Latent Epoxy Curing Catalyst for Low-Temperature Stability

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Solution Overview

Problem

Epoxy resin compositions face issues with low-temperature curability and storage stability due to existing curing catalysts, leading to non-uniform curing and deterioration in mechanical, electrical, and chemical properties of molded articles.

Innovation Solution

A curing catalyst represented by Formula 1, which catalyzes curing at low temperatures while maintaining high storage stability and minimizing viscosity changes, is introduced. This catalyst is specifically designed to decompose and initiate curing between 100°C to 150°C, ensuring controlled curing and maintaining flowability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If a curing catalyst that catalyzes curing even at relatively low temperatures is used, then low-temperature curability is improved, but storage stability deteriorates because the epoxy resin composition undergoes partial curing during storage

Engineering Contradiction:
Improvecuring temperatureVSAvoidstorage stability
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent uses an adduct of triphenylphosphine and 1,4-benzoquinone as a latent curing catalyst that acts as an intermediary. This adduct remains stable during storage but decomposes at curing temperature to release the active catalyst, thereby mediating between storage stability requirements and low-temperature curability needs

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical state of the curing catalyst by forming an adduct that is stable at storage temperature but decomposes at curing temperature. This parameter change (from stable adduct form to active catalyst form) allows the system to achieve both storage stability and low-temperature curability

Inventive Principle:
Principle #35Parameter changes

2Productivity

If the epoxy resin composition is cured at low temperature, then productivity is improved, but uniformity of curing deteriorates leading to non-uniform viscosity and flowability

Engineering Contradiction:
Improvecuring speedVSAvoidcuring uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The adduct serves as a controlled intermediary that releases the active catalyst at a specific temperature threshold, ensuring uniform decomposition and catalyst release throughout the composition, thereby achieving uniform curing even at low temperatures

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The curing catalyst is pre-prepared as a stable adduct that will decompose at the desired curing temperature. This preliminary preparation ensures that the catalyst activates uniformly throughout the composition at the specified temperature, preventing non-uniform curing

Inventive Principle:
Principle #10Preliminary action

3Temperature

If the epoxy resin composition undergoes curing during storage, then low-temperature curability is achieved, but flowability deteriorates due to increase in viscosity

Engineering Contradiction:
Improvecurability temperatureVSAvoidflowability
Core Design Contradiction:
TemperatureVSEase of operation

Solution Approach 1:

The adduct acts as a stable intermediary during storage that prevents premature catalyst activation. Only at the desired curing temperature does the adduct decompose to release the active catalyst, thereby maintaining flowability during storage while achieving curability at low temperature

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The stable adduct form preliminarily counteracts the catalytic activity that would otherwise occur at storage temperature. This preliminary anti-action prevents unwanted curing and viscosity increase during storage, while allowing curability when heated to the decomposition temperature

Inventive Principle:
Principle #9Preliminary anti-action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The catalyst enables low-temperature curing with high storage stability, preventing viscosity changes and maintaining the integrity of mechanical, electrical, and chemical properties in molded products, thus enhancing the reliability and performance of epoxy resin compositions.

Implementation Method 1

a curing catalyst is used together in order to catalyze curing reaction

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

This catalyst is specifically designed to decompose and initiate curing between 100°C to 150°C

Methodology Applied
Scientific EffectDecomposition: Decomposition (biological)

Data Source

PatentUS9890238B2Curing catalyst for epoxy resin composition, epoxy resin composition comprising same, and apparatus manufactured by using same
Publication Date: 2018.02.13 SAMSUNG SDI CO LTD
  • US9890238B2 patent drawing
  • US9890238B2 patent drawing
  • US9890238B2 patent drawing

AI summary

The present invention relates to a curing catalyst for an epoxy resin composition represented by chemical formula 1, an epoxy resin composition comprising the same, and an apparatus manufactured using the same.