Latent Epoxy Curing Catalyst for Low-Temperature Stability
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Solution Overview
Problem
Epoxy resin compositions face issues with low-temperature curability and storage stability due to existing curing catalysts, leading to non-uniform curing and deterioration in mechanical, electrical, and chemical properties of molded articles.
Innovation Solution
A curing catalyst represented by Formula 1, which catalyzes curing at low temperatures while maintaining high storage stability and minimizing viscosity changes, is introduced. This catalyst is specifically designed to decompose and initiate curing between 100°C to 150°C, ensuring controlled curing and maintaining flowability.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Temperature
If a curing catalyst that catalyzes curing even at relatively low temperatures is used, then low-temperature curability is improved, but storage stability deteriorates because the epoxy resin composition undergoes partial curing during storage
Solution Approach 1:
The patent uses an adduct of triphenylphosphine and 1,4-benzoquinone as a latent curing catalyst that acts as an intermediary. This adduct remains stable during storage but decomposes at curing temperature to release the active catalyst, thereby mediating between storage stability requirements and low-temperature curability needs
Solution Approach 2:
The patent changes the chemical state of the curing catalyst by forming an adduct that is stable at storage temperature but decomposes at curing temperature. This parameter change (from stable adduct form to active catalyst form) allows the system to achieve both storage stability and low-temperature curability
2Productivity
If the epoxy resin composition is cured at low temperature, then productivity is improved, but uniformity of curing deteriorates leading to non-uniform viscosity and flowability
Solution Approach 1:
The adduct serves as a controlled intermediary that releases the active catalyst at a specific temperature threshold, ensuring uniform decomposition and catalyst release throughout the composition, thereby achieving uniform curing even at low temperatures
Solution Approach 2:
The curing catalyst is pre-prepared as a stable adduct that will decompose at the desired curing temperature. This preliminary preparation ensures that the catalyst activates uniformly throughout the composition at the specified temperature, preventing non-uniform curing
3Temperature
If the epoxy resin composition undergoes curing during storage, then low-temperature curability is achieved, but flowability deteriorates due to increase in viscosity
Solution Approach 1:
The adduct acts as a stable intermediary during storage that prevents premature catalyst activation. Only at the desired curing temperature does the adduct decompose to release the active catalyst, thereby maintaining flowability during storage while achieving curability at low temperature
Solution Approach 2:
The stable adduct form preliminarily counteracts the catalytic activity that would otherwise occur at storage temperature. This preliminary anti-action prevents unwanted curing and viscosity increase during storage, while allowing curability when heated to the decomposition temperature
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The catalyst enables low-temperature curing with high storage stability, preventing viscosity changes and maintaining the integrity of mechanical, electrical, and chemical properties in molded products, thus enhancing the reliability and performance of epoxy resin compositions.
Implementation Method 1
a curing catalyst is used together in order to catalyze curing reaction
Implementation Method 2
This catalyst is specifically designed to decompose and initiate curing between 100°C to 150°C
Data Source
AI summary
The present invention relates to a curing catalyst for an epoxy resin composition represented by chemical formula 1, an epoxy resin composition comprising the same, and an apparatus manufactured using the same.


