Liquid Crystal Composition for Display Response and Stability

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Solution Overview

Problem

Current liquid crystal compositions for active matrix devices lack optimal balance of high maximum and low minimum temperatures, low viscosity, large dielectric anisotropy, and stability to ultraviolet light and heat, which affects the devices' performance in terms of response time, contrast ratio, and service life.

Innovation Solution

A liquid crystal composition comprising specific compounds represented by formulas (1) and (2), with the first component ranging from 25 wt% to 85 wt%, optimized to achieve a balance of desired characteristics, including a nematic phase with high maximum and low minimum temperatures, low viscosity, and high dielectric anisotropy, stability to ultraviolet light and heat, and a large elastic constant.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If liquid crystal composition uses conventional compounds, then manufacturing is simpler, but the balance of maximum temperature, minimum temperature, viscosity, dielectric anisotropy, and stability is insufficient

Engineering Contradiction:
Improvebalance of temperature range, viscosity, dielectric anisotropy, and stabilityVSAvoidcomposition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs composite liquid crystal compositions containing specific compounds with defined molecular structures (formulas 1 and 2) combined in optimized proportions. This composite approach achieves superior balance of temperature range, viscosity, dielectric anisotropy, and stability that cannot be obtained with single conventional compounds, while maintaining manufacturability through well-defined compositional specifications.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent systematically adjusts key parameters including the proportions of first and second components (25-85 wt% and 15-75 wt% respectively), molecular structure parameters (substituents R1-R6, rings A-D, bonds/atoms X1-X8, Y1-Y4, Z1-Z5), and physical properties (dielectric anisotropy, viscosity, elastic constants). These parameter optimizations resolve the contradiction by achieving reliable performance balance through controlled compositional variations.

Inventive Principle:
Principle #35Parameter changes

2Use of energy by moving object

If liquid crystal composition has high dielectric anisotropy, then threshold voltage and power consumption are reduced, but viscosity may increase affecting response time

Engineering Contradiction:
Improvepower consumptionVSAvoidresponse time
Core Design Contradiction:
Use of energy by moving objectVSSpeed

Solution Approach 1:

The patent optimizes the dielectric anisotropy parameter by selecting specific molecular structures with appropriate substituents (fluorine, chlorine, trifluoromethyl groups) and core configurations. The composition achieves high dielectric anisotropy for low power consumption while maintaining acceptable viscosity through balanced molecular design and compositional proportions, resolving the energy-speed tradeoff.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces specific functional groups and molecular fragments with localized properties that contribute differently to dielectric anisotropy and viscosity. By combining compounds with complementary local characteristics (e.g., fluorinated groups for dielectric enhancement, cyclic structures for viscosity control), the composition achieves optimal balance between power consumption and response time.

Inventive Principle:
Principle #3Local quality

3Speed

If liquid crystal composition has low viscosity, then response time is shortened, but stability to ultraviolet light and heat may be reduced

Engineering Contradiction:
Improveresponse timeVSAvoidstability to ultraviolet light and heat
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent creates a composite composition where low-viscosity compounds (for fast response) are combined with high-stability compounds containing UV-absorbing groups and thermally stable molecular structures. This composite approach achieves both low viscosity for rapid response and high stability for long service life, resolving the speed-reliability contradiction.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces stabilizing compounds as intermediaries that protect the low-viscosity liquid crystal molecules from UV degradation and thermal decomposition. These intermediary substances absorb harmful radiation and dissipate thermal energy, enabling the use of low-viscosity components without sacrificing stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Illumination intensity

If liquid crystal composition has high elastic constant, then contrast ratio is improved, but response time may be prolonged

Engineering Contradiction:
Improvecontrast ratioVSAvoidresponse time
Core Design Contradiction:
Illumination intensityVSSpeed

Solution Approach 1:

The patent optimizes the elastic constant parameter by selecting molecular structures with appropriate rigidity and flexibility balance. The composition achieves high elastic constant for improved contrast ratio while controlling response time through viscosity management and molecular structure selection, resolving the contrast-speed tradeoff.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition provides a liquid crystal display device with improved response time, voltage holding ratio, contrast ratio, and extended service life, suitable for applications in liquid crystal projectors and televisions.

Implementation Method 1

a liquid crystal composition having a positive dielectric anisotropy

Methodology Applied
Scientific EffectDielectric anisotropy: Dielectric Permittivity

Implementation Method 2

The optical anisotropy of the composition relates to the contrast ratio of the device

Methodology Applied
Scientific EffectOptical anisotropy: Birefringence

Data Source

PatentUS9365772B2Compound, liquid crystal composition and liquid crystal display device
Publication Date: 2016.06.14 JIANGSU HECHENG DISPLAY TECH CO LTD
  • US9365772B2 patent drawing
  • US9365772B2 patent drawing
  • US9365772B2 patent drawing

AI summary

A liquid crystal composition is described, which has a nematic phase and contains a compound having a high maximum temperature and a large dielectric anisotropy as a first component, and a specific compound having a large dielectric anisotropy as a second component, and may also contain a specific compound having a large dielectric anisotropy as a third component, and a compound having a small viscosity as a fourth component. An AM liquid crystal display device including the composition is also described.