Latex Polymer Overcoat for Organic Photoconductors

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Solution Overview

Problem

The organic photoconductor (OPC) in electrophotographic printers faces frequent wear-out due to mechanical and physicochemical interactions, leading to degradation in print quality and increased costs, particularly in high-speed and large-volume printing applications, as existing solutions like inorganic coatings are costly and unreliable, and solvent-based organic coatings can damage the existing charge transport layer.

Innovation Solution

A water-based latex polymer coating system with suitable charge transport materials is employed, which forms a protective layer on the OPC using a dispersion mixture of cross-linkable monomers, oligomers, and surfactants, providing enhanced mechanical strength, chemical stability, and adhesion without damaging the existing polycarbonate layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If an inorganic film is coated on the CTL surface to improve durability, then scratch resistance is improved, but cost increases and contamination particles are introduced

Engineering Contradiction:
Improvescratch resistanceVSAvoidcontamination particles
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent replaces expensive inorganic coatings with a cost-effective organic coating system consisting of a polymer matrix and charge transport material. This organic coating provides sufficient protection without the high cost and contamination issues of inorganic alternatives, aligning with the principle of using economical substitutes that fulfill the functional requirement without the harmful side effects.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The invention uses a composite organic coating made from a polymer matrix combined with charge transport material molecules. This composite structure provides both mechanical protection (scratch resistance) and electrical functionality, eliminating the need for separate inorganic protective layers and avoiding contamination particle generation.

Inventive Principle:
Principle #40Composite materials

2Strength

If a solvent-based organic coating is applied to protect the OPC, then damage resistance is improved, but the existing charge transport layer is damaged

Engineering Contradiction:
Improvedamage resistanceVSAvoiddamage to charge transport layer
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent changes the solvent parameter from organic solvents to water as the coating medium. This parameter change fundamentally alters the coating process, allowing application without dissolving or damaging the polycarbonate charge transport layer, while still providing the necessary protective and conductive properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

Water serves as an intermediary medium that enables coating application without directly contacting or damaging the charge transport layer. The water-based formulation allows the coating to be applied and cured without the harmful effects of organic solvents, protecting the underlying CTL while providing surface protection.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If frequent OPC replacements are made to maintain print quality, then printing performance is maintained, but operational costs increase

Engineering Contradiction:
Improveprinting performanceVSAvoidoperational time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent applies a protective organic coating to the OPC surface before it undergoes wear and degradation. This preliminary protective action extends the operational lifetime of the OPC by preventing mechanical and chemical damage, thereby reducing the frequency of replacements and maintaining printing performance over extended periods.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The water-based latex polymer coating significantly extends the operational lifetime of the OPC by improving scratch resistance and maintaining printing performance, reducing the need for frequent replacements and associated costs, while being environmentally friendly and compatible with the existing OPC.

Implementation Method 1

a water-based latex polymer coating system with suitable charge transport materials is employed, which forms a protective layer on the OPC using a dispersion mixture of cross-linkable monomers, oligomers, and surfactants

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Data Source

PatentUS8841053B2Organic photoconductors with latex polymer overcoat layers
Publication Date: 2014.09.23 HEWLETT PACKARD DEVELOPMENT COMPANY LP
  • US8841053B2 patent drawing
  • US8841053B2 patent drawing
  • US8841053B2 patent drawing

AI summary

An organic photoconductor includes: a conductive substrate; a charge generation layer on the conductive substrate; and a charge transport layer on the charge generation layer. An overcoat layer is formed on the charge transport layer. The overcoat layer is a latex polymer in which a charge transport material is dispersed.