Laser Metal-Ceramic Conversion for Titanium Surface Hardness

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Solution Overview

Problem

Existing methods for treating titanium alloys, such as nitriding, result in long and costly processes with thin nitride layers and shallow nitrogen penetration, leading to weak support for hard and brittle nitride layers, and issues with surface uniformity and quality due to variations in material mixing and machining processes.

Innovation Solution

A method involving physical conversion using waveform energy to create a gradient of metal/ceramic ratios, where the surface is machined to uniformity and treated with laser energy to achieve comparable hardness between original and machined surfaces, resulting in a metal ceramic article with a core, intermediate layer, and outer ceramic layer, allowing for controlled ceramic conversion and uniformity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If nitriding is performed in vacuum furnaces, then ceramic titanium nitrides are formed on the surface, but the process is long and costly with thin nitride layers and shallow nitrogen penetration

Engineering Contradiction:
Improvenitride layer qualityVSAvoidprocess duration
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The patent replaces the traditional thermal field-based nitriding process with a laser-based energy conversion process. Laser energy is applied to the titanium surface to directly convert metal to ceramic through localized heating and phase transformation, eliminating the need for prolonged vacuum furnace heating and achieving deeper nitrogen penetration and thicker nitride layers in shorter time.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the energy delivery parameters from conventional thermal field to laser field, and controls the conversion depth by adjusting laser parameters. This enables precise control over the ceramic layer thickness and nitrogen penetration depth, achieving superior nitride layer quality without the extended processing time required by traditional vacuum furnace methods.

Inventive Principle:
Principle #35Parameter changes

2Strength

If conventional nitriding is used, then surface hardness is increased, but the nitride layers are brittle and require strong support from nitrogen diffusion in the bulk metal

Engineering Contradiction:
Improvesurface hardnessVSAvoidnitride layer support
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies laser energy locally to the titanium surface, creating a controlled gradient of ceramic conversion from the surface into the bulk metal. This localized energy input produces a nitrogen concentration gradient that provides strong support to the brittle nitride layer while maintaining surface hardness, addressing both the hardness requirement and the support reliability issue simultaneously.

Inventive Principle:
Principle #3Local quality

3Manufacturing precision

If laser energy is applied to convert metal to ceramic, then physical conversion occurs with controlled gradient, but the oxide layer must be removed to enable uniform conversion

Engineering Contradiction:
Improveconversion uniformityVSAvoidsurface preparation complexity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent performs preliminary surface preparation by removing the natural oxide layer from the titanium surface before applying laser energy for ceramic conversion. This preliminary action ensures uniform laser energy absorption and consistent ceramic formation across the entire surface, achieving precise conversion control without the variability introduced by uneven oxide layers.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the creation of durable and uniform ceramic articles with bespoke configurations, improving surface and interior properties, reducing material waste, and enhancing the durability and utility of titanium-based components across various fields.

Implementation Method 1

physical conversion using waveform energy to create a gradient of metal/ceramic ratios

Methodology Applied
Scientific EffectLaser heating: Laser

Implementation Method 2

An outer layer of the metal ceramic is transformed via physical conversion of the metal to the metal ceramic

Methodology Applied
Scientific EffectPhysical conversion: Phase Change

Implementation Method 3

The physical conversion occurs by waveform conversion in utilizing wave energy for localized conversion

Methodology Applied
Scientific EffectWave energy conversion: Electromagnetic Induction

Implementation Method 4

the nitriding process also results in a second metallic layer portion where nitrogen is diffused into the titanium alloy just beneath the ceramic layer

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 5

The secondary chemical is removed to a large extent

Methodology Applied
Scientific EffectLaser ablation: Laser Ablation

Data Source

PatentUS11993840B2Asynchronous conversion of metals to metal ceramics
Publication Date: 2024.05.28 INTALUS INC
  • US11993840B2 patent drawing
  • US11993840B2 patent drawing
  • US11993840B2 patent drawing

AI summary

A metal-ceramic article and method for creating the same is disclosed in which the article has undergone machining to remove outer surface volume. The intermediate layer of the article includes a gradient of a metal and metal-ceramic that diminishes toward a metal core.