, allowing for thin absorber layers and improved optical path lengths.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If the thickness of photovoltaic device layers is increased to enhance light absorption, then light absorption improves, but manufacturing cost increases and device reliability deteriorates due to carrier diffusion length limitations

Engineering Contradiction:
Improvelight absorptionVSAvoiddevice reliability
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent transitions from increasing thickness (one dimension) to creating surface texture (another dimension). By texturing the rear surface with pyramidal structures, the optical path length is extended without increasing the physical thickness of the absorber layer, thus maintaining reliability while improving light absorption.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

The patent employs curved/pyramidal surface structures instead of flat surfaces. The pyramidal texture creates multiple reflections and extends the optical path length through curved light trajectories, enhancing absorption without requiring increased material thickness.

Inventive Principle:
Principle #14Spheroidality (Curvature)

2Use of energy by moving object

If the thickness of photovoltaic device layers is increased to enhance light absorption, then light absorption improves, but manufacturing cost increases

Engineering Contradiction:
Improvelight absorptionVSAvoidmanufacturing cost
Core Design Contradiction:
Use of energy by moving objectVSEase of manufacture

Solution Approach 1:

Instead of manufacturing thicker layers (increasing material consumption and processing complexity), the patent applies surface texturing to the existing thin-film structure. This dimensional approach allows standard thin-film manufacturing processes to be used while achieving enhanced absorption through optical path extension via pyramidal structures.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach increases light absorption and external quantum efficiency, improving short circuit current and light scattering while maintaining thin device thickness, making it suitable for non-terrestrial applications.

Implementation Method 1

texturing a surface of the semiconductor layer by applying one or more laser pulses to the surface of the semiconductor to form a textured surface, each of the one or more laser pulses causing at least a partial melting of the surface of the semiconductor

Methodology Applied
Scientific EffectLaser heating: Laser

Implementation Method 2

each of the one or more laser pulses causing at least a partial melting of the surface of the semiconductor

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 3

texturing a surface of the semiconductor layer by applying one or more laser pulses to the surface of the semiconductor to form a textured surface

Methodology Applied
Scientific EffectAblation: Ablation

Implementation Method 4

The laser-textured surface, which is formed on a semiconductor layer including a compound semiconductor material such as a group III-V semiconductor material, may cause a longer path for light to travel within the photovoltaic devices resulting in improved light absorption

Methodology Applied
Scientific EffectRefraction: Refraction

Data Source

PatentUS11393938B2Laser-textured thin-film semiconductors by melting and ablation
Publication Date: 2022.07.19 UTICA LEASECO LLC
  • US11393938B2 patent drawing
  • US11393938B2 patent drawing
  • US11393938B2 patent drawing

AI summary

A photovoltaic device and a method of making the photovoltaic device are disclosed. The photovoltaic device may include a semiconductor layer epitaxially grown using a compound semiconductor material, such as a group III-V semiconductor material, wherein a surface of the semiconductor layer is textured via one or more laser pulses of a laser. The photovoltaic device may also include a dielectric layer deposited over the textured surface of the semiconductor layer, and a back metal reflector provided on the dielectric layer. The textured surface extends a path of light traveling through the photovoltaic device to increase absorption of the light within the photovoltaic device.