Laundry Dye Composition Brightening via Sunlight

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Solution Overview

Problem

Existing detergent formulations fail to achieve desired color brightness, particularly in achieving vibrant blue hues, as current dyes tend to produce dull colors when exposed to sunlight.

Innovation Solution

A detergent composition combining violet cationic alkoxylated thiophene dyes with blue triphenyl methane dyes, along with surfactants, where the molar ratio of blue to violet dye is between 1:1 to 1:3, and surfactants comprise 5 to 70 wt% of the formulation, enhancing color brightness upon sunlight exposure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If violet cationic thiophene dyes are mixed with additional dyes to obtain other aesthetic colours, then colour variety is improved, but colour brightness deteriorates

Engineering Contradiction:
Improvecolour varietyVSAvoidcolour brightness
Core Design Contradiction:
Adaptability or versatilityVSIllumination intensity

Solution Approach 1:

The patent applies parameter changes by carefully controlling the molar ratio of blue triphenyl methane dye to violet cationic alkoxylated thiophene dye within the range of 1:1 to 1:3. This specific ratio optimization ensures that the desired aesthetic color variety is achieved while maintaining or enhancing color brightness upon sunlight exposure, resolving the contradiction between color variety and brightness

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite dye system combining blue triphenyl methane dye and violet cationic alkoxylated thiophene dye in specific proportions. This composite approach creates a synergistic effect where the combination produces brighter colors upon sunlight exposure compared to using individual dyes alone, thereby achieving both color variety and brightness

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If dyes are used to provide aesthetic colours in detergent, then visual appeal is improved, but color stability under sunlight deteriorates

Engineering Contradiction:
Improveaesthetic colourVSAvoidcolor stability under sunlight
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent optimizes the concentration parameters of both dyes within specific ranges (violet dye: 0.0001 to 0.1 wt%, preferably 0.0005 to 0.005 wt%; blue dye with molar ratio 1:1 to 1:3). This parameter optimization ensures that the detergent provides desirable aesthetic colors while achieving improved color stability and brightness upon sunlight exposure

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The composite dye system combining blue triphenyl methane dye and violet cationic alkoxylated thiophene dye creates a synergistic effect that enhances color stability under sunlight. The specific composition ratio ensures that the mixture maintains or improves color brightness upon sunlight exposure, contrary to the deteriorating effect observed with single dyes or conventional mixtures

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The combination of violet and blue dyes results in a brighter blue color when exposed to sunlight, with specific surfactant ratios and types optimizing the color enhancement, as demonstrated by increased optical density ratios and minimal dye loss during simulated sunlight exposure.

Implementation Method 1

mixtures of violet thiophene dyes and blue triphenyl methane dyes become brighter blue on exposure to sunlight

Methodology Applied
Scientific EffectPhotochemical interaction: Photo-oxidation

Data Source

PatentEP2875112B1Bright detergent composition
Publication Date: 2017.02.08 UNILEVER PLC
  • EP2875112B1 patent drawing
  • EP2875112B1 patent drawing
  • EP2875112B1 patent drawing

AI summary

A coloured laundry detergent is provided that brightens on exposure to light.