Laval Nozzle Electrode Coating Without Solvent Drying or Calendering

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Solution Overview

Problem

Existing methods for coating anode and cathode plates in lithium-ion battery cells face issues such as high costs, energy consumption, wrinkling, poor adhesion, and complexity due to solvent use and calendering processes, which are not effectively addressed by dry coating alternatives.

Innovation Solution

A method using a Laval nozzle to apply a solvent-free coating by accelerating dry particles to supersonic speeds, allowing for direct adhesion to the carrier material without calendering, enabling multiple layers with varying densities and properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If wet coating with solvent is used, then coating adhesion is improved, but energy consumption increases due to solvent drying

Engineering Contradiction:
Improvecoating adhesionVSAvoidenergy consumption
Core Design Contradiction:
StrengthVSUse of energy by moving object

Solution Approach 1:

The patent removes the solvent component from the coating process entirely, using only dry powder active material and binding material. This extraction of the harmful solvent element eliminates the need for energy-intensive drying operations while maintaining coating integrity through alternative adhesion mechanisms.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent replaces the thermal drying process (heat-based) with a mechanical/physical deposition process using a Laval nozzle. The supersonic gas stream mechanically propels particles onto the substrate, substituting thermal energy with kinetic energy for the coating deposition.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Quantity of substance

If calendering process is used for densification, then specific capacitance is improved, but device complexity increases

Engineering Contradiction:
Improvespecific capacitanceVSAvoidmachinery complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent replaces the complex mechanical calendering system with a simpler Laval nozzle-based particle deposition system. The supersonic gas stream naturally densifies the coating during deposition, eliminating the need for separate calendering equipment and operations.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent combines the coating deposition and densification operations into a single step using the Laval nozzle. The supersonic particle stream simultaneously deposits material and compacts it, merging two previously separate processes into one integrated operation.

Inventive Principle:
Principle #5Merging (Combining)

3Adaptability or versatility

If multiple coating-calendering cycles are performed for different densities, then layer differentiation is improved, but production time increases

Engineering Contradiction:
Improvelayer density controlVSAvoidproduction time
Core Design Contradiction:
Adaptability or versatilityVSProductivity

Solution Approach 1:

The patent introduces dynamic control parameters (gas stream velocity, particle feed rate, nozzle-to-substrate distance) that allow real-time adjustment of coating density during deposition. This dynamic control enables different density layers to be created in a single pass without repeated cycling.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent segments the coating process into controllable parameter zones, where different regions of the substrate or different time periods during deposition can receive different parameter settings to create layers with different densities, all within one continuous operation.

Inventive Principle:
Principle #1Segmentation

4Adaptability or versatility

If substrate is rewound after each process step, then process flexibility is improved, but particle contamination increases

Engineering Contradiction:
Improveprocess flexibilityVSAvoidparticle contamination
Core Design Contradiction:
Adaptability or versatilityVSObject-affected harmful factors

Solution Approach 1:

The patent combines multiple process steps (coating, drying, calendering) into a single continuous operation using the Laval nozzle. This eliminates intermediate rewinding operations that cause contamination, as the entire process occurs in one continuous pass without substrate handling interruptions.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Achieves high-density coatings with improved adhesion and reduced production time and costs by eliminating the need for calendering and solvent use, while allowing for precise control of layer properties.

Implementation Method 1

a gas stream is accelerated by a Laval nozzle to a supersonic velocity

Methodology Applied
Scientific EffectSupersonic flow: De Laval Nozzle

Implementation Method 2

The Laval nozzle has a converging first section, a second section with a smallest flow cross-section and a diverging third section arranged sequentially along a flow direction

Methodology Applied
Scientific EffectGas stream acceleration: De Laval Nozzle

Implementation Method 3

The accelerated particle stream is applied to the carrier material to form a layer of a coating

Methodology Applied
Scientific EffectParticle deposition: Deposition (physical)

Implementation Method 4

The binding material adheres the active material to the carrier material, so that a calendering process is no longer necessary

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentEP4063017B1Method for coating a support material with an active material for producing an electrode foil of a battery cell
Publication Date: 2025.06.25 POWERCO SE
  • EP4063017B1 patent drawingFigure 1~2
  • EP4063017B1 patent drawingFigure 3~4
  • EP4063017B1 patent drawingFigure 5~6

AI summary

Method for coating a carrier material (1) with an active material (2) for producing an electrode foil (3) of a battery cell (4) with a Laval nozzle (5), wherein the Laval nozzle (5) is arranged successively along a flow direction (6) and has at least a converging first section (7), a second section (8) with a minimum flow cross-section (9) and a diverging third section (10).