Layered Alginic Acid Sponge for Biodegradable Adhesion Prevention

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing methods for preventing surgical adhesions are either non-biodegradable or insufficiently effective, and there is a need for a material that prevents adhesions without interfering with wound healing and can be easily applied via trocar during surgery.

Innovation Solution

A biocompatible sponge-like laminate with two layers of low-endotoxin monovalent metal salts of alginic acid, where the first layer has a higher weight-average molecular weight than the second, allowing for controlled dissolution rates to prevent adhesions effectively.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a PTFE film is used as an anti-adhesion barrier, then adhesion prevention is achieved, but the material remains in the body as it is not biodegradable

Engineering Contradiction:
Improveadhesion prevention effectivenessVSAvoidnon-biodegradability
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the barrier material from synthetic PTFE to natural polysaccharides (hyaluronic acid and carboxymethyl cellulose), transforming it into a biodegradable material that maintains adhesion prevention effectiveness while being safely metabolized in the body

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a biodegradable barrier material designed to perform its adhesion prevention function temporarily during the critical healing period and then naturally decompose, eliminating the need for permanent retention in the body and avoiding long-term foreign body presence

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Object-generated harmful factors

If a sheet containing HA and CMC is used as an anti-adhesion barrier, then biodegradability is achieved, but it is unable to completely prevent serious adhesions

Engineering Contradiction:
ImprovebiodegradabilityVSAvoidadhesion prevention effectiveness
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent creates a composite material combining hyaluronic acid and carboxymethyl cellulose in specific ratios, leveraging the complementary properties of both polysaccharides to achieve superior adhesion prevention compared to single-component materials, while maintaining biodegradability

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the local composition and structure of the barrier material at the molecular level, specifically tailoring the polysaccharide ratio and molecular weight distribution to enhance the material's ability to prevent serious adhesions in critical areas while maintaining overall biocompatibility

Inventive Principle:
Principle #3Local quality

3Reliability

If a multilayered material with different dissolution rates is used, then healing is improved, but the manufacturing process becomes more complex

Engineering Contradiction:
Improvehealing promotionVSAvoidmultilayered structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent divides the barrier material into multiple layers with different polysaccharide compositions and dissolution rates, allowing the first layer to dissolve rapidly for initial wound protection while the second layer dissolves slowly for sustained adhesion prevention, optimizing the healing process at different stages

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces temporal dynamics into the barrier material design by creating layers with progressively different dissolution rates, enabling the material to dynamically adapt its protective function as the wound heals, transitioning from rapid initial protection to sustained long-term prevention

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The laminate effectively prevents adhesions, is biocompatible, and can be reapplied during surgery, with controlled dissolution rates and minimal impact on wound healing.

Implementation Method 1

a biocompatible sponge-like laminate which includes first and second sponge-like layers containing low-endotoxin monovalent metal salts of alginic acid which are at least partially crosslinked with a curing agent

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Implementation Method 2

obtainable by commonly or individually lyophilizing the cured first and second layers of the laminate

Methodology Applied
Scientific EffectLyophilization: Freeze Drying

Data Source

PatentEP3741400B1Anti-adhesion composition
Publication Date: 2026.03.11 MOCHIDA PHARM CO LTD
  • EP3741400B1 patent drawingFigure 1
  • EP3741400B1 patent drawingFigure 2
  • EP3741400B1 patent drawingFigure 3

AI summary

The purpose of the present invention is to provide an anti-adhesion material having a high anti-adhesion effect. The present invention pertains to an anti-adhesion material comprising a biocompatible sponge-like layered body having a sponge-like first layer and a sponge-like second layer both being at least partially crosslinked with a curing agent and comprising a low endotoxin monovalent metal salt of alginic acid. The monovalent metal salt of alginic acid in the first layer has a weight average molecular weight of 30000 to 300000. The monovalent metal salt of alginic acid in the second layer has a weight average molecular weight of 1000 to 200000. The weight average molecular weights are determined by GPC-MALS after a de-crosslinking treatment. The weight average molecular weight of the monovalent metal salt of alginic acid in the first layer is higher than the weight average molecular weight of the monovalent metal salt of alginic acid in the second layer.