Layered Solid-Electrolytic Capacitor for High Capacitance Density

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Solution Overview

Problem

The challenge of miniaturizing solid-electrolytic capacitors while maintaining their capacitance has not been adequately addressed, necessitating an improvement in capacitance appearance ratio per unit volume.

Innovation Solution

A solid-electrolytic capacitor design featuring a first ion-conducting electrolyte layer and a second electron-conducting electrolyte layer, with the first layer immobilized using silane coupling agents to prevent ionic liquid leakage, and a conductive polymer layer for enhanced conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Volume of moving object

If the size of solid-electrolytic capacitors is reduced to meet miniaturization requirements, then the volume decreases, but the capacitance appearance ratio deteriorates

Engineering Contradiction:
Improvecapacitor volumeVSAvoidcapacitance appearance ratio
Core Design Contradiction:
Volume of moving objectVSQuantity of substance

Solution Approach 1:

The solid electrolyte layer is segmented into two distinct functional layers: an ion-conducting electrolyte layer (first electrolyte layer) and an electron-conducting electrolyte layer (second electrolyte layer). This segmentation allows each layer to perform its specific function optimally, with the ion-conducting layer enabling ion transport and the electron-conducting layer providing electron transport pathways, thereby maintaining high capacitance appearance ratio even in miniaturized capacitors

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs composite material structure by combining different types of electrolyte materials with complementary properties. The ion-conducting electrolyte (e.g., ionic liquid or polymer electrolyte) and electron-conducting electrolyte (e.g., conductive polymer) are combined in a layered configuration, creating a composite solid electrolyte system that achieves both high ion conductivity and high electron conductivity, thus improving capacitance density in small-volume capacitors

Inventive Principle:
Principle #40Composite materials

2Device complexity

If a single-layer solid electrolyte structure is used, then the device complexity is low, but the capacitance appearance ratio is insufficient

Engineering Contradiction:
Improveelectrolyte layer structureVSAvoidcapacitance appearance ratio
Core Design Contradiction:
Device complexityVSQuantity of substance

Solution Approach 1:

The electrolyte system is divided into two functional layers with distinct roles. The first electrolyte layer (ion-conducting) and second electrolyte layer (electron-conducting) are stacked in sequence on the dielectric layer, creating a segmented structure that enhances overall performance while maintaining manufacturing simplicity through a straightforward layered deposition process

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The solid electrolyte layer is designed to perform multiple functions through its composite structure: the ion-conducting electrolyte layer handles ion transport and storage, while the electron-conducting electrolyte layer provides electron transport and additional capacitance. This multi-functionality allows a single electrolyte layer assembly to achieve high capacitance appearance ratio without significantly increasing device complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The design achieves a high capacitance appearance ratio and prevents deterioration due to ionic liquid outflow, ensuring reliable capacitor performance.

Implementation Method 1

the first electrolyte layer is an ion-conducting electrolyte layer

Methodology Applied
Scientific EffectIon conduction: Conduction (electrical)

Implementation Method 2

the second electrolyte layer is an electron-conducting electrolyte layer

Methodology Applied
Scientific EffectElectron conduction: Conduction (electrical)

Implementation Method 3

a dielectric layer formed on the anode member

Methodology Applied
Scientific EffectDielectric polarization: Dielectric

Data Source

PatentUS12614678B2Solid-electrolytic capacitor and method for manufacturing solid-electrolytic capacitor
Publication Date: 2026.04.28 TOKIN CORP
  • US12614678B2 patent drawing
  • US12614678B2 patent drawing
  • US12614678B2 patent drawing

AI summary

A solid-electrolytic capacitor according to an aspect of the present disclosure includes an anode member made of a valve metal, a dielectric layer formed on the anode member, and a solid electrolyte layer formed on the dielectric layer. The solid electrolyte layer includes a first electrolyte layer formed on the dielectric layer and a second electrolyte layer formed on the first electrolyte layer, in which the first electrolyte layer is an ion-conducting electrolyte layer and the second electrolyte layer is an electron-conducting electrolyte layer.