Layered Oxide Semiconductor Conductivity Control

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Solution Overview

Problem

Current oxide semiconductors primarily consist of n-type materials, limiting the development of p-type oxide semiconductors necessary for forming p-n junctions and other devices, as well as controlling conductivity in bipolar oxide semiconductors.

Innovation Solution

A layered oxide semiconductor structure expressed by the formula ∏i=1L[(AO)(ZO)mi(BO)ni]i is developed, where A, Z, and B are specific elements, allowing for controlled conductivity by adjusting the values of L, mi, and ni, enabling p-type or n-type conductivity through carrier induction.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional oxide semiconductor materials are used, then n-type conductivity is achieved, but p-type conductivity cannot be obtained

Engineering Contradiction:
Improveconductivity typeVSAvoidconductivity limitation
Core Design Contradiction:
Adaptability or versatilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the oxide semiconductor by incorporating specific elements (Cu, Al, Ga, In for p-type; Zn, Sn for n-type) in controlled ratios. By adjusting the concentration of these elements and their oxidation states, the patent achieves transition between p-type and n-type conductivity, resolving the limitation of conventional materials that could only provide n-type conductivity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite oxide semiconductor materials by combining multiple metal elements (Cu, Al, Ga, In, Zn, Sn) with oxygen in specific ratios. These composite materials exhibit tunable conductivity properties that neither single-element oxides could achieve alone, enabling both p-type and n-type conductivity in a unified material system.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If p-type oxide semiconductors are developed, then bipolar devices can be formed, but material composition control becomes complex

Engineering Contradiction:
Improvedevice functionalityVSAvoidcomposition control
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent applies local quality by creating regions with different elemental compositions within the oxide semiconductor structure. By controlling the spatial distribution and concentration of specific elements (e.g., Cu-rich regions for p-type, Zn-rich regions for n-type), the patent enables formation of bipolar devices with distinct functional zones while maintaining overall compositional control through systematic ratios.

Inventive Principle:
Principle #3Local quality

3Adaptability or versatility

If layered oxide structure is adopted, then conductivity control is improved, but manufacturing precision requirements increase

Engineering Contradiction:
Improveconductivity controlVSAvoidlayer structure control
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The patent segments the oxide semiconductor into a layered structure with alternating planes of different compositional characteristics. This segmentation into distinct layers with specific element distributions allows independent optimization of conductivity properties in each layer while simplifying the overall control mechanism through repetitive structural units.

Inventive Principle:
Principle #1Segmentation

Data Source

PatentUS10141185B2Oxide semiconductor, coating liquid, method of forming oxide semiconductor film, semiconductor element, display element, image display device and image display system
Publication Date: 2018.11.27 RICOH CO LTD
  • US10141185B2 patent drawing
  • US10141185B2 patent drawing
  • US10141185B2 patent drawing

AI summary

An oxide semiconductor includes an oxide having a layered structure expressed by an expression of a product of [(AO)(ZO)mi(BO)(ZO)ni]i from i=1 to L. In the product, an atom A is a positive monovalent element, an atom Z is a positive divalent element, an atom B is a positive trivalent element, L is a positive integer, and mi and ni are independent integers greater than or equal to zero. A sum from i=1 to L of (mi+ni) is not zero.