Latex Drag Reducing Polymer Injection for Asphaltene Crude Oils

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Solution Overview

Problem

Conventional polymeric drag reducers are ineffective in low API gravity and high-asphaltene crude oils, leading to inefficiencies and equipment costs due to pressure drops during pipeline transport, and can cause solids formation that plugs pipelines when injected directly.

Innovation Solution

A method involving a slipstream of liquid hydrocarbons being mixed with a latex comprising a high molecular weight drag reducing polymer upstream of an injection pump to create a drag reducing mixture, which is then injected into the pipeline, minimizing the risk of solids formation and enhancing flow efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If conventional polymeric drag reducers are used in low API gravity and high-asphaltene crude oils, then pressure drop reduction is achieved, but solids formation occurs that plugs pipelines

Engineering Contradiction:
Improvepressure dropVSAvoidsolids formation
Core Design Contradiction:
Loss of energyVSObject-affected harmful factors

Solution Approach 1:

The patent uses an aqueous solution or slurry as an intermediary carrier to transport the hydrophobic polymeric drag reducer from the injection point into the crude oil stream. The polymer is first dissolved or suspended in water, then this aqueous mixture is injected into the crude oil where the polymer eventually transfers to the oil phase. This intermediary approach prevents direct contact between the hydrophobic polymer and crude oil at the injection point, eliminating solids formation and plugging while still achieving drag reduction in the crude oil flow.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of operation

If direct pumping of drag reducing polymer into the pipeline is used, then injection simplicity is maintained, but solids formation plagues the injection system

Engineering Contradiction:
Improveinjection simplicityVSAvoidinjection system reliability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The aqueous solution serves as a mediator that allows the polymer to be pumped through standard aqueous-compatible injection systems without forming solids. The injection system only handles the aqueous polymer solution, which remains in liquid form and does not plug equipment. The transfer of polymer from the aqueous phase to the crude oil phase occurs downstream in the pipeline, separating the injection process from the polymer-crust interaction that causes plugging.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If higher flow rates are desired through the pipeline, then throughput increases, but pressure drop increases requiring more pumping pressure

Engineering Contradiction:
ImprovethroughputVSAvoidpumping pressure
Core Design Contradiction:
ProductivityVSStress or pressure

Solution Approach 1:

The patent changes the physical-chemical parameters of the crude oil by adding polymeric drag reducers that alter the flow regime. The high molecular weight polymers (5-10 million MW) change the turbulent flow characteristics, suppressing eddy formation and reducing friction factors. This parameter change allows the system to achieve higher throughput at the same pumping pressure, or equivalently, reduces the pressure required to maintain a given throughput.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively reduces drag and pressure drops in pipelines transporting low API gravity and high-asphaltene crude oils, maintaining flow efficiency while preventing pipeline plugging, thereby reducing operational costs and ensuring continuous pipeline operation.

Implementation Method 1

The role of these additives is to suppress the growth of turbulent eddies, which results in higher flow rate at a constant pumping pressure

Methodology Applied
Scientific EffectTurbulence suppression: Turbulence

Implementation Method 2

Effective drag reducing polymers typically have molecular weights in excess of five million and must dissolve in the hydrocarbon under turbulent flow

Methodology Applied
Scientific EffectDissolution: Solvation

Data Source

PatentUS8616236B2Drag reduction of asphaltenic crude oils
Publication Date: 2013.12.31 LIQUIDPOWER SPECIALTY PRODUCTS INC
  • US8616236B2 patent drawing
  • US8616236B2 patent drawing
  • US8616236B2 patent drawing

AI summary

A method begins by obtaining a slipstream of a liquid. The slipstream of liquid is then mixed upstream of an injection pump with a latex comprising a drag reducing polymer to produce a drag reducing mixture. The drag reducing mixture is then injected into a liquid hydrocarbon to produce a treated liquid hydrocarbon.